IP Library Granted Patent US 8,992,637
Granted Patent B2
US 8,992,637 · App. 13/366,985 · Granted Mar 31, 2015

Remote additive application

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Quick Facts
Patent No.
US 8,992,637
App. No.
13/366,985
Granted
Mar 31, 2015
Kind
B2
Abstract

The present disclosure is directed to the application of additives to a feed material at a location remote from an industrial facility using the feed material.

Claims (26)

1. A method, comprising:

at first location, receiving a treated feed material comprising a combustible, mercury-containing feed material and a halogen-containing additive; and

transporting the treated feed material to a second location, the second location being located discretely from the first location, wherein the treated feed material is combusted at the second location to generate a waste gas comprising mercury and the halogen, the halogen enabling removal of at least most of the mercury from the waste gas.

2. The method of claim 1 , wherein the halogen is one or more of iodine and bromine, wherein the feed material is coal, wherein the first location is a mine site, wherein the second location is a utility site, wherein the halogen is added in addition to any halogen occurring natively in the feed material, and wherein the transportation of the treated feed material is by one or more of rail car, truck, barge and ship.

3. The method of claim 1 , wherein the halogen-containing additive is in the form of an agglomerate comprising a binder, a halogen compound, and a substrate.

4. The method of claim 3 , wherein the substrate is a portion of the feed material.

5. The method of claim 3 , wherein the treated feed material comprises a dust control agent to stabilize the halogen-containing additive during transportation.

6. The method of claim 3 , wherein the treated feed material comprises a freeze control agent to stabilize the halogen-containing additive during transportation.

7. A method, comprising:

receiving, at an industrial facility, a treated feed material comprising a combustible, mercury-containing feed material and a halogen-containing additive, wherein the treated feed material was transported to the industrial facility from a remote location located discretely from the industrial facility; and

combusting, by the industrial facility, the treated feed material to generate a waste gas comprising mercury and the halogen, the halogen enabling removal of at least most of the mercury from the waste gas.

8. The method of claim 7 , wherein the halogen is one or more of iodine and bromine, wherein the feed material is coal, wherein the remote location is a mine site, wherein the industrial facility is a utility power plant, wherein the halogen is added substantially above the level of native halogen in the feed material, and wherein the transportation of the treated feed material is by one or more of rail car, truck, barge and ship.

9. The method of claim 7 , wherein the halogen-containing additive is in the form of an agglomerate comprising a binder, a halogen compound, and a substrate.

10. The method of claim 9 , wherein the substrate is a portion of the feed material.

11. The method of claim 9 , wherein the treated feed material comprises a dust control agent to stabilize the halogen-containing additive during transportation.

12. The method of claim 9 , wherein the treated feed material comprises a freeze control agent to stabilize the halogen-containing additive during transportation.

13. The method of claim 1 , wherein the halogen comprises one or more of a halide and inter-halogen compound, wherein a selected halogen in the additive is at least about 50% above a level of the selected halogen natively in the treated feed material, wherein the selected halogen is one or more of iodine and bromine, and wherein the treated feed material, before additive addition, natively comprises from about 1 to about 100 ppm of the selected halogen.

14. The method of claim 1 , wherein the first location is one or more of a transload facility located between a mine site and the second location and a coal blending location between the mine site and the second location and wherein at least about 75% of the additive in the treated feed material is contacted with the treated feed material at one or more locations remote from the second location.

15. The method of claim 7 , wherein the halogen comprises one or more of a halide and inter-halogen compound, wherein a selected halogen in the additive is at least about 25% above a level of the selected halogen natively in the treated feed material, wherein the selected halogen is one or more of iodine and bromine, and wherein the treated feed material, before additive addition, natively comprises from about 5 to about 100 ppm of the selected halogen.

16. The method of claim 7 , wherein the first location is one or more of a transload facility located between a mine site and the industrial facility and a coal blending location between the mine site and the industrial facility and wherein at least about 75% of the additive in the treated feed material is contacted with the treated feed material at one or more locations remote from the industrial facility.

17. A method, comprising:

receiving, at an industrial facility, a treated feed material comprising a combustible, mercury-containing feed material and a halogen-containing additive, wherein the treated feed material was transported to the industrial facility from a remote location located discretely from the industrial facility; and

combusting, by the industrial facility, the treated feed material to generate a waste gas comprising mercury and the halogen, the halogen enabling removal of at least most of the mercury from the waste gas, wherein the halogen is one or more of iodine and bromine, wherein the feed material is coal, wherein the remote location is a mine site, wherein the industrial facility is a utility power plant, and wherein the treated feed material, before additive addition, natively comprises from about 5 to about 100 ppm of the selected halogen.

18. The method of claim 17 , wherein the transportation of the treated feed material is by one or more of rail car, truck, barge and ship.

19. The method of claim 17 , wherein the halogen-containing additive is in the form of an agglomerate comprising a binder, a halogen compound, and a substrate, wherein the substrate is a portion of the feed material, wherein the treated feed material comprises one or more of a dust control agent to stabilize the halogen-containing additive during transportation and a freeze control agent to stabilize the halogen-containing additive during transportation.

20. The method of claim 17 , wherein the halogen comprises one or more of a halide and inter-halogen compound, wherein a selected halogen in the additive is at least about 50% above a level of the selected halogen natively in the treated feed material, wherein the selected halogen is one or more of iodine and bromine, and wherein the treated feed material, before additive addition, natively comprises from about 1 to about 100 ppm of the selected halogen.

Assignments (7)
SECURITY INTEREST Recorded Jan 3, 2025
From: ARQ SOLUTIONS, LLC; ARQ SOLUTIONS (ES), INC.
To: MIDCAP FUNDING IV TRUST
Reel/Frame 069817/0645 →
RELEASE OF SECURITY INTEREST Recorded Dec 27, 2024
From: CF GLOBAL CREDIT, LP, AS ADMINISTRATIVE AGENT
To: ARQ SOLUTIONS, LLC (F/K/A ADA CARBON SOLUTIONS, LLC); ARQ SOLUTIONS (ES), INC. (F/K/A ADA-ES, INC.)
Reel/Frame 069791/0980 →
CHANGE OF NAME Recorded Feb 21, 2024
From: ADA-ES, INC.
To: ARQ SOLUTIONS (ES), INC.
Reel/Frame 066643/0579 →
PATENT SECURITY AGREEMENT Recorded Feb 1, 2023
From: ADA CARBON SOLUTIONS, LLC; ADA-ES, INC.
To: CF GLOBAL CREDIT, LP
Reel/Frame 062622/0051 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jun 4, 2021
From: THE BANK OF NEW YORK MELLON, AS ADMINISTRATIVE AGENT
To: ADA-ES, INC.
Reel/Frame 056483/0657 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Dec 7, 2018
From: ADA-ES, INC.
To: THE BANK OF NEW YORK MELLON, AS ADMINISTRATIVE AGENT
Reel/Frame 047742/0652 →
SECURITY INTEREST Recorded Oct 23, 2015
From: ADA-ES, INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 036865/0055 →