Ferrite magnetic material
View Patent ↗An object of the present invention is to provide a ferrite magnetic material capable of providing a permanent magnet in which high Br and HcJ are kept, and which has a high Hk/HcJ. A ferrite magnetic material in accordance with a preferred embodiment has a ferrite phase having a hexagonal structure and has a main composition represented by Ca 1-w-x-y R w Sr x Ba y Fe z M m O 19 (R is at least one element of rare earth elements (including Y) essentially including La, and Bi, and M is at least one element of Co, Mn, Mg, Ni, Cu, and Zn essentially including Co), where 0.25<w<0.65, 0.01<x<0.45, 0.0002<y<0.011, y<x, 8<z<11, 1.0<w/m<2.5, and 0.017<m/z<0.065 are satisfied. The total amount of a Si component is 0.1 to 3 mass % based on the amount of the main composition, and respective elements satisfy the relationship of 1.5≦[(Ca+R+Sr+Ba)−(Fe+M)/12]/Si≦3.5.
1. A ferrite magnetic material having a main phase comprising a ferrite phase having a hexagonal structure,
wherein the ferrite magnetic material has a main composition represented by the following formula (1):
Ca 1-w-x-y R w Sr x Ba y Fe z M m O 19 (1)
(where in the formula (1), R is at least one element selected from the group consisting of rare earth elements (including Y) and Bi, and includes at least La, and M is at least one element selected from the group consisting of Co, Mn, Mg, Ni, Cu, and Zn, and includes at least Co),
w, x, y, z, and m in the formula (1) satisfying the following formulae (2), (3), (4), (5), (6), (7), (8), and (10):
0.25< w< 0.65 (2)
0.05≦ x< 0.2 (3)
0.0002< y< 0.011 (4)
y<x (5)
8< z< 11 (6)
1.0< w/m< 2.5 (7)
0.017< m/z< 0.065 (8), and
0.05<(1 −w−x−y )<0.59 (10),
the ferrite magnetic material includes at least a Si component as a sub-component, the total amount of the Si component being 0.1 to 3 mass % based on the amount of the main composition, and
the mole ratios of Ca, R, Sr, Ba, Fe, M, and Si satisfy the following formula (9):
1.5≦[(Ca+R+Sr+Ba)−(Fe+M)/12]/Si≦3.5. (9)
2. A magnet comprising the ferrite magnetic material according to claim 1 , the magnet having an arc segment shape, and having a central angle of the shape of 30° or more.
3. The magnet according to claim 2 , wherein the central angle is 60° or more.