ACRYLIC POLYOL COATING COMPOSITION
This invention is directed to a coating composition comprising an coating composition comprising a crosslinkable composition and a crosslinking composition. The crosslinkable composition comprises an acrylic polyol wherein the acrylic polyol comprises at least 40 percent by weight of at least one linear or branched C8 or higher alkyl acrylate monomer and at least one polyester extended acrylate monomer. The coating composition is suitable for use as a basecoat and can be used in a 3-wet paint process that eliminates the primer curing booth.
1 - 16 . (canceled)
17 . A process for forming a multi-layer coating comprising sequentially applying directly onto a layer of a cured electrocoat composition, a layer of a primer composition, a layer of a basecoat composition and a layer of a clearcoat composition; and simultaneously curing the applied layers by heating;
wherein the basecoat composition comprises a crosslinkable component, a crosslinking component, an organic liquid carrier, and optionally pigment; wherein
a) the crosslinkable component comprises an acrylic polyol wherein the acrylic polyol comprises at least one linear or branched C8 or higher alkyl acrylate monomer, and at least one polyester-extended acrylate monomer, and
b) the crosslinking component comprises at least one of the group selected from melamine, aminoplast resin, amino resin, polyisocyanate, blocked polyisocyanate, or a combination thereof; and
wherein the total weight percentage of the linear or branched C8 or higher alkyl acrylate monomer and polyester-extended acrylate monomer is at least 40 percent by weight based on the total weight of the acrylic polyol; wherein the applied layer of primer composition and the applied layer of basecoat composition resist intermixing;
and wherein said curing is the first curing for each of the applied primer, basecoat, and clearcoat layers; and
wherein the primer composition comprises a crosslinkable primer component and a crosslinking primer component wherein the crosslinkable primer component comprises about 40 to 95 percent by weight, based on the total weight of the crosslinkable primer component and the crosslinking primer component, of a polyester-extended branched acrylic polymer having a hydroxyl and/or carboxyl monomer content, all or part of which has been reacted with a cyclic lactone, of about 1 to 65 percent by weight and a weight average molecular weight of about 10,000 to 150,000; and wherein the crosslinking primer component that comprises about 5 to 60 percent by weight, based on the total weight of the crosslinkable primer component and the crosslinking primer component, of an aminoplast resin, a blocked polyisocyanate resin, or a combination thereof.
18 . A process for forming a multi-layer coating comprising sequentially applying directly onto a layer of a cured electrocoat composition, a layer of a primer composition, a layer of a basecoat composition and a layer of a clearcoat composition; and simultaneously curing the applied layers by heating;
wherein the basecoat composition comprises a crosslinkable component, a crosslinking component, an organic liquid carrier, and optionally pigment; wherein
a) the crosslinkable component comprises an acrylic polyol wherein the acrylic polyol comprises at least one linear or branched C8 or higher alkyl acrylate monomer, and at least one polyester-extended acrylate monomer, and
b) the crosslinking component comprises at least one of the group selected from melamine, aminoplast resin, amino resin, polyisocyanate, blocked polyisocyanate, or a combination thereof; and
wherein the total weight percentage of the linear or branched C8 or higher alkyl acrylate monomer and polyester-extended acrylate monomer is at least 40 percent by weight based on the total weight of the acrylic polyol; wherein the applied layer of primer composition and the applied layer of basecoat composition resist intermixing;
and wherein said curing is the first curing for each of the applied primer, basecoat, and clearcoat layers; and
wherein the primer composition comprises a crosslinkable primer component and a crosslinking primer component wherein the crosslinkable primer component comprises about 40 to 95 percent by weight, based on the total weight of the crosslinkable primer component and the crosslinking primer component, of a branched acrylic polymer having a hydroxyl, carboxyl, and or other crosslinkable functional group monomer content of about 1 to 65 percent by weight and a weight average molecular weight of about 10,000 to 150,000; and wherein the crosslinking primer component comprises about 5 to 60 percent by weight, based on the total weight of the crosslinkable primer component and the crosslinking primer component, of an aminoplast resin, a blocked polyisocyanate resin, or a combination thereof.
19 . A process for forming a multi-layer coating comprising sequentially applying directly onto a layer of a cured electrocoat composition, a layer of a primer composition, a layer of a basecoat composition and a layer of a clearcoat composition; and simultaneously curing the applied layers by heating;
wherein the basecoat composition comprises a crosslinkable component, a crosslinking component, an organic liquid carrier, and optionally pigment; wherein
a) the crosslinkable component comprises an acrylic polyol wherein the acrylic polyol comprises at least one linear or branched C8 or higher alkyl acrylate monomer, and at least one polyester-extended acrylate monomer, and
b) the crosslinking component comprises at least one of the group selected from melamine, aminoplast resin, amino resin, polyisocyanate, blocked polyisocyanate, or a combination thereof; and
wherein the total weight percentage of the linear or branched C8 or higher alkyl acrylate monomer and polyester-extended acrylate monomer is at least 40 percent by weight based on the total weight of the acrylic polyol; wherein the applied layer of primer composition and the applied layer of basecoat composition resist intermixing;
and wherein said curing is the first curing for each of the applied primer, basecoat, and clearcoat layers; and
wherein the primer composition comprises a crosslinkable primer component and a crosslinking primer component wherein the crosslinkable primer component comprises about 40 to 95 percent by weight, based on the total weight of the crosslinkable primer component and the crosslinking primer component, of a polyester-extended linear acrylic polymer having a hydroxyl and/or carboxyl monomer content, all or part of which is reacted with a cyclic lactone, of about 1 to 90 percent by weight and a weight average molecular weight of about 10,000 to 150,000; and
wherein the crosslinking primer component comprises about 5 to 60 percent by weight, based on the total weight of the crosslinkable primer component and the crosslinking primer component, of an aminoplast resin, a blocked polyisocyanate resin, or a combination thereof.
