IP Library Granted Patent US 8,753,947
Granted Patent B2
US 8,753,947 · App. 13/366,281 · Granted Jun 17, 2014

Method of manufacturing a light emitting, photovoltaic or other electronic apparatus and system

Inventors: William Johnstone Ray (Fountain Hills, AZ); Mark David Lowenthal (Gilbert, AZ); Neil O. Shotton (Tempe, AZ); Richard A. Blanchard (Los Altos, CA); Mark Allan Lewandowski (North Port, FL); Kirk A. Fuller (Madison, AL); Donald Odell Frazier (Huntsville, AL)
Assignees: NthDegree Technologies Worldwide Inc; NASA
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Quick Facts
Patent No.
US 8,753,947
App. No.
13/366,281
Granted
Jun 17, 2014
Kind
B2
Abstract

The present invention provides a method of manufacturing an electronic apparatus, such as a lighting device having light emitting diodes (LEDs) or a power generating device having photovoltaic diodes. The exemplary method includes depositing a first conductive medium within a plurality of channels of a base to form a plurality of first conductors; depositing within the plurality of channels a plurality of semiconductor substrate particles suspended in a carrier medium; forming an ohmic contact between each semiconductor substrate particle and a first conductor; converting the semiconductor substrate particles into a plurality of semiconductor diodes; depositing a second conductive medium to form a plurality of second conductors coupled to the plurality of semiconductor diodes; and depositing or attaching a plurality of lenses suspended in a first polymer over the plurality of diodes. In various embodiments, the depositing, forming, coupling and converting steps are performed by or through a printing process.

Claims (79)

1. A method of manufacturing an electronic apparatus, the method comprising:

depositing a first conductive medium within a plurality of channels of a base to form a plurality of first conductors;

depositing within the plurality of channels a plurality of semiconductor substrate particles suspended in a carrier medium;

forming an ohmic contact between each semiconductor substrate particle of the plurality of semiconductor substrate particles and a first conductor of the plurality of first conductors;

converting the plurality of semiconductor substrate particles into a plurality of semiconductor diodes, wherein about fifteen percent to fifty-five percent of a surface of each diode of substantially all of the plurality of diodes has a penetration layer or region having a first majority carrier or dopant and the remaining diode substrate has a second majority carrier or dopant;

depositing a second conductive medium to form a plurality of second conductors coupled to the plurality of semiconductor diodes; and

depositing a plurality of lenses.

2. The method of claim 1 , wherein the plurality of semiconductor diodes have shapes selected from the group consisting of: substantially spherical, substantially toroidal, substantially cylindrical, substantially faceted, substantially rectangular, substantially flat, substantially elliptical, and mixtures or combinations thereof.

3. The method of claim 1 , wherein the plurality of lenses have shapes selected from the group consisting of: substantially spherical, substantially hemispherical, substantially faceted, substantially elliptical, substantially oblong, substantially cubic, substantially prismatic, substantially trapezoidal, substantially triangular, substantially pyramidal, and mixtures or combinations thereof.

4. The method of claim 1 , wherein the plurality of semiconductor diodes and the plurality of lenses are substantially spherical, and wherein a ratio of a mean diameter of the plurality of lenses to a mean diameter of the plurality of semiconductor diodes is substantially about five to one (5:1).

5. The method of claim 1 , wherein the plurality of semiconductor diodes and the plurality of lenses are substantially spherical, and wherein a ratio of a mean diameter of the plurality of lenses to a mean diameter of the plurality of semiconductor diodes is between about ten to one (10:1) and two to one (2:1).

6. The method of claim 1 , wherein the plurality of semiconductor diodes and the plurality of lenses are substantially spherical, and wherein the comparative size or spacing of the plurality of substantially spherical lenses provide a mode coupling to the plurality of diodes.

7. The method of claim 1 , wherein a mean diameter or length of the plurality of semiconductor diodes is greater than about twenty (20) microns and less than about forty (40) microns.

8. The method of claim 1 , wherein the step of depositing the plurality of lenses further comprises attaching a prefabricated lens layer to the plurality of semiconductor diodes, the prefabricated lens layer comprising the plurality of lenses.

9. The method of claim 1 , wherein the plurality of semiconductor substrate particles comprise at least one semiconductor selected from the group consisting of: gallium nitride, gallium arsenide, silicon, and combinations thereof.

