Molded parts containing a polylactic acid composition
View Patent ↗A molded part that is formed from a thermoplastic composition that contains a polylactic acid, propylene/α-olefin copolymer, and a polyolefin compatibilizer is provided. The propylene/α-olefin copolymer can be dispersed as discrete physical domains within a continuous matrix of the polylactic acid. Without intending to be limited by theory, it is believed that the discrete domains can help resist the expansion of the composition during a molding operation, which minimizes the degree of expansion experienced by the composition during molding in comparison to conventional polylactic acid compositions.
1. A molded part that is formed from a thermoplastic composition, wherein the thermoplastic composition comprises:
from about 50 wt. % to about 95 wt. % of at least one polylactic acid having a glass transition temperature of about 40° C. or more;
from about 5 wt. % to about 30 wt. % of at least one propylene/α-olefin copolymer having a propylene content of from about 60 mole % to about 90 mole % and an α-olefin content of from about 10 mole % to about 40 mole %, wherein the copolymer further has a density of from about 0.82 to about 0.90 grams per cubic centimeter; and
from about 0.5 wt. % to about 20 wt. % of at least one polyolefin compatibilizer that contains a polar component;
wherein the part exhibits a degree of expansion of about 0.9% or less in a width direction, as determined in accordance with ASTM D955-08.
2. The molded part of claim 1 , wherein the part exhibits a degree of expansion of from 0.3% to about 0.7% in the width direction.
3. The molded part of claim 1 , wherein the thermoplastic composition has a morphology in which a plurality of discrete primary domains are dispersed within a continuous phase, the domains containing the propylene/α-olefin copolymer and the continuous phase containing the polylactic acid.
4. The molded part of claim 1 , wherein the polylactic acid has a glass transition temperature of from about 50° C. to about 65° C.
5. The molded part of claim 1 , wherein the α-olefin of the copolymer is ethylene, 1-octene, 1-hexene, 1-butene, or a combination thereof.
6. The molded part of claim 1 , wherein the propylene content of the copolymer is from about 70 mole % to about 80 mole % and the α-olefin content of the copolymer is from about 20 mole % to about 30 mole %.
7. The molded part of claim 1 , wherein the copolymer has a density of from about 0.86 to about 0.88 grams per cubic centimeter.
8. The molded part of claim 1 , wherein the copolymer has a melt flow rate of from about 1 to about 50 grams per 10 minutes, determined at a load of 2160 grams and a temperature of 230° C. in accordance with ASTM D1238-E.
9. The molded part of claim 1 , wherein the copolymer is metallocene-catalyzed.
10. The molded part of claim 1 , wherein the copolymer is elastomeric.
11. The molded part of claim 1 , wherein the copolymer exhibits a flexural modulus of from about 1 about 100 Megapascals, determined in accordance with ASTM D790 at 23° C.
12. The molded part of claim 1 , wherein the polar component is grafted onto a polyolefin backbone.
13. The molded part of claim 12 , wherein the polar component includes maleic anhydride.
14. The molded part of claim 1 , wherein the polar component is a monomeric constituent of the polyolefin compatibilizer.
15. The molded part of claim 14 , wherein the polar component includes a (methy)acrylic monomeric constituent.
16. The molded part of claim 1 , wherein the molded part exhibits a tensile modulus of from about 2.0 to about 3.0 Gigapascals measured at 23° C. according to ASTM D638-10.
17. A container comprising the molded part of claim 1 .
18. The container of claim 17 , wherein the container is configured to receive a plurality of wipes.