Foamable oil-water emulsion
View Patent ↗The present invention relates to foamable oil-in-water emulsions containing: A) one or more emulsifiers, at least one of which is a non-ionic emulsifier, B) one or more cotensides, C) one or more oils, D) optionally, one or more polar solubilizers, E) optionally, auxiliary and additive substances, F) one or more surfactants, G) water, H) optionally, water-soluble substances, provided that the water content of the emulsion is ≧70% by weight and the concentration of surfactant(s) F) is from 0.01 to less than 10% by weight, each based on the entire emulsion. The invention further relates to a method for producing the oil-water emulsions according to the invention, to foams obtained from these oil-water emulsions, to a method for producing the foams, and to the application of the oil-water emulsions according to the invention and to the foams produced therefrom.
1. A foamable oil-in-water emulsion, comprising the following components:
(A) at least one nonionic emulsifier, wherein the at least one nonionic emulsifier (A) comprises an emulsifier mixture comprising:
(a) at least one nonionic primary emulsifier, said at least one nonionic primary emulsifier is at least one polyol partial ester selected form the group consisting of:
a1) a glycerol and polyglycerol partial ester, produced by esterification of at least one aliphatic, linear or branched, optionally unsaturated and/or hydroxyfunctionalized carboxylic acid with a chain length of from 6 to 22 carbon atoms with glycerol, polyglycerol or a mixture thereof,
a2) sorbitan or a sorbitol partial ester, produced by esterification of at least one aliphatic, linear or branched, optionally unsaturated and/or hydroxyfunctionalized carboxylic acid with a chain length of from 6 to 22 carbon atoms with sorbitol,
a3) a carbohydrate ester, produced by esterification of at least one aliphatic, linear or branched, optionally unsaturated and/or hydroxyfunctionalized carboxylic acid with a chain length of ≧6 to ≦22 carbon atoms with at least one mono- or polysaccharide, and
a4) an (alkyl poly)glycoside, produced by reacting at least one aliphatic, linear or branched, optionally unsaturated and/or additionally hydroxyfunctionalized alcohol with a chain length of from 6 to 22 carbon atoms with at least one mono- or polysaccharide,
wherein at least one nonionic primary emulsifier (a) is a polyglycerol laurate and optionally a sorbitan laurate, and
(b) at least one secondary emulsifier comprising at least one acid function, wherein the at least one acid function is optionally completely or partially neutralized, said at least one secondary emulsifier is at least one compound selected from the group consisting of:
b1) optionally a hydroxyl-group-containing di- or polycarboxylate, malonate, malate, succinate, sulfosuccinate, citrate, tartrate, in which acid groups have been optionally partially esterified with at least one aliphatic or aromatic, linear or branched, optionally unsaturated and/or hydroxyfunctionalized alcohol with a chain length of from 6 to 22 carbon atoms,
b2) optionally a hydroxyl-group-containing di- or polycarboxylate, malonate, malate, succinate, sulfosuccinate, citrate, tartrate, in which acid groups have been optionally partially esterified with a polyol, polyol partial ester, with at least one aliphatic or aromatic, linear or branched, optionally unsaturated and/or hydroxyfunctionalized carboxylic acid with a chain length of from 6 to 22 carbon atoms,
b3) polyol which has been optionally partially esterified with at least one aliphatic or aromatic, linear or branched, optionally unsaturated and/or hydroxyfunctionalized mono-, di- or polycarboxylic acid with a chain length of from 2 to 22 carbon atoms, wherein free, neutralizable acid groups are present in a molecule,
b4) a hydroxyfunctional mono-, di- or polycarboxylic acid, hydroxyl groups of which have been optionally reacted at least partially with at least one aliphatic, linear or branched, optionally unsaturated and/or hydroxyfunctionalized carboxylic acid with a chain length of from 6 to 22 carbon atoms,
b5) a N-acylamino acid, optionally comprising an aliphatic or aromatic, linear or branched, optionally unsaturated and/or hydroxyfunctionalized radical with a chain length of from 6 to 22 carbon atoms, and
b6) carboxylate, sulfate, sulfonate, phosphonate or phosphate, optionally comprising an aliphatic or aromatic, linear or branched, optionally unsaturated and/or hydroxyfunctionalized acyl radical with a chain length of from 6 to 22 carbon atoms;
wherein at least one secondary emulsifier is glyceryl stearate citrate;
wherein the at least one nonionic emulsifier (A) comprises ≧75 to ≦99.5% by weight of nonionic primary emulsifier component (a) and ≧0.5 to ≦25% by weight of secondary emulsifier component b), based on the emulsifier A);