10. The method of claim 1 , further comprising:

partially curing the first conductive medium;

wherein the step of forming an ohmic contact further comprises fully curing the first conductive medium.

11. The method of claim 10 , wherein the first conductive medium comprises a conductive ink or a conductive polymer.

12. The method of claim 1 , wherein the step of depositing the first conductive medium comprises at least one deposition process selected from the group consisting of: sputtering, coating, vapor depositing, electroplating, and combinations thereof; and wherein the first conductive medium is at least one conductive medium selected from the group consisting of: a metal, a metal alloy, and combinations thereof.

13. The method of claim 1 , wherein the carrier medium is a reactive carrier medium and wherein the step of forming an ohmic contact further comprises:

removing the reactive carrier medium; and

curing or re-curing the first conductive medium.

14. The method of claim 1 , wherein the carrier medium is an anisotropic carrier medium and wherein the step of forming an ohmic contact further comprises:

compressing the plurality of semiconductor substrate particles suspended in the anisotropic conductive medium.

15. The method of claim 1 , wherein the step of forming an ohmic contact further comprises:

annealing or alloying the plurality of semiconductor substrate particles within the plurality of channels.

16. The method of claim 1 , wherein the plurality of channels are spaced-apart and substantially parallel.

17. The method of claim 1 , wherein the plurality of channels are at least partially hemispherically-shaped and are disposed in an array.

18. The method of claim 1 , wherein the plurality of channels are spaced-apart and least partially parabolic.

19. The method of claim 1 , wherein the base further comprises a plurality of angled ridges.

20. The method of claim 1 , wherein the plurality of spaced-apart channels further comprise a plurality of integrally formed projections or supports.

21. The method of claim 20 , wherein the plurality of first conductors are coupled to the plurality of integrally formed projections or supports within the plurality of spaced-apart channels and wherein the step of forming an ohmic contact further comprises:

annealing, or alloying, or chemically coupling the plurality of substrate particles to the plurality of first conductors.

22. The method of claim 1 , wherein the step of converting the plurality of semiconductor substrate particles into the plurality of semiconductor diodes further comprises:

forming a pn junction in each semiconductor substrate particle by depositing a dopant material onto the plurality of semiconductor substrate particles and annealing or alloying the dopant material with the plurality of substrate particles.

23. The method of claim 22 , wherein the annealing or alloying is laser or thermal annealing or alloying.

24. The method of claim 22 , wherein the dopant material is a substrate liquid or film or a dopant element or compound suspended in a carrier.

25. The method of claim 22 , wherein the pn junction is formed at least a partially hemispherical shell or cap.

26. The method of claim 22 , wherein the dopant material is deposited on a first, upper portion of the plurality of substrate particles to form the plurality of diodes.

27. The method of claim 22 , wherein the resulting plurality of diodes are light emitting diodes or photovoltaic diodes.

28. The method of claim 1 , further comprising:

depositing a plurality of third conductors over or within the plurality of second conductors.

29. The method of claim 1 , wherein the base further comprises a Bragg reflector or a reflective plastic or polyester coating.

30. The method of claim 1 , wherein the base further comprises:

a plurality of conductive vias extending between a first side and a second side of the base and correspondingly coupled at the first side to the plurality of first conductors; and

a conductive backplane coupled to the plurality of conductive vias and coupled to or integrated with the second side of the base.

31. The method of claim 1 , further comprising:

depositing a plurality of inorganic dielectric particles suspended with a photoinitiator compound in a polymer or resin to form a plurality of insulators correspondingly coupled to each of the plurality of diodes.

32. The method of claim 1 , wherein the base comprises at least one material selected from the group consisting of: paper, coated paper, plastic coated paper, embossed paper, fiber paper, cardboard, poster paper, poster board, wood, plastic, rubber, fabric, glass, ceramic, and combinations thereof.

33. The method of claim 1 , wherein the step of depositing a second conductive medium further comprises:

depositing an optically transmissive conductor or conductive compound suspended in a polymer, resin or other media.

34. The method of claim 33 , wherein the optically transmissive conductor or conductive compound suspended in a polymer, resin or other media further comprises at least one of the following: carbon nanotubes, antimony tin oxide, indium tin oxide, or polyethylene-dioxithiophene.

