Electrochromic multi-layer devices with spatially coordinated switching
View Patent ↗A multi-layer device comprising a first substrate and a first electrically conductive layer on a surface thereof, the first electrically conductive layer having a sheet resistance to the flow of electrical current through the first electrically conductive layer that varies as a function of position.
1. A multi-layer device comprising a first substrate and a first electrically conductive layer on a surface thereof, the first electrically conductive layer being transmissive to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet and having a sheet resistance, R s , to the flow of electrical current through the first electrically conductive layer that varies as a function of position in the first electrically conductive layer wherein the ratio of the value of maximum sheet resistance, R max , to the value of minimum sheet resistance, R min , in the first electrically conductive layer is at least 2.
2. The multi-layer device of claim 1 wherein the ratio of the average sheet resistance in a first region of the first electrically conductive layer circumscribed by a first convex polygon to the average sheet resistance in a second region of the first electrically conductive layer circumscribed by a second convex polygon is at least 2, the first and second regions circumscribed by the first and second convex polygons, respectively, each comprising at least 25% of the surface area of the first electrically conductive layer.
3. The multi-layer device of claim 1 wherein the ratio of the average sheet resistance in a first region of the first electrically conductive layer, R 1 avg , to the average sheet resistance in a second region of the first electrically conductive layer, R 2 avg , is at least 1.25, the ratio of the average sheet resistance in the second region of the first electrically conductive layer, R 2 avg , to the average sheet resistance in a third region of the first electrically conductive layer, R 3 avg , is at least 1.25, the ratio of the average sheet resistance in the third region of the first electrically conductive layer, R 3 avg , to the average sheet resistance in a fourth region of the first electrically conductive layer, R 4 avg , is at least 1.25, wherein the first region is contiguous with the second region, the second region is contiguous with the third region, the third region is contiguous with the fourth region, each of the regions is circumscribed by a convex polygon, and each comprises at least 10% of the surface area of the first electrically conductive layer.
4. The multi-layer device of claim 1 wherein the first electrically conductive layer has a spatially varying sheet resistance, R s , that varies as a function of position in the first electrically conductive layer, a contour map of the sheet resistance, R s , as a function of position within the first electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and the sheet resistance along a gradient line in the set generally increases, generally decreases, generally increases until it reaches a maximum and then generally decreases, or generally decreases until it reaches a minimum and then generally increases.
5. The multi-layer device of claim 1 wherein the first electrically conductive layer is graded in composition or thickness.
6. The multi-layer device of claim 1 wherein the first substrate is transparent to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet.
7. The multi-layer device of claim 1 , the multi-layer device further comprising a first electrode layer on a surface of the first electrically conductive layer, the first electrically conductive layer being between the first electrode layer and the first substrate.
8. The multi-layer device of claim 7 wherein the first electrode layer comprises an electrochromic material.
9. The multi-layer device of claim 7 wherein the first electrode layer comprises an anodic species and a cathodic species, at least one of the anodic species and the cathodic species being an electrochromic material.
10. The multi-layer device of claim 7 , the multi-layer device further comprising a second electrically conductive layer, the first electrode layer being transparent to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet and located between the first and second electrically conductive layers, the second electrically conductive layer having a sheet resistance, R s , to the flow of electrical current through the second electrically conductive layer that varies as a function of position in the first electrically conductive layer wherein the ratio of the value of maximum sheet resistance, R max , to the value of minimum sheet resistance, R min , in the second electrically conductive layer is at least 2.
11. The multi-layer device of claim 10 wherein the ratio of the average sheet resistance in a first region of the second electrically conductive layer circumscribed by a first convex polygon to the average sheet resistance in a second region of the second conductive layer circumscribed by a second convex polygon is at least 2, the first and second regions circumscribed by the first and second convex polygons, respectively, each comprising at least 25% of the surface area of the second electrically conductive layer.
12. The multi-layer device of claim 10 wherein the ratio of the average sheet resistance in a first region of the second electrically conductive layer, R 1 avg , to the average sheet resistance in a second region of the second electrically conductive layer, R 2 avg , is at least 1.25, the ratio of the average sheet resistance in the second region of the second electrically conductive layer, R 2 avg , to the average sheet resistance in a third region of the second electrically conductive layer, R 3 avg , is at least 1.25, the ratio of the average sheet resistance in the third region of the second electrically conductive layer, R 3 avg , to the average sheet resistance in a fourth region of the second electrically conductive layer, R 4 avg , is at least 1.25, wherein the first region is contiguous with the second region, the second region is contiguous with the third region, the third region is contiguous with the fourth region, each of the regions is circumscribed by a convex polygon, and each comprises at least 10% of the surface area of the second electrically conductive layer.
