Method for producing pentafluoropropane
View Patent ↗The present invention relates to a method for producing 1,2,3,3,3-pentafluoropropane, involving reacting gaseous phase 1,2,3,3,3-pentafluoropropene with hydrogen in a superstoichimetric amount in the presence of a hydrogenation catalyst in a reactor, and recirculating a part of the gaseous effluent from the reactor.
1. Process for the manufacture of 1,1,1,2,3-pentafluoropropane, comprising (i) reacting 1,2,3,3,3-pentafluoropropene in the gas phase with hydrogen in a superstoichiometric amount, at a temperature of between 80 and 250° C. in the presence of a hydrogenation catalyst in a reactor to produce a gaseous output stream, wherein the gaseous output stream comprises from 5 to 96% by volume of 1,1,1,2,3-pentafluoropropane, from 2 to 90% by volume of hydrogen, from 1 to 20% of 1,1,1,2-tetrafluoropropane and from 0 to 10% of 1,2,3,3,3-pentafluoropropene; (ii) recycling a first portion of the gaseous output stream from the reactor, comprising 1,1,1,2,3-pentafluoropropane, unreacted hydrogen, optionally unreacted 1,2,3,3,3-pentafluoropropene, 1,1,1,2-tetrafluoropropane and hydrofluoric acid, and (iii) recovering 1,1,1,2,3-pentafluoropropane from a second portion of the gaseous output stream from the reactor, optionally after a purification stage, wherein the recycled first portion of the gaseous output stream represents at least 80%, by volume of the output stream.
2. Process according to claim 1 , characterized in that the catalyst comprises supported palladium.
3. Process according to claim 2 , characterized in that the support is based on alumina.
4. Process according to claim 1 , characterized in that the molar ratio of hydrogen to 1,2,3,3,3-pentafluoropropene is between 1.5 and 40.
5. Process according to claim 1 , characterized in that the contact time in the reactor is between 0.2 and 20 s.
6. Process according to claim 1 , characterized in that the reaction is carried out at a pressure of between 0.5 and 20 bar absolute.
7. Process according to claim 1 , characterized in that it is carried out continuously.
8. Process according to claim 1 , characterized in that the temperature is between 110 and 160° C.
9. Process according to claim 1 , characterized in that between 93 and 98% by volume of the output stream is recycled.
10. Process according to claim 1 , characterized in that the molar ratio of hydrogen to 1,2,3,3,3-pentafluoropropene is between 3 and 10.
11. Process according to claim 1 , characterized in that the reaction is carried out at a pressure of between 1 and 5 bar absolute.
12. Process according to claim 1 , characterized in that the contact time in the reactor is between 1 and 5 s.