Reformer-gas-based reduction process with decarbonization of the fuel gas for the reformer
View Patent ↗In a process and apparatus for the reduction of metal oxides to form metalized material by contact with hot reducing gas, which is produced at least partially by catalytic reformation of a mixture of—a gas containing carbon dioxide (CO 2 ) and/or steam (H 2 O) with—gaseous hydrocarbons, the fuel gas for burners which provide the heat for the endothermal reformation processes which take place during the reformation is obtained at least partially from a partial quantity of the top gas produced during the reduction of metal oxides to form metalized material, wherein this partial quantity of the top gas, before it is used as a component of the fuel gas, is firstly subjected to dedusting and then to a CO conversion reaction, and the conversion gas obtained during the CO conversion reaction is subjected to CO 2 removal after cooling.
1. A process for the reduction of metal oxides to form metalized material by contact with hot reducing gas, wherein the reducing gas is produced at least partially by catalytic reformation, in a reformer, of a mixture of a gas containing at least one of carbon dioxide and steam with gaseous hydrocarbons, the process comprising:
providing the heat for the catalytic reformation in the reformer at least partially by the combustion of a fuel gas, and
drawing off the combustion off-gas that is produced by the combustion of the fuel gas,
wherein a partial quantity of the top gas produced during the reduction of metal oxides to form metalized material is used in the making of the fuel gas,
wherein the partial quantity of the top gas is firstly subjected to dedusting in a dedusting apparatus and then to a CO conversion reaction in a CO reactor to obtain a conversion gas having a CO 2 content, a lower CO content than the CO content of the partial quantity of the top gas, and a higher H 2 content than the partial quantity of the top gas, and the conversion gas obtained during the CO conversion reaction is subjected to CO 2 removal after cooling to obtain a CO 2 -depleted conversion gas, and the CO 2 -depleted conversion gas is used in the making of the fuel gas, and
wherein the CO reactor is located after the dedusting apparatus and before the reformer.
2. The process according to claim 1 , wherein the gas containing at least one of carbon dioxide and steam is top gas from the process for the reduction of metal oxides.
3. The process according to claim 1 , wherein the gas containing at least one of carbon dioxide and steam is export gas from a smelting reduction process or syngas from a coal gasification process.
4. The process according to claim 1 , wherein gaseous hydrocarbons are admixed to the CO 2 -depleted conversion gas in order to obtain fuel gas.
5. The process according to claim 1 , wherein the dedusting takes place in dry form.
6. The process according to claim 1 , wherein the dedusting takes place in wet form.