IP Library Granted Patent US 8,753,946
Granted Patent B2
US 8,753,946 · App. 13/366,279 · Granted Jun 17, 2014

Method of manufacturing a light emitting, photovoltaic or other electronic apparatus and system

Inventors: William Johnstone Ray (Fountain Hills, AZ); Mark David Lowenthal (Gilbert, AZ); Neil O. Shotton (Tempe, AZ); Richard A. Blanchard (Los Altos, CA); Mark Allan Lewandowski (North Port, FL); Kirk A. Fuller (Madison, AL); Donald Odell Frazier (Huntsville, AL)
Assignees: NthDegree Technologies Worldwide Inc; NASA, an agency of the United States
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Quick Facts
Patent No.
US 8,753,946
App. No.
13/366,279
Granted
Jun 17, 2014
Kind
B2
Abstract

The present invention provides a method of manufacturing an electronic apparatus, such as a lighting device having light emitting diodes (LEDs) or a power generating device having photovoltaic diodes. The exemplary method includes depositing a first conductive medium within a plurality of channels of a base to form a plurality of first conductors; depositing within the plurality of channels a plurality of semiconductor substrate particles suspended in a carrier medium; forming an ohmic contact between each semiconductor substrate particle and a first conductor; converting the semiconductor substrate particles into a plurality of semiconductor diodes; depositing a second conductive medium to form a plurality of second conductors coupled to the plurality of semiconductor diodes; and depositing or attaching a plurality of lenses suspended in a first polymer over the plurality of diodes. In various embodiments, the depositing, forming, coupling and converting steps are performed by or through a printing process.

Claims (57)

1. A method of manufacturing an electronic apparatus, the method comprising:

depositing a first conductive medium on a base to form at least one first conductor;

depositing a plurality of semiconductor substrate particles suspended in a carrier medium;

forming an ohmic contact between the plurality of semiconductor substrate particles and the at least one first conductor;

forming a pn junction in each semiconductor substrate particle by depositing a dopant onto the plurality of semiconductor substrate particles and annealing the plurality of semiconductor substrate particles to form a plurality of semiconductor diodes;

depositing a second conductive medium to form at least one second conductor coupled to the plurality of semiconductor diodes; and

depositing a plurality of substantially spherical lenses suspended in a first polymer over the plurality of diodes, the plurality of substantially spherical lenses having at least a first index of refraction and the first polymer having at least a second, different index of refraction.

2. The method of claim 1 , wherein the plurality of semiconductor diodes are substantially spherical, substantially toroidal, substantially cylindrical, substantially faceted, substantially rectangular, substantially flat, or substantially elliptical.

3. The method of claim 1 , wherein the plurality of semiconductor diodes are substantially spherical, and wherein a ratio of a mean diameter of the plurality of substantially spherical lenses to a mean diameter of the plurality of semiconductor diodes is substantially about five to one (5:1).

4. The method of claim 1 , wherein the plurality of semiconductor diodes are substantially spherical, and wherein a ratio of a mean diameter of the plurality of substantially spherical lenses to a mean diameter of the plurality of semiconductor diodes is between about ten to one (10:1) and two to one (2:1).

5. The method of claim 1 , wherein the plurality of semiconductor diodes are substantially spherical, and wherein the comparative size or spacing of the plurality of substantially spherical lenses provide a mode coupling to the plurality of semiconductor diodes.

6. The method of claim 1 , wherein a mean diameter or length of the plurality of semiconductor diodes is greater than about twenty (20) microns and less than about forty (40) microns.

7. The method of claim 1 , wherein the step of depositing the plurality of substantially spherical lenses suspended in the first polymer further comprises attaching a prefabricated layer to the plurality of semiconductor diodes, the prefabricated layer comprising the plurality of substantially spherical lenses suspended in the first polymer.

8. The method of claim 1 , wherein the plurality of semiconductor substrate particles comprise gallium nitride, gallium arsenide, or silicon.

9. The method of claim 8 , wherein the first conductive medium comprises a conductive ink or a conductive polymer.

10. The method of claim 1 , further comprising:

partially curing the first conductive medium;

wherein the step of forming an ohmic contact further comprises fully curing the first conductive medium.

11. The method of claim 1 , wherein the step of depositing the first conductive medium comprises sputtering, coating, vapor depositing or electroplating a metal, a metal alloy, or a combination of metals.