20 . The process of claim 17 wherein the primer composition is free from or essentially free from nonaqueous dispersion polymers.
21 . The process of claim 17 wherein the process further comprises a flash step between the application of the layer of basecoat composition and the layer of clearcoat composition; or
wherein the process further comprises a flash step between the application of the layer of primer composition and the layer of basecoat composition.
22 . The process of claim 17 wherein said at least one linear or branched C8 or higher alkyl acrylate monomer comprises in the range of from 10 percent to 60 percent by weight of the acrylic polyol.
23 . The process of claim 17 wherein said at least one linear or branched C8 or higher acrylate monomer is chosen from the group consisting of octyl acrylate, octyl methacrylate, nonyl acrylate, nonyl methacrylate, decyl acrylate, decyl methacrylate, undecyl acrylate, undecyl methacrylate, dodecyl acrylate, dodecyl methacrylate, isodecyl acrylate, isodecyl methacrylate, isotridecyl acrylate, isotridecyl methacrylate, tridecyl acrylate, tridecyl methacrylate, tridecyl acrylate, tridecyl methacrylate, stearyl acrylate, and stearyl methacrylate, lauryl acrylate, lauryl methacrylate, or a combination thereof.
24 . The process of claim 17 wherein the crosslinking component comprises a melamine.
25 . The process of claim 17 wherein said at least one polyester extended acrylate monomer is the product of the reaction between a 2-hydroxyethyl methacrylate or 2-hydroxyethyl acrylate and caprolactone.
26 . The process of claim 18 wherein the primer composition is free from or essentially free from nonaqueous dispersion polymers.
27 . The process of claim 18 wherein the process further comprises a flash step between the application of the layer of basecoat composition and the layer of clearcoat composition; or
wherein the process further comprises a flash step between the application of the layer of primer composition and the layer of basecoat composition.
28 . The process of claim 18 wherein said at least one linear or branched C8 or higher alkyl acrylate monomer comprises in the range of from 10 percent to 60 percent by weight of the acrylic polyol.
29 . The process of claim 18 wherein said at least one linear or branched C8 or higher acrylate monomer is chosen from the group consisting of octyl acrylate, octyl methacrylate, nonyl acrylate, nonyl methacrylate, decyl acrylate, decyl methacrylate, undecyl acrylate, undecyl methacrylate, dodecyl acrylate, dodecyl methacrylate, isodecyl acrylate, isodecyl methacrylate, isotridecyl acrylate, isotridecyl methacrylate, tridecyl acrylate, tridecyl methacrylate, tridecyl acrylate, tridecyl methacrylate, stearyl acrylate, and stearyl methacrylate, lauryl acrylate, lauryl methacrylate, or a combination thereof.
30 . The process of claim 18 wherein the crosslinking component comprises a melamine.
31 . The process of claim 18 wherein said at least one polyester extended acrylate monomer is the product of the reaction between a 2-hydroxyethyl methacrylate or 2-hydroxyethyl acrylate and caprolactone.
32 . The process of claim 19 wherein the primer composition is free from or essentially free from nonaqueous dispersion polymers.
33 . The process of claim 19 wherein the process further comprises a flash step between the application of the layer of basecoat composition and the layer of clearcoat composition; or
wherein the process further comprises a flash step between the application of the layer of primer composition and the layer of basecoat composition.
34 . The process of claim 19 wherein said at least one linear or branched C8 or higher alkyl acrylate monomer comprises in the range of from 10 percent to 60 percent by weight of the acrylic polyol.
35 . The process of claim 19 wherein said at least one linear or branched C8 or higher acrylate monomer is chosen from the group consisting of octyl acrylate, octyl methacrylate, nonyl acrylate, nonyl methacrylate, decyl acrylate, decyl methacrylate, undecyl acrylate, undecyl methacrylate, dodecyl acrylate, dodecyl methacrylate, isodecyl acrylate, isodecyl methacrylate, isotridecyl acrylate, isotridecyl methacrylate, tridecyl acrylate, tridecyl methacrylate, tridecyl acrylate, tridecyl methacrylate, stearyl acrylate, and stearyl methacrylate, lauryl acrylate, lauryl methacrylate, or a combination thereof.
36 . The process of claim 19 wherein the crosslinking component comprises a melamine.
37 . The process of claim 19 wherein said at least one polyester extended acrylate monomer is the product of the reaction between a 2-hydroxyethyl methacrylate or 2-hydroxyethyl acrylate and caprolactone.