Porous polypropylene film
View Patent ↗Provided is a porous polypropylene film having both air permeability properties and puncture strength. A porous polypropylene film which has an air permeability of 700 seconds/100 ml or less and a puncture strength of 1.5 N or greater, and has β activity can be obtained when the porous polypropylene film is made to have a tensile strength in the machine direction of the film, E MD , of 100 MPa or greater, a tensile strength in the transverse direction to the machine direction, E TD , of less than 100 MPa, and a ratio of E MD and E TD , E MD /E TD , of 1.5 to 10.
1. A porous polypropylene film having a tensile strength in the flow direction of the film, E MD , of 100 MPa or greater; a tensile strength in the direction perpendicular to the flow direction, E TD , of less than 100 MPa; a ratio of E MD and E TD , E MD /E TD , of 1.5 to 10; an air permeability of 700 seconds/100 ml or less; a puncture strength of 1.5 N or greater; and having β activity wherein the porous polypropylene film is obtained under the following stretching conditions of a TD stretching temperature of from 100-160° C., and a MD stretching temperature of from 10 to 120° C. such that a stretch ratio in the flow direction of the film, λ MD , is 3.0 to 8.0 times; a stretch ratio in the direction perpendicular to the flow direction, λ TD , is 1.1 to 2.5 times; and a ratio between λ MD and λ TD , λ MD /λ TD , is 1.5 to 5.0.
2. The film of claim 1 , wherein a coefficient of dynamic friction at the front and back surfaces of the film is 0.10 to 0.80.
3. The film of claim 2 , wherein the porous polypropylene film is obtained under the following stretching conditions of a TD stretching temperature of from 100-160° C., and a MD stretching temperature of from 10 to 120° C. such that a stretch ratio in the flow direction of the film, λ MD , is 3.0 to 8.0 times; a stretch ratio in the direction perpendicular to the flow direction, λ TD , is 1.1 to 2.5 times; and a ratio between λ MD and λ TD , λ MD /λ TD , is 1.5 to 5.0.
4. The film of claim 1 , wherein the porous propylene film comprises a polypropylene resin comprising a β crystal nucleating agent.
5. The film of claim 4 , wherein the β crystal nucleating agent is contained in an amount of 0.0001 to 5.0 parts by mass relative to 100 parts by mass of the polypropylene resin.
6. The film of claim 1 , wherein the porous propylene film comprises a polypropylene resin having a isotactic pentad fraction of 80% to 99%.
7. The film of claim 1 , wherein the porous propylene film comprises a polypropylene resin having a Mw/Mn ratio of from 2.0 to 10.0.
8. The film of claim 1 , wherein the porous propylene film comprises a polypropylene resin having a melt flow rate of from 0.5 to 15 g/10 min.
9. The film of claim 4 , wherein the thickness of the porous propylene film is from 1 to 500 μm.
10. The film of claim 1 , wherein the porous propylene film has a porosity of from 30% to 70%.
11. The film of claim 1 , wherein the porous propylene film has a puncture strength of 3.0 N or greater.