Device for continuously carrying out chemical reactions at high temperatures
View Patent ↗The invention relates to a device for continuously carrying out chemical reactions. The device comprises a microwave generator, a microwave applicator accommodating a microwave-transparent tube, and an isothermal reaction section which is arranged such that the material to be reacted is guided inside the microwave-transparent tube through a microwave applicator which is used as the heating zone and in which it is heated to reaction temperature by means of microwaves that are emitted from the microwave generator into the microwave applicator. The material to be reacted, which is heated and optionally under pressure, is transferred from the microwave applicator to an isothermal reaction zone once it has left the heating zone, said reaction zone being arranged downstream of the heating zone, and is cooled once it has left the isothermal reaction zone.
1. An apparatus for continuously performing a chemical reaction, comprising a microwave generator, a monomode microwave applicator with a microwave-transparent tube within, and an isothermal reaction zone, which are arranged such that the longitudinal axis of the microwave-transparent tube is in the direction of propagation of the microwaves in the monomode microwave applicator, and that a reaction mixture in the microwave-transparent tube is conducted through the monomode microwave applicator as a heating zone, within which the reaction mixture is heated to reaction temperature by means of microwaves which are conducted out of the microwave generator into the monomode microwave applicator, and wherein the heated and the optionally pressurized, reaction mixture is transferred immediately after leaving the heating zone into the isothermal reaction zone adjoining the heating zone and, after leaving the isothermal reaction zone, the reaction mixture is cooled down.
2. The apparatus as claimed in claim 1 , in which the microwave-transparent tube is within a hollow conductor as a microwave applicator connected to a microwave generator.
3. The apparatus as claimed in claim 1 , in which the microwave applicator is configured as a cavity resonator.
4. The apparatus as claimed in claim 1 , in which the microwave applicator is configured as a reflection-type cavity resonator.
5. The apparatus as claimed in claim 2 , in which the microwave-transparent tube is aligned axially with a central axis of symmetry of the hollow conductor.
6. The apparatus as claimed in claim 3 , in which the cavity resonator has a coaxial transition of the microwaves.
7. The apparatus as claimed in claim 3 , in which the cavity resonator is operated in E 01n mode where n is an integer from 1 to 200.
8. The apparatus as claimed in claim 1 , wherein the isothermal reaction zone is a thermally insulated tube.
9. The apparatus as claimed in claim 1 , in which the isothermal reaction zone comprises an apparatus for supply or removal of energy.
10. A process for continuously performing a chemical reaction, in which the reaction mixture, in an apparatus as claimed in claim 1 , is conducted through a heating zone in which it is heated to reaction temperature by microwaves and from which the heated and optionally pressurized reaction mixture is transferred immediately after leaving the heating zone into an isothermal reaction zone adjoining the heating zone and, after leaving the isothermal reaction zone, is cooled.
11. The process as claimed in claim 10 , in which the reaction mixture is heated by the microwaves to temperatures between 70 and 500° C.
12. The process as claimed in claim 10 , in which the microwaves are effected at pressures above atmospheric pressure.
13. The process as claimed in claim 10 , in which the properties of the isothermal reaction zone are such that the temperature of the reaction mixture after passing through the isothermal reaction zone differs by at most ±20° C. from the inlet temperature of the heating zone.
14. The process for continuously performing a chemical reaction in an apparatus as claimed in claim 3 in which a standing wave forms in the cavity resonator.