13. The multi-layer device of claim 10 wherein the second electrically conductive layer has a spatially varying sheet resistance, R s , that varies as a function of position in the second electrically conductive layer, a contour map of the sheet resistance, R s , as a function of position within the second electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and the sheet resistance along a gradient line in the set generally increases, generally decreases, generally increases until it reaches a maximum and then generally decreases, or generally decreases until it reaches a minimum and then generally increases.
14. The multi-layer device of claim 10 wherein (a) the first electrically conductive layer comprises a region A 1 and a region B 1 wherein region A 1 and region B 1 each comprise at least 25% of the surface area of the first electrically conductive layer, are each circumscribed by a convex polygon and are mutually exclusive, (b) a projection of region A 1 onto the second electrically conductive layer defines a region A circumscribed by a convex polygon in the second electrically conductive layer comprising at least 25% of the surface area of the second electrically conductive, (c) a projection of region B 1 onto the second electrically conductive layer defines a region B circumscribed by a convex polygon in the second electrically conductive layer comprising at least 25% of the surface area of the second electrically conductive, (d) the first electrically conductive layer has an average sheet resistance in region A 1 corresponding to R A1 avg and an average sheet resistance in region B 1 corresponding to R B1 avg (e) the second electrically conductive layer has an average sheet resistance in region A corresponding to R A avg and an average sheet resistance in region B corresponding to R B avg , (f) the ratio of R A1 avg to R B1 avg or the ratio of R B avg to R A avg is at least 1.5 and (g) the ratio of (R A1 avg /R A avg ) to (R B1 avg /R B avg ) is at least 1.5.
15. The multi-layer device of claim 7 , the multi-layer device further comprising an ion conducting layer, the first electrode layer being between the ion conducting layer and the first electrically conductive layer, the ion conducting layer being a dielectric material having an ionic conductivity for carrier ions of at least 10 −7 Siemens/cm at 25° C.
16. The multi-layer device of claim 15 , the multi-layer device further comprising a second electrode layer, the ion conducting layer being between the first and second electrode layers.
17. The multi-layer device of claim 16 wherein the second electrode layer comprises an electrochromic material.
18. The multi-layer device of claim 7 , the multi-layer device further comprising a second substrate, the second electrically conductive layer being between the second substrate and the first electrically conductive layer.
19. The multi-layer device of claim 18 wherein the second substrate is transparent to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet.
20. The multi-layer device of claim 1 wherein the first substrate has an inner surface facing the first electrically conductive layer, the surface area of the inner surface of the first substrate being at least 0.1 meter 2 .
21. An electrochromic device comprising a first substrate, a first electrically conductive layer, a first electrode layer, a second electrically conductive layer and a second substrate, the first and second electrically conductive layers each having a sheet resistance, R s , to the flow of electrical current through the first and second electrically conductive layers that varies as a function of position in the first and second electrically conductive layers, respectively, wherein the ratio of the value of maximum sheet resistance, R max , to the value of minimum sheet resistance, R min , in the first electrically conductive layer is at least 2 and the ratio of the value of maximum sheet resistance, R max , to the value of minimum sheet resistance, R min , in the second electrically conductive layer is at least 2, the first substrate and the first electrically conductive layer being transmissive to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet.
22. The electrochromic device of 21 wherein (i) the ratio of the average sheet resistance in a first region of the first electrically conductive layer circumscribed by a first convex polygon to the average sheet resistance in a second region of the first electrically conductive layer circumscribed by a second convex polygon is at least 2, the first and second regions of the first electrically conductive layer each comprising at least 25% of the surface area of the first electrically conductive layer and (ii) the ratio of the average sheet resistance in a first region of the second electrically conductive layer circumscribed by a first convex polygon to the average sheet resistance in a second region of the second electrically conductive layer circumscribed by a second convex polygon is at least 2, the first and second regions of the second electrically conductive layer each comprising at least 25% of the surface area of the second electrically conductive layer.
23. The electrochromic device of claim 21 wherein the first electrically conductive layer has a spatially varying sheet resistance, R s , that varies as a function of position in the first electrically conductive layer, a contour map of the sheet resistance, R s , as a function of position within the first electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and the resistance along a gradient line in the set generally increases, generally decreases, generally increases until it reaches a maximum and then generally decreases, or generally decreases until it reaches a minimum and then generally increases.
