Silica removal from pregnant leach solutions
View Patent ↗The present invention relates generally to a process for removing dissolved or colloidal silica from a pregnant leach solution (“PLS”). More particularly, an exemplary embodiment of the present invention relates to a, process which mixes PLS with an acid source, preferably lean electrolyte, to induce formation of colloidal silica that can then be collected and removed. Additionally, in an exemplary embodiment of the present invention, at least one silica seeding agent is added to induce formation of colloidal silica, at least one flocculant is added to induce aggregation of the colloidal silica, and a solid-liquid separation process is utilized to remove advantageous amounts or substantially all of the colloidal silica, thereby providing relief from supersaturation of dissolved silica in the metal recovery processes.
1. A method for providing relief from dissolved silica in pregnant leach solutions comprising:
providing a meal-bearing solution comprising a metal value and dissolved silica;
introducing an acid and a seeding agent to a the metal-bearing solution to yield a metal bearing solution comprising the metal value and colloidal silica;
adding a flocculant to the metal-hearing solution such that the colloidal silica agglomerates;
removing at least a portion of the agglomerated silica.
2. The method of claim 1 , wherein the seeding agent is a colloidal silica seeding agent.
3. The method of claim 1 , wherein the seeding agent comprises a portion of the removed agglomerated silica.
4. The method of claim 1 , wherein the step of removing at least a portion of the agglomerated silica comprises providing the metal-bearing solution comprising agglomerated silica to a solid-liquid separation apparatus, wherein the solid-liquid separation apparatus comprises at least one of a filtration system, a countercurrent decantation circuit, a thickener, a centrifuge, a screen, a flotation method, a clarification method, and a flocculation method.
5. The method of claim 1 , further comprising a step of providing the metal-bearing solution to an electrowinning process after a portion of the agglomerated silica is removed.
6. The method of claim 5 , wherein the colloidal silica seeding agent is recycled from the electrowinning process.