Acrylic film for punching, surface light-source device and process for manufacturing optical member
View Patent ↗Provided is an acrylic film for punching excellent in transparency and free from breakage or whitening even if it is punched. The present invention is an acrylic film for punching containing a polymer (C) containing a di(meth)acrylate (A) unit represented by general formula (1) below and a mono(meth)acrylate (B) unit: —CH 2 —CR 1 —COO—(X) n —COCR 1 —CH 2 — (1) wherein (X) represents at least one repeat unit selected from C 2 H 4 O, C 3 H 6 O and C 4 H 8 O; the molecular weight of (X) n is 500 or more; and R 1 represents H or CH 3 .
1. An acrylic film comprising a polymer comprising (i) a mono(meth)acrylate unit and (ii) a di(meth)acrylate unit of formula (1):
—CH 2 —CR 1 —COO—(X) n —COCR 1 —CH 2 — (1)
wherein
(X) represents at least one repeat unit selected from the group consisting of C 2 H 4 O, C 3 H 6 O and C 4 H 8 O;
(X) n has a number-average molecular weight of 500 or more; and
R 1 represents H or CH 3 .
2. The acrylic film of claim 1 , having a thickness of 5 μm to 500 μm.
3. A process for manufacturing an optical member, the process comprising forming a fine convexoconcave configuration on at least one surface of the acrylic film of claim 1 and punching the acrylic film to obtain the optical member.
4. The process of claim 3 , wherein the fine convexoconcave configuration is formed on a processed surface by the punching.
5. A surface light-source device emitting planar light by converting light from a single or a plurality of light-sources into planar light, the device comprising
a light guide body, a light-source arranged adjacent to an edge surface of the light guide body, a light deflection device arranged in contact with a surface of the light guide body, and a reflector arranged in contact with a rear surface of the light guide body,
wherein the light guide body comprises a polymer comprising (i) a mono(meth)acrylate unit and (ii) a di(meth)acrylate unit of formula (2):
—CH 2 —CR 1 —COO—(X) n —COCR 1 —CH 2 — (2)
wherein
(X) represents at least one repeat unit selected from the group consisting of C 2 H 4 O, C 3 H 6 O and C 4 H 8 O;
(X) n has a number-average molecular weight of 500 or more; and
R 1 represents H or CH 3 .
6. The device of claim 5 , wherein a change ratio of an x value and a y value of a color coordinate of light emitted from the light deflection device versus a light guide distance from an edge surface of the light guide body is 0.00065/cm or less.
7. The device of claim 5 , wherein the single or plurality of light-sources is a light-emitting diode (LED).
8. A light guide body comprising a polymer comprising (i) a mono(meth)acrylate unit and (ii) a di(meth)acrylate unit of formula (3):
—CH 2 —CR 1 —COO—(X) n —COCR 1 —CH 2 — (3)
wherein
(X) represents at least one repeat unit selected from the group consisting of C 2 H 4 O, C 3 H 6 O and C 4 H 8 O;
(X) n has a number-average molecular weight of 500 or more; and
R 1 represents H or CH 3 .
9. A process for manufacturing an optical member, the process comprising forming a fine convexoconcave configuration on at least one surface of the acrylic film of claim 2 and punching the acrylic film to obtain the optical member.
10. The device of claim 6 , wherein the single or plurality of light-sources is a light-emitting diode (LED).
11. The acrylic film of claim 1 , wherein (X) represents C 4 H 8 O.
12. The acrylic film of claim 1 , wherein (X) n represents (C 4 H 8 O) 9 and R 1 represents CH 3 .
13. The acrylic film of claim 1 , wherein (X) n represents (C 2 H 4 O) 7.5 —(C 3 H 6 O) 18 —(C 2 H 4 O) 7.5 and R 1 represents CH 3 .
14. The acrylic film of claim 1 , wherein the mono(meth)acrylate unit is methylmethacrylate.
15. The acrylic film of claim 1 , wherein (X) n has a number-average molecular weight of 600 to 2000.
16. The acrylic film of claim 1 , wherein the polymer comprises 10 to 90% by mass, based on the mass of the polymer, of the di(meth)acrylate unit.
17. The acrylic film of claim 1 , wherein the polymer comprises 35 to 65% by mass, based on the mass of the polymer, of the di(meth)acrylate unit.
18. The acrylic film of claim 1 , having a thickness of 30 μm to 350 μm.
19. The acrylic film of claim 1 , having a stretch rate of 30% or more in a tensile test performed in accordance with JIS K6251 using a test piece of Dumbbell-form No. 1 at 23° C. and 500 mm/minute.
20. The acrylic film of claim 1 , having a stretch rate of 50% or more in a tensile test performed in accordance with JIS K6251 using a test piece of Dumbbell-form No. 1 at 23° C. and 500 mm/minute.