Method for making renewable fuels
View Patent ↗Multiple catalytic processing stations enable a method for producing volatile gas streams from biomass decomposition at discrete increasing temperatures. These catalytic processing stations can be programmed to maximize conversion of biomass to useful renewable fuel components based on input feedstock and desired outputs.
1. A method for converting biomass to renewable fuels, comprising the steps of:
(a) providing a device containing a number of processing stations (N) and a series of catalysts;
(b) subjecting biomass within a processing station to a first programmable operating temperature (T) to produce a first volatile and a first non-volatile component;
(c) contacting the first volatile component with an aromatization catalyst to produce a first product which on cooling to a temperature of 1-20° C. produces a second volatile component, a first renewable fuel and water;
(d) subjecting said first non-volatile component within a processing station different from (b) to a second programmable operating temperature (T+ΔT) to produce a third volatile and a second non-volatile component;
(e) contacting the third volatile component with an aromatization catalyst to produce a second product which on cooling to a temperature of 1-20° C. produces a fourth volatile component, a second renewable fuel and water.
2. The method of claim 1 , wherein the processing station of step (b) is programmable such that the processing station temperature can be incremented by a programmable increment (ΔT), and wherein steps (b) and (d) are conducted in the same processing station.
3. The method of claim 1 , wherein steps (b) and (d) are conducted in different processing stations within the device of step (a).
4. The method of claim 1 , wherein the first programmable operating temperature (T) is less than about 300° C.
5. The method of claim 1 , wherein the second programmable operating temperature (T+ΔT) is less than about 300° C.
6. The method of claim 1 , wherein the programmable operating temperature (T) is less than the second programmable operating temperature (T+ΔT).
7. The method of claim 1 , further comprising recovering the first renewable fuel.
8. The method of claim 1 , further comprising contacting the second volatile component with a gas-upgrading catalyst to produce a third product which on cooling to a temperature of 1-20° C. produces a fourth volatile component, a third renewable fuel and water.
9. The method of claim 8 , further comprising recovering the third renewable fuel.
10. The method of claim 8 , further comprising subjecting the fourth volatile component to at least one of the group consisting of: other processing stations, a dehydration catalyst, an aromatization catalyst, a gas-upgrading catalyst, and a combustion gas treatment plant.
11. A method for converting biomass to renewable fuels, comprising the steps of:
(a) providing a device containing a number of processing stations (N) and a series of catalysts;
(b) subjecting hemicellulose-rich biomass within a processing station to a first programmable operating temperature (T) to produce a first volatile and a first non-volatile component;
(c) contacting the first volatile component with an aromatization catalyst to produce a first product which on cooling to a temperature of 0-5° C. produces a second volatile component, a first renewable fuel and water;
(d) subjecting said first non-volatile component within a processing station different from (b) to a second programmable operating temperature (T+ΔT) to produce a third volatile and a second non-volatile component;
(e) contacting the third volatile component with an aromatization catalyst to produce a second product which on cooling to a temperature of 0-5° C. produces a fourth volatile component, a second renewable fuel and water.
12. The method of claim 11 , wherein the processing station of step (b) is programmable such that the processing station temperature can be incremented by a programmable increment (ΔT), and wherein steps (b) and (d) are conducted in the same processing station.
13. The method of claim 11 , wherein steps (b) and (d) are conducted in different processing stations within the device of step (a).
14. The method of claim 11 , wherein the first programmable operating temperature (T) is between about 300-500° C.
15. The method of claim 11 , wherein the second programmable operating temperature (T+ΔT) is between about 300-500° C.
16. The method of claim 11 , wherein the programmable operating temperature (T) is less than the second programmable operating temperature (T+ΔT).
17. The method of claim 11 , further comprising recovering the first renewable fuel.
18. The method of claim 11 , further comprising contacting the second volatile component with a gas-upgrading catalyst to produce a third product which on cooling to a temperature of 0-5° C. produces a fourth volatile component, a third renewable fuel and water.
19. The method of claim 18 , further comprising recovering the third renewable fuel.
20. The method of claim 18 , further comprising routing the fourth volatile component to at least one of the group consisting of: other processing stations, a dehydration catalyst, an aromatization catalyst, a gas-upgrading catalyst, or a combustion gas treatment plant.
21. A method for converting biomass to renewable fuels, comprising the steps of:
(a) providing a device containing a number of processing stations (N) and a series of catalysts;
(b) subjecting lignin-rich biomass within a processing station to a first programmable operating temperature (T) to produce a first volatile and a first non-volatile component;
(c) contacting the first volatile component with an aromatization catalyst to produce a first product which on cooling to a temperature of 2-20° C. produces a second volatile component, a first renewable fuel and water;
(d) subjecting said first non-volatile component within a processing station different from (b) to a second programmable operating temperature (T+ΔT) to produce a third volatile and a second non-volatile component;
(e) contacting the third volatile component with an aromatization catalyst to produce a second product which on cooling to a temperature of 2-20° C. produces a fourth volatile component, a second renewable fuel and water.
22. The method of claim 21 , wherein the processing station of step (b) is programmable such that the processing station temperature can be incremented by a programmable increment (ΔT), and wherein steps (b) and (d) are conducted in the same processing station.
23. The method of claim 21 , wherein steps (b) and (d) are conducted in different processing stations within the device of step (a).
24. The method of claim 21 , wherein the first programmable operating temperature (T) is greater than about 500° C.
25. The method of claim 21 , wherein the second programmable operating temperature (T+ΔT) is greater than about 500° C.
26. The method of claim 21 , wherein the programmable operating temperature (T) is less than the second programmable operating temperature (T+ΔT).
27. The method of claim 21 , further comprising recovering the first renewable fuel.
28. The method of claim 21 , further comprising contacting the second volatile component with a gas-upgrading catalyst to produce a third product which on cooling to a temperature of 0-5° C. produces a fourth volatile component, a third renewable fuel and water.
29. The method of claim 28 , further comprising recovering the third renewable fuel.
30. The method of claim 28 , further comprising contacting the fourth volatile component with a gas-upgrading catalyst to produce an fourth product which on cooling to a temperature of 0-5° C. produces a fifth volatile component, a fourth renewable fuel and water.
31. The method of claim 30 , further comprising recovering the fourth renewable fuel.
32. The method of claim 30 , further comprising subjecting the fifth volatile component to at least one of the group consisting of: other processing stations, a dehydration catalyst, an aromatization catalyst, a gas-upgrading catalyst, and a combustion gas treatment plant.