IP Library Granted Patent US 8,460,572
Granted Patent B2
US 8,460,572 · App. 13/380,085 · Granted Jun 11, 2013

Aircraft anti-icing fluids formulated with nanocrystalline cellulose

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Quick Facts
Patent No.
US 8,460,572
App. No.
13/380,085
Granted
Jun 11, 2013
Kind
B2
Abstract

An aircraft anti-icing composition is provided comprising a freezing point depressant and a thickener comprising nanocrystalline cellulose. A thickening composition is also provided comprising nanocrystalline cellulose. Also taught is the use of nanocrystalline cellulose in the manufacture of an anti-icing composition and the use of nanocrystalline cellulose in a thickening composition.

Claims (37)

1. An aircraft anti-icing composition comprising: a. a freezing point depressant; and b. a thickener comprising nanocrystalline cellulose.

2. The aircraft anti-icing composition of claim 1 , wherein the freezing point depressant is a glycol solution in water.

3. The aircraft anti-icing composition of claim 2 , wherein the glycol solution makes up at least 40% by weight of the anti-icing composition.

4. The aircraft anti-icing composition of claim 3 , wherein the glycol solution makes up between 50 to 95% by weight of the anti-icing composition.

5. The aircraft anti-icing composition of claim 2 , wherein the glycol solution is selected from the group consisting of ethylene glycol, propylene glycol, diethylene glycol, triethylene triol and 1,2-propane diol.

6. The aircraft anti-icing composition of claim 1 , wherein the nanocrystalline cellulose is present in an amount of 0.25 to 5% by weight of the anti-icing composition.

7. The aircraft anti-icing composition of claim 6 , wherein the nanocrystalline cellulose is present in an amount of 0.25 to 2% by weight of the anti-icing composition.

8. The aircraft anti-icing composition of claim 1 , wherein the thickener further comprises one or more water soluble polymeric thickeners.

9. The aircraft anti-icing composition of claim 8 , wherein the polymeric thickeners are present in an amount of 0.1 to 2% by weight of the anti-icing composition.

10. The aircraft anti-icing composition of claim 9 , wherein the polymeric thickeners are present in an amount of 0.1 to 0.5% by weight of the anti-icing composition.

11. The aircraft anti-icing composition of claim 8 , wherein the water soluble polymeric thickeners are selected from the group consisting of crosslinked polyacrylates, carboxypolymethylene, polysaccharides, associative synthetic polymers, carboxymethyl cellulose, hydroxyethyl cellulose and hydrophobically modified hydroxyethyl cellulose.

12. The aircraft anti-icing composition of claim 11 , wherein the polysaccharides are xanthan gum, guar gum or carageenan.

13. The aircraft anti-icing composition of claim 1 , further comprising one or more components selected from the group consisting of surfactants, corrosion inhibitors, anti-foamers, colorants and fire inhibitors.

14. The aircraft anti-icing composition of claim 1 , further comprising a pH control agent selected from triethylamine and potassium hydroxide.

15. The aircraft anti-icing composition of claim 1 , comprising nanocrystalline cellulose in an amount of 0.5% by weight of the anti-icing composition and hydroxyethyl cellulose in an amount of 0.2% by weight of the anti-icing composition as the thickener.

16. A process for the use of nanocrystalline cellulose in the manufacture of an aircraft anti-icing or de-icing composition, comprising the steps of:

a. providing an aircraft anti-icing or de-icing composition, and

b. adding nanocrystalline cellulose to the anti-icing or de-icing composition.

17. the process of claim 16 , further comprising the step of adding a freezing point depressant that is a glycol solution in water.

18. The process of claim 17 , wherein the glycol solution is added to make up at least 40% by weight of the anti-icing composition.

19. The process of claim 17 , wherein the glycol solution is added to make up between 50 to 95% by weight of the anti-icing composition.

20. The process of claim 17 , wherein the glycol solution is selected from the group consisting of ethylene glycol, propylene glycol, diethylene glycol, triethylene triol and 1,2-propane diol.

21. The process of claim 16 , wherein the nanocrystalline cellulose is added in an amount of 0.25 to 5% by weight of the anti-icing composition.

22. The process of claim 16 , wherein the nanocrystalline cellulose is added in an amount of 0.25 to 2% by weight of the anti-icing composition.

23. The process of claim 16 , wherein the nanocrystalline cellulose is added as a thickener together with one or more water soluble polymeric thickeners.

24. The process of claim 23 , wherein the polymeric thickeners are present in an amount of 0.1 to 2% by weight of the thickening composition.

25. The process of claim 23 , wherein the polymeric thickeners are present in an amount of 0.1 to 0.5% by weight of the thickening composition.

26. The process of claim 23 , wherein the water soluble polymeric thickeners are selected from the group consisting of crosslinked polyacrylates, carboxypolymethylene, polysaccharides, associative synthetic polymers, carboxymethyl cellulose, hydroxyethyl cellulose and hydrophobically modified hydroxyethyl cellulose.

27. The process of claim 26 , wherein the polysaccharides are xanthan gum, guar gum or carageenen.

28. The process of claim 23 , wherein the thickener comprises 0.5% by weight of nanocrystalline cellulose and 0.2% by weight hydroxyethyl cellulose.

29. A process for the use of nanocrystalline cellulose in the manufacture of a thickening composition comprising of the steps of:

a. providing a water soluble polymeric thickener, and

b. adding nanocrystalline cellulose to the polymeric thickener in an amount of 0.1 to 1.0% by weight of the thickening composition.

30. The process of claim 29 , wherein the polymeric thickeners are present in an amount of 0.1 to 5.0% by weight of the thickening composition.

31. The process of claim 29 , wherein the water soluble polymeric thickeners are selected from the group consisting of crosslinked polyacrylates, carboxypolymethylene, polysaccharides, associative synthetic polymers, carboxymethyl cellulose, hydroxyethyl cellulose and hydrophobically modified hydroxyethyl cellulose.

32. The process of claim 31 , wherein the polysaccharides are xanthan gum, guar gum or carrageenan.

33. The process of claim 29 , wherein the thickener comprising 0.5% by weight of nanocrystalline cellulose and 0.2% by weight hydroxyethyl cellulose.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 21, 2017
From: ALBERTA INNOVATES
To: INNOTECH ALBERTA INC.
Reel/Frame 044935/0144 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE NAME PREVIOUSLY RECORDED ON REEL 043315 FRAME 0074. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Sep 8, 2017
From: ALBERTA INNOVATES - TECHNOLOGY FUTURES
To: ALBERTA INNOVATES
Reel/Frame 043790/0646 →
CHANGE OF NAME Recorded Jul 24, 2017
From: ALBERTA INNOVATES - TECHNOLOGY FUTURE
To: ALBERTA INNOVATES
Reel/Frame 043315/0074 →
CORRECTIVE ASSIGNMENT TO ADD AN ASSIGNOR TO A DOCUMENT PREVIOUSLY RECORDED ON REEL 028396, FRAME 0430. Recorded Jul 27, 2012
From: BOLUK, YAMAN; ZHAO, LLYAN
To: ALBERTA RESEARCH COUNCIL INC.
Reel/Frame 028663/0013 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 18, 2012
From: BOLUK, YAMAN
To: ALBERTA RESEARCH COUNCIL INC.
Reel/Frame 028396/0430 →