Extraction of gallium and/or arsenic from gallium arsenide
View Patent ↗Extracting gallium and/or arsenic from materials comprising gallium arsenide is generally disclosed. In some example embodiments, a material comprising gallium arsenide may be exposed to a first heating condition to form a first exhaust. The first exhaust may be directed to an arsenic collection bed including aluminum, which may form aluminum arsenide. The material including gallium arsenide may be exposed to a second heating condition and/or a vacuum may be applied, which may form a second exhaust. The second exhaust may be directed to a gallium collection bed including aluminum, which may form gallium alloys of aluminum.
1. A method of processing a material comprising gallium arsenide, the method comprising:
exposing a material comprising gallium arsenide to a first heating condition of about 415 degrees C. to less than about 1100 degrees C. to form a first exhaust;
forming aluminum arsenide by directing the first exhaust to an arsenic collection bed comprising aluminum;
exposing the material to a second heating condition of about 1200 degrees C. to about 1400 degrees C. and applying a vacuum to form a second exhaust; and
forming gallium alloys of aluminum by directing the second exhaust to a gallium collection bed comprising aluminum.
2. The method of claim 1 , wherein the first heating condition is about 515 degrees C. to about 715 degrees C.
3. The method of claim 1 , further comprising one or more of crushing, chopping, or pulverizing the material prior to exposing the material to the first heating condition.
4. The method of claim 1 , wherein the material comprises particles approximately 1 μm in size.
5. The method of claim 1 , further comprising monitoring the first exhaust to detect when substantially all of the arsenic has been removed from the material prior to exposing the material to the second heating condition.
6. The method of claim 1 , further comprising monitoring the second exhaust to detect when substantially all of the gallium has been removed from the material.
7. The method of claim 1 , wherein:
at least one of the arsenic collection bed and the gallium collection bed comprises aluminum powder; and
the aluminum powder comprises aluminum particles about 1 μm in size.
8. The method of claim 1 , wherein the vacuum is about 1 mTorr to about 1 Torr in pressure.
9. The method of claim 1 , wherein the vacuum is about 2 mTorr in pressure.
10. The method of claim 1 , further comprising removing the arsenic from the aluminum arsenide by heating the aluminum arsenide.
11. The method of claim 1 , further comprising removing the gallium from the gallium alloys of aluminum by heating the gallium alloys of aluminum.