24. The electrochromic device of claim 23 wherein the second electrically conductive layer has a spatially varying sheet resistance, R s , that varies as a function of position in the second electrically conductive layer, a contour map of the sheet resistance, R s , as a function of position within the second electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and the resistance along a gradient line in the set generally increases, generally decreases, generally increases until it reaches a maximum and then generally decreases, or generally decreases until it reaches a minimum and then generally increases.
25. The electrochromic device of claim 23 wherein (i) the first electrically conductive layer has a spatially varying sheet resistance, R s , that varies as a function of position in the first electrically conductive layer, (ii) a contour map of the sheet resistance, R s , as a function of position within the first electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and (iii) a projection of a line segment having a length of at least 1 cm of one of the gradient lines onto the second electrically conductive layer defines a complementary line segment in the second electrically conductive layer wherein (a) the average value of the slope of the sheet resistance of the first electrically conductive layer over the gradient line segment, S 1 avg , is a positive or negative value, and (b) the average value of the slope of the sheet resistance of the second electrically conductive layer over the complementary line segment, S 2 avg , is zero or is opposite in sign to S 1 avg .
26. The electrochromic device of claim 21 wherein the second substrate and the second electrically conductive layer are transparent to electromagnetic radiation having a wavelength in the range of infrared to ultraviolet.
27. The multi-layer device of claim 21 wherein the multi-layer device comprises, in succession, the first substrate, the first electrically conductive layer, the first electrode layer, an ion conducting layer, a second electrode layer, the second electrically conductive layer and the second substrate.
28. The multi-layer device of claim 21 wherein the multi-layer device comprises, in succession, the first substrate, the first electrically conductive layer, the first electrode layer, the second electrically conductive layer and the second substrate.
29. The multi-layer device of claim 21 wherein the multi-layer device comprises, in succession, the first substrate, the first electrically conductive layer, the first electrode layer, an ion conducting layer, the second electrically conductive layer and the second substrate.
30. A process for the preparation of a multi-layer device comprising forming a multi-layer layer structure comprising an electrochromic layer between and in electrical contact with a first and a second electrically conductive layer, the first and/or the second electrically conductive layer having a spatially varying sheet resistance, R s , to the flow of electrical current through the first and/or the second electrically conductive layer that varies as a function of position in the first and/or the second electrically conductive layer, respectively, wherein the ratio of the average sheet resistance in a first region of the first electrically conductive layer circumscribed by a first convex polygon to the average sheet resistance in a second region of the first electrically conductive layer circumscribed by a second convex polygon is at least 2, the first and second regions circumscribed by the first and second convex polygons, respectively, each comprising at least 25% of the surface area of the first electrically conductive layer.
31. The process of claim 30 wherein the ratio of the average sheet resistance in a first region of the first electrically conductive layer, R 1 avg , to the average sheet resistance in a second region of the first electrically conductive layer, R 2 avg , is at least 1.25, the ratio of the average sheet resistance in the second region of the first electrically conductive layer, R 2 avg , to the average sheet resistance in a third region of the first electrically conductive layer, R 3 avg , is at least 1.25, the ratio of the average sheet resistance in the third region of the first electrically conductive layer, R 3 avg , to the average sheet resistance in a fourth region of the first electrically conductive layer, R 4 avg , is at least 1.25, wherein the first region is contiguous with the second region, the second region is contiguous with the third region, the third region is contiguous with the fourth region, each of the regions is circumscribed by a convex polygon, and each comprises at least 10% of the surface area of the first electrically conductive layer.
32. The process of claim 30 wherein the first electrically conductive layer has a spatially varying sheet resistance, R s , that varies as a function of position in the first electrically conductive layer, a contour map of the sheet resistance, R s , as a function of position within the first electrically conductive layer contains a set of isoresistance lines and a set of resistance gradient lines normal to the isoresistance lines, and the sheet resistance along a gradient line in the set generally increases, generally decreases, generally increases until it reaches a maximum and then generally decreases, or generally decreases until it reaches a minimum and then generally increases.
33. The process of claim 30 wherein the process comprises depositing the first electrically conductive layer on a substrate and varying the sheet resistance of the deposited layer as a function of position in the first electrically conductive layer.
34. The process of claim 30 wherein the process comprises depositing a first electrically conductive layer having a composition or thickness that varies as a function of position in the first electrically conductive layer.