(B) at least one cosurfactant selected from the group consisting of an aliphatic cosurfactant and aromatic cosurfactant, wherein the aliphatic cosurfactant is selected from the group consisting of n-pentanol, n-hexanol, 1,2-hexanediol, 1,2-heptanediol and 1,2-octanediol and the aromatic cosurfactant is selected from the group consisting of phenoxyethanol, benzyl alcohol and alkyl paraben ester, wherein the at least one cosurfactant (B) is optionally used in a mixture with at least one customary preservative;
(C) at least one oil;
(D) optionally at least one polar solubilizer;
(E) optionally an auxiliary, an additive, or a mixture thereof;
(F) at least one surfactant selected from the group consisting of isethionate, sulfosuccinate, amphopropionate, betaine, amphoacetate, glycoside, amino acid surfactant, polyethylene glycol lauryl ether and sarcosinate;
(G) water; and
(H) optionally a water-soluble substance,
wherein a water content of the emulsion is ≧70% by weight and a content of the at least one surfactant (F) is from 0.01 to less than 10% by weight, based on the total weight of the emulsion, and
wherein a mass ratio of the at least one surfactant (F) to the at least one nonionic emulsifier (A) is from 1:20 to 2:1, and a mass ratio of the at least one oil (C) to the at least one nonionic emulsifier (A) is from 20:1 to 1:2.
2. The emulsion of claim 1 , wherein the at least one surfactant (F) is at least one selected from the group consisting of sodium cocoyl isethionate, sodium lauroyl sarcosinate, disodium laureth sulfosuccinate, sodium cocoamphopropionate, a fatty alcohol C 8-14 -alkyl glycoside, disodium cocoyl glutamate, betaine, and PEG-6 lauryl ether.
3. The emulsion of claim 1 , wherein (E) the auxiliary, additive, or both, are at least one selected from the group consisting of a pH regulator, a consistency regulator, a stabilizer, a humectant, a dye, a care substance, an active ingredient, an odor corrector, a plant extract, a perfume, a preservative, and a film former.
4. The emulsion of claim 1 , wherein a partially neutralized or neutralized citric acid partial ester having a hydrophobic radical comprising from 10 to 18 carbon atoms other than glyceryl stearate citrate is present.
5. A method for producing a foamable oil-in-water emulsion according to claim 1 , the method comprising mixing an oil phase with water and at least one surfactant to produce an emulsion,
wherein
the oil phase comprises:
(A) at least one nonionic emulsifier;
(B) at least one cosurfactant;
(C) at least one oil;
(D) from 0 to less than 10% by weight, based on the total oil phase, of at least one polar solubilizer; and
(E) optionally an auxiliary, an additive, or a mixture thereof,
wherein the water optionally comprises a water-soluble substance, and
the emulsion has a water content of ≧70% by weight and a surfactant content of from 0.01 to less than 10% by weight.
6. A foam, comprising the oil-in-water emulsion of claim 1 .
7. The foam of claim 6 , obtained by foaming an oil-in-water emulsion.
8. The foam of claim 6 further comprising foam bubbles containing a gas mixture of air.
9. A method for producing the foam of claim 6 , the method comprising foaming the oil-in-water emulsion.
10. The method of claim 9 , wherein the emulsion is foamed by introducing ambient air.
11. An article comprising the oil-in-water emulsion of claim 1 , which article is at least one selected from the group consisting of a cosmetic, a dermatological foam, a pharmaceutical foam, and a household cleaner foam.
12. An article comprising the oil-in-water emulsion of claim 1 , which article is at least one selected from the group consisting of a foam for face and body care, a foam for baby care, a sunscreen, a make-up remover, and an article for cleaning and care of surfaces in the home and in industry.
13. The emulsion of claim 1 , wherein the carbohydrate ester a3) is present and is selected from the group consisting of a glycoside and sucrose ester.
14. The emulsion of claim 1 , wherein the hydroxyl-group-containing di- or polycarboxylate b1) is present and is selected from the group consisting of a sulfated, sulfonated, and phosphated carboxylate.
15. The emulsion of claim 1 , wherein the hydroxyl-group-containing di- or polycarboxylate b2) is present and is selected from the group consisting of a sulfated, sulfonated, and phosphated carboxylate.
16. The emulsion of claim 1 , wherein the polyol b3) is present and is selected from the group consisting of glycerol, polyglycerol and sorbitol.
17. The emulsion of claim 1 , wherein the N-acylamino acid b5) is present and is selected from the group consisting of sarcosinate, glutamate, and aspartate.