Nuclear power plant, method of forming corrosion-resistant coating therefor, and method of operating nuclear power plant
View Patent ↗In a nuclear power plant, a corrosion-resistant oxide film on a surface of the metal component of a reactor structure is exposed to a high-temperature water, the corrosion-resistant oxide film containing an oxide having a property of a P-type semiconductor, and a catalytic substance having a property of an N-type semiconductor is deposited on the oxide film. The oxide film maintains the property of the P-type semiconductor.
1. A method of forming a corrosion-resistant coating, the method comprising:
controlling a water chemistry inside a reactor to have a feedwater hydrogen concentration of 1.0 ppm or less with a hydrogen injection device, to deposit an oxide film having a property of a P-type semiconductor in a reducing atmosphere or converting an existing oxide film on a surface of a metal component of a reactor structure exposed to high-temperature water; and
depositing, on the oxide film, a catalytic substance having a property of an N-type semiconductor, thereby forming a corrosion-resistant coating having a p-n junction,
wherein the oxide film of the corrosion-resistant coating retains the property of the P-type semiconductor.
2. The method of claim 1 , wherein the reducing atmosphere comprises high-temperature water having a dissolved hydrogen concentration of 30 ppb or more.
3. The method of claim 1 , wherein the reducing atmosphere has a feedwater hydrogen concentration of 0.3 ppm.
4. The method of claim 1 , wherein the reducing atmosphere is adjusted such that the corrosion potential is −0.4 V(SHE).
5. The method of claim 1 , wherein the oxide film having the property of the P-type semiconductor is formed on the surface of the metal component by controlling the ambient aquatic environment to convert an existing oxide film on the metal surface to the oxide having the property of the P-type semiconductor.
6. The method of claim 1 , wherein the oxide film having the property of the P-type semiconductor is formed on the surface of the metal component by removing an existing oxide film on the metal surface in a reducing atmosphere having a feedwater hydrogen concentration of 0.3 ppm and a corrosion potential of −0.4 V(SHE) by removing and converting an exposed surface portion of the metal component into the oxide film having the property of the P-type semiconductor.
7. The method of claim 1 , wherein the catalytic substance on the oxide film is deposited through a spraying process, a flame spraying process or a water chemical injection process.
8. The method of claim 1 , wherein the oxide film is Fe 3 O 4 .
9. The method of claim 1 , wherein the catalytic substance is TiO 2 .
10. The method of claim 8 , wherein the catalytic substance is TiO 2 .
11. The method of claim 1 , wherein the oxide film has a thickness of 0.1 μm or less.
12. The method of claim 1 , wherein the amount of the catalytic substance deposited on the oxide film is at least 100 μg/cm 2 .
13. The method of claim 9 , wherein the amount of the catalytic substance deposited on the oxide film is at least 100 μg/cm 2 .