Aqueous active material composition, electrode, and rechargeable lithium battery using the same
View Patent ↗An aqueous active material composition, an electrode, and a rechargeable lithium battery including the same, the aqueous active material composition including an active material; a binder; and a water-soluble cellulose mixture, wherein the water-soluble cellulose mixture includes a first cellulose compound having a degree of substitution of about 0.5 to about 0.9 and a second cellulose compound having a degree of substitution of about 1.1 to about 1.5.
1. An aqueous active material composition, comprising:
an active material;
a binder; and
a water-soluble cellulose mixture,
wherein the water-soluble cellulose mixture includes:
a first cellulose compound having a degree of substitution of about 0.5 to about 0.9, and
a second cellulose compound having a degree of substitution of about 1.1 to about 1.5, and
wherein a weight ratio of the first cellulose compound to the second cellulose compound is 50:50 to about 99:1.
2. The aqueous active material composition as claimed in claim 1 , wherein the first cellulose compound and the second cellulose compound each independently include carboxylmethyl cellulose, methyl cellulose, hydroxylethyl cellulose, hydroxypropyl cellulose, or a combination thereof.
3. The aqueous active material composition as claimed in claim 1 , wherein a weight ratio of the first cellulose compound to the second cellulose compound is 50:50 to about 60:40.
4. The aqueous active material composition as claimed in claim 1 , wherein the active material is a positive active material or a negative active material.
5. The aqueous active material composition as claimed in claim 4 , wherein the active material is the positive active material, the positive active material including LiCoO 2 , LiMn 2 O 4 , LiMnPO 4 , LiFePO 4 , LiNiO 2 , Li(NixCoyMnz)O 2 (x+y+z=1, 0<x, y, z<1), or a combination thereof.
6. The aqueous active material composition as claimed in claim 4 , wherein the active material is the positive active material, the positive active material including LiNi x Mn 1-x O 2 (0.1≦x≦0.4).
7. The aqueous active material composition as claimed in claim 4 , wherein the active material is the positive active material, the positive active material having an average particle diameter of about 3 μm to about 12 μm.
8. The aqueous active material composition as claimed in claim 4 , wherein the active material is the negative active material, the negative active material including a material that reversibly intercalates/deintercalates lithium ions, a lithium metal, a lithium metal alloy, a material being capable of doping and dedoping lithium, a transition metal oxide, or a combination thereof.
9. The aqueous active material composition as claimed in claim 1 , further comprising a conductive material, the conductive material including natural graphite, artificial graphite, carbon black, acetylene black, ketjen black, a carbon fiber, a metal powder, a metal fiber, or a combination thereof.
10. The aqueous active material composition as claimed in claim 1 , wherein the binder includes a styrene-based latex binder, an acrylate-based binder, or a combination thereof.
11. The aqueous active material composition as claimed in claim 10 , wherein the binder includes the styrene-based latex binder, the styrene-based latex binder including a styrene-butadiene rubber, an acrylate-styrene butadiene copolymer rubber, an acrylonitrile-styrene butadiene copolymer rubber, or a combination thereof.
12. The aqueous active material composition as claimed in claim 10 , wherein the binder includes the acrylate-based binder, the acrylate-based binder including a methylmethacrylate-lithiummethacrylic acid copolymer, an alkylacrylate-acrylonitrile-acrylic acid copolymer, or a combination thereof.
13. The aqueous active material composition as dammed in claim 1 , wherein the aqueous active material composition includes:
about 84 wt % to about 99 wt % of the active material;
about 0.5 wt % to about 3 wt % of the binder; and
about 0.5 wt % to about 3 wt % of the water-soluble cellulose mixture.
14. An electrode manufactured using the aqueous active material composition as claimed in claim 1 .
15. The electrode as claimed in claim 14 , wherein the electrode is a positive electrode, the positive electrode having a thickness of about 80 μm to about 250 μm.
16. The electrode as claimed in claim 14 , wherein the electrode is a negative electrode, the negative electrode having a resistivity of about 20 Ωm or less.
17. The electrode as claimed in claim 16 , wherein the resistivity of the negative electrode is about 0.5 Ωm or less.
18. The electrode as claimed in claim 14 , wherein the electrode is a negative electrode, the negative electrode having a thickness of about 50 μm to about 200 μm.
19. A rechargeable lithium battery comprising the electrode as claimed in claim 14 .
20. The aqueous active material composition as claimed in claim 1 , wherein the first cellulose compound and the second cellulose compound are both a carboxylmethyl cellulose compound, both a methyl cellulose compound, both a hydroxylethyl cellulose compound, or both a hydroxypropyl cellulose compound.