System for making renewable fuels
View Patent ↗Multiple catalytic processing stations couple with a system which produces volatile gas streams from biomass decomposition at discrete increasing temperatures. These catalytic processing stations can be programmed to maximize conversion of biomass to useful renewable fuel components based on input feedstock and desired outputs.
1. A system for the conversion of biomass to renewable fuel, comprising:
a programmable number of processing stations (N) for subjecting biomass to at least one programmable starting temperature (Tstart) and for incrementing the temperature by programmable increments (ΔT) to produce a volatile and a non-volatile component;
a series of catalyst columns; and
means for subjecting the volatile components generated in each station through the series of catalyst columns to produce at least one renewable fuel.
2. The system of claim 1 , wherein the series of catalyst columns comprise catalysts for catalytic aromatization and catalytic gas-upgrading.
3. The system of claim 1 , wherein the series of catalyst columns comprise catalysts for catalytic dehydration and catalytic gas-upgrading.
4. The system of claim 1 , wherein the series of catalyst columns comprise catalysts for catalytic dehydration and catalytic aromatization.
5. The system of claim 1 , wherein the processing station is further used for incrementing the non-volatile component temperature by ΔT to produce additional volatile and non-volatile components.
6. The system of claim 1 , wherein N ranges from 2 to 1000, and wherein Tstart ranges from 100° C. to 1000° C.
7. The system of claim 1 , wherein the temperature increment (ΔT) ranges from 0° C. to 200° C., and wherein biomass moisture content is less than 15%.
8. The system of claim 7 , wherein biomass is ground to a particle size between 1/16 inch and 1 inch.
9. The system of claim 1 , wherein a co-solvent is added to volatile components or added to at least one of the processing stations, wherein the co-solvent is selected from the group consisting of alcohols, aldehydes, ketones, ethers, carboxylic acids, and hydrocarbons, and wherein the co-solvent is generated via a syngas conversion catalyst.
10. The system of claim 1 , wherein biomass is selected from the group consisting of lipids, hemicellulose, cellulose and lignins.
11. The system of claim 10 , wherein Tstart is below 300° C. for biomass composition comprising 20-80% lipids, wherein Tstart is in the range of 300-500° C. for biomass comprising 20-80% hemicellulose, and wherein Tstart is greater than 500° C. for biomass composition comprising 20-80% lignins.
12. The system of claim 10 , wherein Tstart is selected according to the highest biomass compositional component selected from the groups consisting of lipids, hemicellulose and lignins.
13. The system of claim 1 , wherein all processing stations are set at the same Tstart.
14. The system of claim 1 , wherein the non-volatile component is thermally conductive.
15. A system for converting biomass to renewable fuel, comprising:
a programmable number of processing stations (N) for subjecting biomass to at least one programmable starting temperature (Tstart) and for incrementing the temperature by programmable increments (ΔT) to produce a volatile and a non-volatile component;
a series of catalyst columns for catalytic aromatization and catalytic gas-upgrading; and
means for subjecting the volatile components generated in each station through the series of catalyst columns to produce at least one renewable fuel.
16. The system of claim 15 , wherein the aromatization catalyst is selected from the group consisting of MFI type zeolites and metal modified MFI-type zeolites.
17. The system of claim 16 , wherein the metal modified MFI-type zeolites include one or more metals selected from the group consisting of: Group VIB metals, Group VIIB metals, Group VIII metals, Group IB metals, Group IIB metals, Ga, and In.
18. The system of claim 15 , wherein the gas-upgrading catalyst comprises one or more metal modified MFI type zeolites.
19. The system of claim 18 , wherein the metal modified MFI type zeolites include one or more metals selected from the group consisting of: Ga, Zn, In, Mo, W, Cr, Pt, Pd, Rh, Ru, Au, and Ir.
20. The system of claim 15 , wherein a sequence of catalysts is determined by renewable fuel yield or by temperature of devolatization of biomass components.