Process for removing contaminants from gas streams
View Patent ↗The present invention provides for process for inhibiting the levels of nitrogen oxides in process gas streams from sulfuric acid regeneration and sulfuric acid production plants. Partial oxidation of the nitrogen oxides is achieved by feeding a sub stoichiometric amount of ozone as to nitrogen oxides to the process gas stream.
1. A method for removing contaminants from a process gas stream in a sulfuric acid production process comprising the steps: a) directing the process gas stream to a particulate scrubber; b) contacting the process gas stream with ozone at less than stoichiometric amounts; c) scrubbing partially oxidized nitrogen oxides in the particulate scrubber; d) establishing conditions under which nitrous acid is formed and absorbed; e) feeding a compound selected from the group consisting of urea, ammonia and a compound that can provide an ammonical radical to the aqueous phase of the particulate scrubber; e) directing the process gas stream to a gas dryer; and f) recovering the process gas stream.
2. The method as claimed in claim 1 wherein said contaminants are selected from the group consisting of sulfur oxides and nitrogen oxides.
3. The method as claimed in claim 1 wherein said less than stoichiometric amount is one-third the amount of ozone necessary to oxidize nitrogen oxides.
4. The method as claimed in claim 1 wherein said conditions under which nitrous acid is formed and absorbed are in the particulate scrubber.
5. The method as claimed in claim 1 wherein said partial oxidation is performed in a process gas stream selected from the group consisting of upstream, within and downstream of a particulate scrubber.
6. The method as claimed in claim 1 wherein said process gas stream and ozone are mixed prior to the process gas stream entering the particulate scrubber.
7. The method as claimed in claim 1 wherein said process gas stream is quenched prior to mixing with ozone.
8. The method as claimed in claim 1 wherein air is injected into said process gas stream prior to entering said gas dryer.
9. The method as claimed in claim 1 wherein said absorption of nitrous acid is in a neutral or acidic medium.
10. The method as claimed in claim 1 further comprising a different gas-liquid contacting device with aqueous scrubbing medium.
11. The method as claimed in claim 1 wherein said recovered process gas stream is oxidized using catalytic converters and then fed to a sulfuric acid absorption tower.
12. The method as claimed in claim 1 wherein said ozone is up to 10 weight percent ozone in oxygen.
13. A method for removing contaminants from a process gas stream from a sulfuric acid production process comprising the steps: a) feeding the process gas stream to a particulate scrubber; b) introducing ozone into the process gas stream at less than stoichiometric amounts with the oxides of nitrogen and scrubbing the partially oxidized oxides of nitrogen in the scrubber; c) establishing conditions in the scrubber to facilitate the formation of nitrous acid; d) feeding a compound selected from the group consisting of urea, ammonia and a compound that can provide an ammonical radical to the aqueous phase of the particulate scrubber; e) absorbing nitrous acid in a neutral or acidic medium; and f) recovering the process gas stream.
14. The method as claimed in claim 13 wherein said contaminants are selected from the group consisting of sulfur oxides and nitrogen oxides.
15. The method as claimed in claim 13 wherein said less than stoichiometric amount is one-third the amount of ozone necessary to oxidize nitrogen oxides.
16. The method as claimed in claim 13 wherein said conditions under which nitrous acid is formed and absorbed are in the particulate scrubber.
17. The method as claimed in claim 13 wherein said partial oxidation is performed in a process gas stream selected from the group consisting of upstream, within and downstream of a particulate scrubber.
18. The method as claimed in claim 13 wherein said process gas stream and ozone are mixed prior to the process gas stream entering the particulate scrubber.
19. The method as claimed in claim 13 wherein said process gas stream is quenched prior to mixing with ozone.
20. The method as claimed in claim 13 wherein air is injected into said process gas stream prior to entering said gas dryer.
21. The method as claimed in claim 13 wherein said absorption of nitrous acid is in a neutral or acidic medium.
22. The method as claimed in claim 13 further comprising a different gas-liquid contacting device with aqueous scrubbing medium.
23. The method as claimed in claim 13 wherein said recovered process gas stream is fed to a sulfuric acid absorption tower.
24. The method as claimed in claim 13 wherein said ozone is up to 10 weight percent ozone in oxygen.