35. The method of claim 1 , wherein the depositing and converting steps are performed by or through a printing process.

36. The method of claim 1 , wherein the plurality of lenses comprise borosilicate glass or polystyrene latex.

37. The method of claim 1 , further comprising:

attaching an interface for insertion into a standardized lighting socket.

38. The method of claim 37 , wherein the interface is compatible with an E12, E14, E26, E27, or GU-10 lighting standard.

39. The method of claim 37 , wherein the interface is compatible with a standard Edison-type lighting socket.

40. The method of claim 37 , wherein the interface is compatible with a standard fluorescent-type lighting socket.

41. The method of claim 1 , wherein the plurality of lenses have at least a first index of refraction and are suspended in a polymer, wherein the polymer has at least a second, different index of refraction.

42. The method of claim 1 , wherein the deposition steps further comprise at least one deposition process selected from the group consisting of: printing, coating, rolling, spraying, layering, sputtering, lamination, screen printing, inkjet printing, electro-optical printing, electroink printing, photoresist printing, thermal printing, laser jet printing, magnetic printing, pad printing, flexographic printing, hybrid offset lithography, Gravure printing, and combinations thereof.

43. The method of claim 1 , wherein the step of depositing the first conductive medium further comprises coating the plurality of channels with the first conductive medium and removing excess first conductive medium by scraping a first surface of the base using a doctor blade.

44. The method of claim 1 , wherein the step of depositing the plurality of semiconductor substrate particles further comprises coating the plurality of channels with the plurality of semiconductor substrate particles suspended in a carrier medium and removing excess plurality of spherical substrate particles by scraping a first surface of the base using a doctor blade.

45. A method of manufacturing an electronic apparatus, the method comprising:

depositing a first conductive medium on a base to form at least one first conductor;

depositing a plurality of semiconductor substrate particles suspended in a liquid or gel carrier medium, wherein the plurality of semiconductor substrate particles are inorganic and substantially spherical;

forming one or more ohmic contacts between at least some semiconductor substrate particles of the plurality of semiconductor substrate particles and the at least one first conductor;

converting at least some semiconductor substrate particles of the plurality of semiconductor substrate particles into a plurality of semiconductor diodes, wherein the plurality of semiconductor diodes are substantially spherical and wherein about fifteen percent to fifty-five percent of a surface of each semiconductor diode of substantially all of the plurality of semiconductor diodes has a penetration layer or region having a first majority carrier or dopant and the remaining diode substrate has a second majority carrier or dopant;

depositing a second conductive medium to form a plurality of second conductors coupled to the plurality of semiconductor diodes; and

depositing a plurality of lenses suspended in a first polymer over the plurality of semiconductor diodes, wherein the plurality of lenses are substantially spherical and have at least a first index of refraction and wherein the first polymer, when solidified or cured, has at least a second, different index of refraction.

46. A method of manufacturing an electronic apparatus, the method comprising:

depositing a first conductive medium on a base to form at least one first conductor;

depositing a plurality of semiconductor substrate particles suspended in a liquid or gel carrier medium, wherein the plurality of semiconductor substrate particles are inorganic and substantially spherical;

forming one or more ohmic contacts between at least some semiconductor substrate particles of the plurality of semiconductor substrate particles and the at least one first conductor;

depositing a dopant material onto the plurality of semiconductor substrate particles;

converting at least some semiconductor substrate particles of the plurality of semiconductor substrate particles into a plurality of semiconductor diodes, wherein the plurality of semiconductor diodes are substantially spherical and wherein about fifteen percent to fifty-five percent of a surface of each semiconductor diode of substantially all of the plurality of semiconductor diodes has a penetration layer or region having a first majority carrier or dopant and the remaining diode substrate has a second majority carrier or dopant;

depositing a second conductive medium to form a plurality of second conductors coupled to the plurality of semiconductor diodes, wherein the second conductive medium is substantially optically transmissive when solidified or cured; and

depositing a plurality of lenses suspended in a first polymer over the plurality of semiconductor diodes, wherein the plurality of lenses are substantially spherical and have at least a first index of refraction and wherein the first polymer, when solidified or cured, has at least a second, different index of refraction.

