Positively chargeable toner for electrostatic image development
View Patent ↗Domains of a charge control resin are formed by dispersing a charge control resin containing a quaternary ammonium salt functional group-containing resin of a copolymer of an addition-polymerizable monomer having a quaternary ammonium salt functional group and a styrene and/or acrylic monomer into a polyester resin as binder resin, and the proportion of the number of domains of the charge control resin with a domain diameter of no less than 0.01 μm to less than 0.3 μm versus the number of domains of the charge control resin with a domain diameter of no less than 0.01 μm, which is measured by a predetermined method, is adjusted to no less than 98% by number.
1. A positively chargeable toner for electrostatic image development, comprising a binder resin and a mixture of a styrene resin and a quaternary ammonium salt functional group-containing resin of a copolymer of an addition-polymerizable monomer having a quaternary ammonium salt functional group, a styrene monomer and acrylic monomer,
wherein the mixture of the styrene resin and the quaternary ammonium salt functional group-containing resin forms domains, which are not compatible with the binder resin, in the binder resin,
the binder resin is a polyester resin which is a polycondensate of one or more alcohol components selected from bivalent, trivalent or higher-valent alcohols and one or more carboxylic acid components selected from bivalent, trivalent or higher-valent carboxylic acids, and
the number % of the sum of N1 to N29 (Nn: number of domains consisting of the mixture of the styrene resin and the quaternary ammonium salt functional group-containing resin of which the diameter of domains dispersed is no less than 0.01×n μm to less than 0.01×(n+1) μm; n: a positive integer of 1 or more) versus the total number of domains consisting of the charge control resin, for which the diameter of domains dispersed of no less than 50 by number of domains consisting of the mixture of the styrene resin and the quaternary ammonium salt functional group-containing resin have been measured using an image of magnification 10,000× taken by a scanning electron microscope, is no less than 98% by number.
2. The positively chargeable toner for electrostatic image development according to claim 1 , wherein proportion of total area of domains consisting of the mixture of the styrene resin and the quaternary ammonium salt functional group-containing resin charge control resin versus the cross-sectional area of the toner is 1% to 10% by area.
3. The positively chargeable toner for electrostatic image development according to claim 1 , wherein the content of the styrene resin in the mixture of the styrene resin and the quaternary ammonium salt functional group-containing resin is 40 to 200 parts by mass based on 100 parts by mass of the quaternary ammonium salt functional group-containing resin.
4. The positively chargeable toner for electrostatic image development according to claim 1 , wherein proportion of repeating units derived from the addition-polymerizable monomer having a quaternary ammonium salt functional group versus the total repeating units of the quaternary ammonium salt functional group-containing resin is 0.1% to 20% by mole in the quaternary ammonium salt functional group-containing resin.
5. A positively chargeable toner for electrostatic image development, comprising a binder resin and a mixture of a nitrogen atom-containing charge control agent and a charge control resin,
wherein the mixture of the nitrogen atom-containing charge control agent and the charge control resin forms domains which are not compatible with the binder resin in the binder resin,
the binder resin is a polyester resin which is a polycondensate of one or more alcohol components selected from bivalent, trivalent or higher-valent alcohols and one or more carboxylic acid components selected from bivalent, trivalent or higher-valent carboxylic acids,
the charge control resin contains a quaternary ammonium salt functional group-containing resin of a copolymer of an addition-polymerizable monomer having a quaternary ammonium salt functional group and a styrene monomer and acrylic monomer, and
the number % of the sum of N1 to N29 (Nn: number of domains consisting of the charge control resin of which the diameter of domains dispersed is no less than 0.01×n μm to less than 0.01×(n+1) μm; n: a positive integer of 1 or more) versus the total number of domains consisting of the charge control resin, for which the diameter of domains dispersed of no less than 50 by number of domains consisting of the charge control resin have been measured using an image of magnification 10,000× taken by a scanning electron microscope, is no less than 98% by number.
6. The positively chargeable toner for electrostatic image development according to claim 5 , wherein proportion of total area of the charge control domains versus the cross-sectional area of the toner is 1% to 10% by area.
7. The positively chargeable toner for electrostatic image development according to claim 5 , wherein the amount of the nitrogen atom-containing charge control agent in the toner is 1% to 10% by mass based on the total mass of the nitrogen atom-containing charge control agent in the toner and the charge control resin.
8. The positively chargeable toner for electrostatic image development according to claim 5 , wherein the nitrogen atom-containing charge control agent is a quaternary ammonium salt.
9. The positively chargeable toner for electrostatic image development according to claim 5 , wherein the amount of repeating units derived from the addition-polymerizable monomer having a quaternary ammonium salt functional group versus the total repeating units of the quaternary ammonium salt functional group-containing resin is 0.1% to 20% by mole in the quaternary ammonium salt functional group-containing resin.