Austenitic stainless steel
View Patent ↗An austenitic stainless steel, which consists of by mass percent, C: not more than 0.02%, Si: not more than 1.5%, Mn: not more than 2%, Cr: 17 to 25%, Ni: 9 to 13%, Cu: more than 0.26% not more than 4%, N: 0.06 to 0.35%, sol. Al: 0.008 to 0.03%. One or more elements selected from Nb, Ti, V, TA, Hf, and Zr in controlled amounts can be included with the balance being Fe and impurities. P, S, Sn, As, Zn, Pb and Sb among the impurities are controlled as P: 0.006 to 0.04%, S: 0.0004 to 0.03%, Sn: 0.001 to 0.1%, As: not more than 0.01%, Zn: not more than 0.01%, Pb: not more than 0.01% and Sb: not more than 0.01%. The amounts of S, P, Sn, As, Zn, Pb and Sb and the amounts of Nb, Ta, Zr, Hf, and Ti are further controlled using formulas.
1. An austenitic stainless steel, which consists of by mass percent, C: not more than 0.02%, Si: not more than 0.38%, Mn: not more than 2%, Cr: 17 to 25%, Ni: 9 to 13%, Cu: 2.95% to 4%, N: 0.06 to 0.35%, sol. Al: 0.008 to 0.03%, an amount of Co, the Co amount not more than 1.0%, an amount of Ta, the Ta amount not more than 0.2%, and further contains one or more elements selected from Nb: not more than 0.5%, Ti: not more than 0.4%, V: not more than 0.4%, and Hf: not more than 0.2%, with the balance being Fe and impurities, in which the contents of P, S, Sn, As, Zn, Pb and Sb among the impurities are P: 0.006 to 0.04%, S: 0.0004 to 0.03%, Sn: 0.001 to 0.1%, As: not more than 0.01%, Zn: not more than 0.01%, Pb: not more than 0.01% and Sb: not more than 0.01%, and the values of F1 and F2 defined respectively by the following formula (1) and formula (2) satisfy the conditions F1≦0.075 and 0.05≦F2≦1.7−9×F1;
F 1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5} (1),
F 2=Nb+Ta+Zr+Hf+2Ti+(V/10) (2);
wherein each element symbol in the formulas (1) and (2) represents the content by mass percent of the element concerned.
2. An austenitic stainless steel, which consists of by mass percent, C: not more than 0.02%, Si: not more than 0.38%, Mn: not more than 2%, Cr: 17 to 25%, Ni: 9 to 13%, Cu: 2.95% to 4%, N: 0.06 to 0.1%, sol. Al: 0.008 to 0.03%, an amount of Co, the Co amount not more than 1.0%, an amount of Ta, the Ta amount not more than 0.2%, and further contains one or more elements selected from Nb: not more than 0.5%, Ti: not more than 0.4%, V: not more than 0.4%, and Hf: not more than 0.2%, with the balance being Fe and impurities, in which the contents of P, S, Sn, As, Zn, Pb and Sb among the impurities are P: 0.006 to 0.04%, S: 0.0004to 0.03%, Sn: 0.001 to 0.1%, As: not more than 0.01%, Zn: not more than 0.01%, Pb: not more than 0.01% and Sb: not more than 0.01%, and the values of F1 and F2 defined respectively by the following formula (1) and formula (2) satisfy the conditions F1≦0.075 and 0.05≦F2≦1.7−9×F1;
F 1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5} (1),
F 2=Nb+Ta+Zr+Hf+2Ti+(V/10) (2);
wherein each element symbol in the formulas (1) and (2) represents the content by mass percent of the element concerned.
3. An austenitic stainless steel, which consists of by mass percent, C: not more than 0.02%, Si: not more than 0.38%, Mn: not more than 2%, Cr: 17 to 25%, Ni: 9 to 13%, Cu: 2.95% to 4%, N: 0.06 to 0.35%, sol. Al: 0.008 to 0.03%, an amount of Co, the Co amount not more than 1.0%, an amount of Ta, the Ta amount not more than 0.2%, and further contains one or more elements selected from Nb: not more than 0.5%, Ti: not more than 0.4%, V: not more than 0.4%, and Hf: not more than 0.2%, with the balance being Fe and impurities, in which the contents of P, S, Sn, As, Zn, Pb and Sb among the impurities are P: 0.006 to 0.04%, S: 0.0004 to 0.03%, Sn: 0.001 to 0.1%, As: not more than 0.01%, Zn: not more than 0.01%, Pb: not more than 0.01% and Sb: not more than 0.01%, and the values of F1 and F2 defined respectively by the following formula (1) and formula (2) satisfy the conditions F1≦0.075 and 0.05≦F2≦1.7−9×F1;
F 1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5} (1);
F 2=Nb+Ta+Zr+Hf+2Ti+(V/10) (2);
wherein each element symbol in the formulas (1) and (2) represents the content by mass percent of the element concerned, wherein the austenitic stainless steel further consists of, by mass percent, one or more elements of one or more groups selected from the first to third groups listed below in lieu of a part of Fe:
first group: Mo: not more than 1.5%;
second group: B: not more than 0.012%; and
third group: Ca: not more than 0.02%, Mg: not more than 0.02% and rare earth element: not more than 0.1%.
4. An austenitic stainless steel, which consists of by mass percent, C: not more than 0.02%, Si: not more than 0.38%, Mn: not more than 2%, Cr: 17 to 25%, Ni: 9 to 13%, Cu: 2.95% to 4%, N: 0.06 to 0.1%, sol. Al: 0.008 to 0.03%, an amount of Co, the Co amount not more than 1.0%, an amount of Ta, the Ta amount not more than 0.2%, and further contains one or more elements selected from Nb: not more than 0.5%, Ti: not more than 0.4%, V: not more than 0.4%, and Hf: not more than 0.2%, with the balance being Fe and impurities, in which the contents of P, S, Sn, As, Zn, Pb and Sb among the impurities are P: 0.006 to 0.04%, S: 0.0004 to 0.03%, Sn: 0.001 to 0.1%, As: not more than 0.01%, Zn: not more than 0.01%, Pb: not more than 0.01% and Sb: not more than 0.01%, and the values of F1 and F2 defined respectively by the following formula (1) and formula (2) satisfy the conditions F1≦0.075 and 0.05≦F2≦1.7−9×F1;
F 1=S+{(P+Sn)/2}+{(As+Zn+Pb+Sb)/5} (1),
F 2=Nb+Ta+Zr+Hf+2Ti+(V/10) (2);
wherein each element symbol in the formulas (1) and (2) represents the content by mass percent of the element concerned, wherein the austenitic stainless steel further consists of, by mass percent, one or more elements of one or more groups selected from the first to third groups listed below in lieu of a part of Fe:
first group: Mo: not more than 1.5%;
second group: B: not more than 0.012%; and
third group: Ca: not more than 0.02%, Mg: not more than 0.02% and rare earth element: not more than 0.1%.