Process for the preparation of isocyanates in the gas phase
View Patent ↗Isocyanates are produced by reacting a primary amine with phosgene in the gas phase. In this process, the amine is vaporized and then superheated prior to introduction into the reactor. The amine is superheated to a temperature at least 10° C. above dew point before entry into the reactor. A pressure difference between the vaporizer and entry into the reactor of from 1 to 500 mbar is maintained.
1. A process for the production of an isocyanate comprising reacting a primary amine with phosgene in a reactor in the gas phase the process comprising the following steps:
(a) vaporizing the amine in a vaporizer, the vaporized amine containing droplets,
(b) superheating the vaporized amine in a feed to the reactor to a temperature at least 15° C. above dew point in the feed directly before entry into the reactor, wherein either (i) no device for drop separation is included in the feed to the reactor, or (ii) a drop separator which has a drop diameter limit of from 5 to 550 micron is arranged in the feed to the reactor,
(c) allowing the vaporized amine to remain in the feed to the reactor for a dwell time of more than 0.08 seconds,
(d) maintaining a pressure difference between exit of the vaporizer and entry into the reactor of from 1 to 500 mbar, and
(e) introducing the superheated amine into the reactor via the feed.
2. The process of claim 1 in which the amine is toluene diamine, phenyldiamine, naphthyldiamine, methylene diphenyldiamine, hexamethylene diamine and/or isophorone diamine.
3. The process of claim 1 in which the dwell time of the vaporized amine in the feed is greater than 0.1 second.
4. The process of claim 1 in which (a) is carried out in the presence of an inert gas and/or in the presence of vapors of an inert solvent.
5. The process of claim 1 in which (a) is carried out at an absolute pressure of from 0.1 to 20 bars.
6. The process of claim 1 in which an after-heater is included in the feed and the vaporized amine is heated to a temperature of from 200 to 600° C.
7. The process of claim 1 , wherein a drop separator which has a drop diameter limit of from 5 to 550 micron is arranged in the feed to the reactor.
8. The process of claim 1 , wherein the primary amine is a primary aromatic amine.
9. The process of claim 8 , wherein the primary aromatic amine is toluene diamine.