Aluminum alloy heat exchanger and method of producing refrigerant tube used for the heat exchanger
An aluminum alloy heat exchanger is produced by applying a coating material that is prepared by adding a binder to a mixture of an Si powder and a Zn-containing compound flux powder to a surface of an aluminum alloy refrigerant tube, assembling a bare fin that is formed of an Al—Mn—Zn alloy with the refrigerant tube, and brazing the refrigerant tube and the bare fin by heating in an atmosphere-controlled furnace, the refrigerant tube being an extruded product of an aluminum alloy that comprises 0.5 to 1.7% (mass %, hereinafter the same) of Mn, less than 0.10% of Cu, and less than 0.10% of Si, with the balance being Al and unavoidable impurities, a mixing ratio of the Si powder to the Zn-containing compound flux powder being 10:90 to 40:60, the binder being added in an amount of 5 to 40% based on the total amount of the coating material, the coating material being applied to an outer surface of the refrigerant tube so that the total amount of the Si powder and the Zn-containing compound flux powder is 5 to 30 g/m 2 , the surface of the refrigerant tube subjected to brazing having a potential lower than that of an area of the refrigerant tube that is deeper than a diffusion depth of Si and Zn by 20 to 200 mV, and a potential of the fin being lower than that of a deep area of the refrigerant tube.
1. An aluminum alloy heat exchanger comprising a coated aluminum alloy extruded refrigerant tube having an aluminum alloy bare fin made of an Al—Mn—Zn alloy and brazed thereto, the aluminum alloy extruded refrigerant tube comprising 0.6-1.7 mass % of Mn, less than 0.05 mass % of Cu, less than 0.10 mass % Si and the balance being Al and unavoidable impurities, the coating on the aluminum alloy extruded refrigerant tube comprising a mixture of Si powder, a Zn-containing compound flux powder and a binder, a mixing ratio of the Si powder to the Zn-containing compound flux powder being 10:90-40:60, the binder being present in an amount of 5-40% based on the total amount of the coating, the coating being present on an outer surface of the refrigerant tube such that the total amount of Si powder and Zn-containing compound flux powder is 5-30 g/m2, the refrigerant tube having a surface and an area underlying the diffusion depth of Si and Zn, wherein the surface of the refrigerant tube subjected to brazing has a potential lower than the area of the refrigerant tube that is underlying the diffusion depth of Si and Zn by 20-200 mV, both the fin and the area of the refrigerant tube subjected to brazing having a potential, the potential of the fin being lower than the potential of the area of the refrigerant tube underlying the depth of Si and Zn.
2. The aluminum alloy heat exchanger according to claim 1 , wherein the aluminum alloy extruded refrigerant tube further comprises at least one of 0.30 mass % or less of Ti, 0.10 mass % or less of Sr, and 0.3 mass % or less of Zr.
3. The aluminum alloy heat exchanger according to claim 1 , wherein the Zn-containing compound flux powder is KZnF 3 .
4. The aluminum alloy heat exchanger according to claim 1 , wherein the Al—Mn—Zn alloy comprises 0.1 to 1.8 mass % of Mn, 0.8 to 3.0 mass % of Zn, and at least one of 0.1 to 1.2 mass % of Si, 0.01 to 0.8 mass % of Fe, 0.05 to 0.5 mass % of Mg, 0.3 mass % or less of Cu, 0.3 mass % or less of Cr, 0.3 mass % or less of Zr, and 0.3 mass % or less of Ti, with the balance being Al and unavoidable impurities.
5. The aluminum alloy heat exchanger according to claim 4 , wherein the Al—Mn—Zn alloy further comprises at least one of 0.001 to 0.10 mass % of In and 0.001 to 0.10 mass % of Sn.