Organometallic compounds containing a metal belonging to the second column of the periodic table, and method for preparing same
View Patent ↗The present invention relates to a novel organometallic compound based on a divalent metal belonging to the 2 nd column of the Periodic Table that can be used as an alkylating agent in a catalytic system based on a rare-earth metal. This novel compound corresponds to the formula: in which, M is a metal belonging to the 2 nd column of the Periodic Table, chosen from Be, Mg, Sr, Ba, and Ra; R 1 , R 2 , R 3 and R 4 are hydrogen atoms or alkyl or aryl substituents, optionally bonded together to form at least one ring or at least one aromatic ring; R and R′ denote alkyl or aryl substituents; L is a Lewis base; x is an integer from 0 to 4; m is an integer greater than or equal to 0; and n is an integer greater than or equal to 1.
1. A method of producing a catalytic system for polymerization based on a rare earth metal salt comprising introducing an organometallic compound of formula (III):
in which,
M is a metal belonging to the 2 nd column of the Periodic Table;
R 1 , R 2 , R 3 and R 4 , which are identical to or different from one another, are hydrogen atoms or linear or branched alkyl substituents, or aryl substituents, which are substituted or unsubstituted, optionally bonded together to form at least one ring composed of 5 or 6 atoms, or at least one aromatic ring;
R and R′, which are identical to or different from one another, denote linear or branched alkyl substituents, or aryl substituents, which are substituted or unsubstituted;
L is a Lewis base;
x is an integer which is equal to 0, 1, 2, 3 or 4;
m is an integer having a value ranging from 0 to 3;
n is an integer having a value ranging from 1 to 3,
as an alkylating co-catalyst in the catalytic system.
2. The method according to claim 1 , wherein the (compound of formula (III)/rare-earth metal) molar ratio has a value ranging from 1.5 to 20.