12. The method of claim 1 , wherein the carrier medium is a reactive carrier medium and wherein the step of forming an ohmic contact further comprises:

removing the reactive carrier medium; and

curing or re-curing the first conductive medium.

13. The method of claim 1 , wherein the carrier medium is an anisotropic carrier medium and wherein the step of forming an ohmic contact further comprises:

compressing the plurality of semiconductor substrate particles suspended in the anisotropic conductive medium.

14. The method of claim 1 , wherein the step of forming an ohmic contact further comprises:

annealing or alloying the plurality of semiconductor substrate particles with the at least one first conductor.

15. The method of claim 1 , wherein the annealing or alloying is laser or thermal annealing or alloying.

16. The method of claim 1 , wherein the dopant material is a substrate liquid or film or a dopant element or compound suspended in a carrier.

17. The method of claim 1 , wherein the dopant is deposited on a first, upper portion of the plurality of semiconductor substrate particles and wherein about fifteen percent to fifty-five percent of a surface of each semiconductor diode of substantially all of the plurality of semiconductor diodes has a layer or region having a first majority carrier or dopant and the remaining diode substrate has a second majority carrier or dopant.

18. The method of claim 1 , wherein the resulting plurality of semiconductor diodes are light emitting diodes or photovoltaic diodes.

19. The method of claim 1 , further comprising:

depositing a plurality of third conductors over or within the plurality of second conductors.

20. The method of claim 1 , wherein the base further comprises a Bragg reflector or a reflective plastic or polyester coating.

21. The method of claim 1 , wherein the base further comprises:

a plurality of conductive vias extending between a first side and a second side of the base and correspondingly coupled at the first side to the plurality of first conductors; and

a conductive backplane coupled to the plurality of conductive vias and coupled to or integrated with the second side of the base.

22. The method of claim 1 , further comprising:

depositing a plurality of inorganic dielectric particles suspended with a photoinitiator compound in a second polymer or resin to form a plurality of insulators correspondingly coupled to each of the plurality of diodes.

23. The method of claim 1 , wherein the base comprises at least one of the following: paper, coated paper, plastic coated paper, embossed paper, fiber paper, cardboard, poster paper, poster board, wood, plastic, rubber, fabric, glass, and/or ceramic.

24. The method of claim 1 , wherein the step of depositing a second conductive medium further comprises:

depositing an optically transmissive conductor or conductive compound suspended in a polymer, resin or other media.

25. The method of claim 24 , wherein the optically transmissive conductor or conductive compound suspended in a polymer, resin or other media further comprises at least one of the following: carbon nanotubes, antimony tin oxide, indium tin oxide, or polyethylene-dioxithiophene.

26. The method of claim 1 , wherein the plurality of substantially spherical lenses comprise borosilicate glass or polystyrene latex.

27. The method of claim 1 , further comprising:

attaching an interface for insertion into a standardized lighting socket.

28. The method of claim 27 , wherein the interface is compatible with an E12, E14, E26, E27, or GU-10 lighting standard.

29. The method of claim 27 , wherein the interface is compatible with a standard Edison-type lighting socket.

30. The method of claim 27 , wherein the interface is compatible with a standard fluorescent-type lighting socket.

31. The method of claim 1 , wherein the deposition steps further comprise at least one of the following types of deposition: printing, coating, rolling, spraying, layering, sputtering, lamination, screen printing, inkjet printing, electro-optical printing, electroink printing, photoresist printing, thermal printing, laser jet printing, magnetic printing, pad printing, flexographic printing, hybrid offset lithography, or Gravure printing.

32. A method of manufacturing an electronic apparatus, the method comprising:

printing a first conductive medium within a plurality of cavities of a base to form a plurality of first conductors;

printing within the plurality of cavities a plurality of substantially spherical substrate particles suspended in a carrier medium;

printing a dopant on first, upper portion the plurality of substantially spherical semiconductor substrate particles;

annealing the doped plurality of substantially spherical semiconductor substrate particles to form a plurality of substantially spherical diodes having at least a partially hemispherical shell pn junction;

printing an electrically insulating medium over a first portion of the plurality of substantially spherical diodes;

printing a second conductive medium over a second portion of the plurality of substantially spherical diodes to form a plurality of second conductors; and

printing a plurality of substantially spherical lenses suspended in a first polymer over the plurality of substantially spherical diodes, the plurality of substantially spherical lenses having at least a first index of refraction and the first polymer having at least a second, different index of refraction.