Assignments (5)
SECURITY INTEREST Recorded Mar 25, 2016
From: NTHDEGREE TECHNOLOGIES WORLDWIDE INC
To: PLANNING FOR SUCCESS LLC
Reel/Frame 038260/0049 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2014
From: FRAZIER, DONALD ODELL
To: UNITED STATES GOVERNMENT, AS REPRESENTED BY THE ADMINISTRATOR OF THE NATIONAL AERONAUTICS AND SPACE ADMINSTRATION
Reel/Frame 032865/0690 →
TERMINATION OF SECURITY AGREEMENT Recorded Mar 25, 2014
From: MILLER INVESTMENT GROUP, LLC
To: NTHDEGREE TECHNOLOGIES WORLDWIDE INC.
Reel/Frame 032520/0108 →
SECURITY INTEREST Recorded May 1, 2012
From: NTHDEGREE TECHNOLOGIES WORLDWIDE INC
To: MILLER INVESTMENT GROUP, LLC; DACURO, LLC; JUST INK, LLC; JOSEPH A. NATHAN, INDIVIDUALLY AND AS TRUSTEE OF THE JOSEPH A. NATHAN LIVING TRUST; INSIGHT 2811 TECHNOLOGY ENTREPRENEUR FUND, LP; ALPHA CAPITAL, INC.; LOLE, CHRISTOPHER; PALISADE CONCENTRATED EQUITY PARTNERSHIP II, LP; MARGULIS, BRUCE A.; BIG BASIN PARTNERS LP; TIMARK LP; RICHARD A. BLANCHARD TRUSTEE OF THE RICHARD & ESTHER BLANCHARD 1990 TRUST 10/01/90; INSIGHT TECHNOLOGY CAPITAL PARTNERS, LP; BYRNE, ARTHUR; JAMES C. HOLMES JR., AS TRUSTEE OF THE JAMES C. HOLMES JR. TRUST, UTA DATED JANUARY 30, 1986, AS AMENDED; GORDON RAINS; INDIAN GROVE PRODUCTIONS; SIMONS, PETER; CHYE KIAT ANG; ROBINSON, PETER; JOSEPH A. NATHAN IRA ROLLOVER, MS & CO., CUSTODIAN; CORR INVESTMENTS LLC; DUNN INVESTMENT COMPANY INC; MIG, LLC; RUBAIYAT TRADING COMPANY, LTD.; TIMBERLINE HOLDINGS LLC; TIMBERLINE PRIVATE EQUITY INVESTMENTS LLC; DOLLY RIDGE LLC; FOSTER, A. KEY; CHARLES AND LYNDRA DANIEL, JTWROS; HARSH, MILTON; G. RUFFNER PAGE, JR.; PORTER, MARGARET M.; WHITE, JAMES H. III; PRICE, JOSEPH T.; P.C. JACKSON, JR.; RUSSELL, BENJAMIN; MILAGRO DE LADERA, L.P.; OAKWORTH CAPITAL BANK, AS TRUSTEE FOR RICHARD H. MONK, JR., INDIVIDUAL RETIREMENT ACCOUNT; SOCOLOF, JOSEPH D.; THOMPSON INVESTMENT COMPANY, LLC; LOGAN, GREG P.; JONES FOUNDATION III, LLC, THE; GORRIE, M. JAMES; JOHN STEINER TRUST U/W DOROTHY L. STEINER; STEWART MOTT DANSBY REVOCABLE TRUST
Reel/Frame 028146/0908 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 16, 2012
From: RAY, WILLIAM JOHNSTONE; LOWENTHAL, MARK DAVID; SHOTTON, NEIL O.; BLANCHARD, RICHARD A.; LEWANDOWSKI, MARK ALLAN; FULLER, KIRK A.
To: NTHDEGREE TECHNOLOGIES WORLDWIDE INC
Reel/Frame 027878/0884 →
Continuity (8)
Continuation 12560371 · Sep 15, 2009
Continuation In Part 12560334 · Sep 15, 2009
Continuation In Part 12560340 · Sep 15, 2009
Continuation In Part 12560355 · Sep 15, 2009
Continuation In Part 12560364 · Sep 15, 2009
Continuation In Part 11756619 · May 31, 2007
Continuation In Part 11756616 · May 31, 2007
Related Publication 20120178195A1 · Jul 12, 2012