Assignments (5)
SECURITY INTEREST Recorded Mar 25, 2016
From: NTHDEGREE TECHNOLOGIES WORLDWIDE INC
To: PLANNING FOR SUCCESS LLC
Reel/Frame 038260/0049 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2014
From: FRAZIER, DONALD ODELL
To: UNITED STATES GOVERNMENT, AS REPRESENTED BY THE ADMINISTRATOR OF THE NATIONAL AERONAUTICS AND SPACE ADMINSTRATION
Reel/Frame 032865/0688 →
TERMINATION OF SECURITY AGREEMENT Recorded Mar 25, 2014
From: MILLER INVESTMENT GROUP, LLC
To: NTHDEGREE TECHNOLOGIES WORLDWIDE INC.
Reel/Frame 032520/0108 →
SECURITY INTEREST Recorded May 1, 2012
From: NTHDEGREE TECHNOLOGIES WORLDWIDE INC
To: MILLER INVESTMENT GROUP, LLC; DACURO, LLC; JUST INK, LLC; JOSEPH A. NATHAN, INDIVIDUALLY AND AS TRUSTEE OF THE JOSEPH A. NATHAN LIVING TRUST; INSIGHT 2811 TECHNOLOGY ENTREPRENEUR FUND, LP; ALPHA CAPITAL, INC.; LOLE, CHRISTOPHER; PALISADE CONCENTRATED EQUITY PARTNERSHIP II, LP; MARGULIS, BRUCE A.; BIG BASIN PARTNERS LP; TIMARK LP; RICHARD A. BLANCHARD TRUSTEE OF THE RICHARD & ESTHER BLANCHARD 1990 TRUST 10/01/90; INSIGHT TECHNOLOGY CAPITAL PARTNERS, LP; BYRNE, ARTHUR; JAMES C. HOLMES JR., AS TRUSTEE OF THE JAMES C. HOLMES JR. TRUST, UTA DATED JANUARY 30, 1986, AS AMENDED; GORDON RAINS; INDIAN GROVE PRODUCTIONS; SIMONS, PETER; CHYE KIAT ANG; ROBINSON, PETER; JOSEPH A. NATHAN IRA ROLLOVER, MS & CO., CUSTODIAN; CORR INVESTMENTS LLC; DUNN INVESTMENT COMPANY INC; MIG, LLC; RUBAIYAT TRADING COMPANY, LTD.; TIMBERLINE HOLDINGS LLC; TIMBERLINE PRIVATE EQUITY INVESTMENTS LLC; DOLLY RIDGE LLC; FOSTER, A. KEY; CHARLES AND LYNDRA DANIEL, JTWROS; HARSH, MILTON; G. RUFFNER PAGE, JR.; PORTER, MARGARET M.; WHITE, JAMES H. III; PRICE, JOSEPH T.; P.C. JACKSON, JR.; RUSSELL, BENJAMIN; MILAGRO DE LADERA, L.P.; OAKWORTH CAPITAL BANK, AS TRUSTEE FOR RICHARD H. MONK, JR., INDIVIDUAL RETIREMENT ACCOUNT; SOCOLOF, JOSEPH D.; THOMPSON INVESTMENT COMPANY, LLC; LOGAN, GREG P.; JONES FOUNDATION III, LLC, THE; GORRIE, M. JAMES; JOHN STEINER TRUST U/W DOROTHY L. STEINER; STEWART MOTT DANSBY REVOCABLE TRUST
Reel/Frame 028146/0908 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 16, 2012
From: RAY, WILLIAM JOHNSTONE; LOWENTHAL, MARK DAVID; SHOTTON, NEIL O.; BLANCHARD, RICHARD A.; LEWANDOWSKI, MARK ALLAN; FULLER, KIRK A.
To: NTHDEGREE TECHNOLOGIES WORLDWIDE INC
Reel/Frame 027879/0001 →
Continuity (8)
Division 12560371 · Sep 15, 2009
Continuation In Part 12560334 · Sep 15, 2009
Continuation In Part 12560340 · Sep 15, 2009
Continuation In Part 12560355 · Sep 15, 2009
Continuation In Part 12560364 · Sep 15, 2009
Continuation In Part 11756619 · May 31, 2007
Continuation In Part 11756616 · May 31, 2007
Related Publication 20120178194A1 · Jul 12, 2012