IP Library Granted Patent US 9,320,701
Granted Patent B2
US 9,320,701 · App. 13/388,688 · Granted Apr 26, 2016

Sun-care compositions

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Quick Facts
Patent No.
US 9,320,701
App. No.
13/388,688
Granted
Apr 26, 2016
Kind
B2
Abstract

A sun-care composition having an SPF value of at least (15) containing (a) one or more sun-care actives; (b) a copolymer (or a terpolymer) containing (A) at least one vinyl pyrrolidone monomer and (i) at least one vinyl caprolactam monomer or (ii) at least one vinyl acetate monomer or (B) at least one vinyl caprolactam monomer and at least one vinyl acetate monomer; and (c) a pharmaceutically/cosmetically/dermatologically acceptable vehicle.

Claims (14)

1. A sun-care composition having an SPF value of at least 15 comprising an admixture of:

(a) one or more sun-care actives;

(b) a copolymer (or a terpolymer) containing at least one vinyl pyrrolidone monomer and at least one vinyl caprolactam monomer; and

(c) a pharmaceutically/cosmetically/dermatologically acceptable vehicle.

2. The composition according to claim 1 , wherein the sun-care active is selected from the group consisting of UV-A sunscreens, UV-B sunscreens, physical sun blockers and combination thereof.

3. The composition according to claim 1 , wherein the sun-care active is selected from the group consisting of p-aminobenzoic acid, oxyethylene (25 mol) p-aminobenzoate, 2-ethylhexyl p-dimethylaminobenzoate, ethyl N-oxypropylene p-aminobenzoate, glycerol p-aminobenzoate, 4-isopropylbenzyl salicylate, 2-ethylhexyl 4-methoxycinnamate, methyl diisopropylcinnamate, isoamyl 4-methoxycinnamate, diethanolamine 4-methoxycinnamate, 3-(4′-trimethylammunium)-benzyliden-bornan-2-one methylsulfate, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 2,4-dihydroxybenzophenone, 2,2′,4,4′-tetrahydroxybenzophenone, 2,2′-dihydroxy-4,4′ dimethoxybenzophenone, 2-hydroxy-4-n-octoxybenzophenone, 2-hydroxy-4-methoxy-4′-methoxybenzophenone, .beta.(2-oxoborn-3-ylidene)-tolyl-4-sulfonic acid and soluble salts thereof, 3-(4′-sulfo)benzyliden-bornan-2-one and soluble salts thereof, 3-(4′methylbenzylidene)-d,1-camphor, 3-benzylidene-d,1-camphor, benzene 1,4-di(3-methylidene-10-camphosulfonic) acid, urocanic acid, 2,4,6-tris[p-(2′-ethylhexyl-1′-oxycarbonyl)-anilino]-1,3,5-triazine, 2-[(p-(tertiobutylamido)anilino]-4,6-bis-[(p-(2′-ethylhexyl-1′-oxycarbony-1) anilino]-1,3,5-triazine, 2,4-bis {[4-(2-ethyl-hexyloxy)]-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3-,5-triazine, N-(2 et 4)-[(2-oxoborn-3-yliden)methyl]benzyl]-acrylamide, 1,4-bisbenzimidazolyl-phenylen-3,3′,5,5′-tetrasulfonic acid, the benzalmalonate-substituted polyorganosiloxanes, the benzotriazole-substituted polyorganosiloxanes (Drometrizole Trisiloxane), dispersed 2,2′-methylene-bis-[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol], solubilized 2,2′-methylene-bis-[6-(2H-benzotriazol-2-yl)-4-(methyl)phenol, cerium oxides, chromium oxides, cobalt oxides, iron oxides, red petrolatum, silicone-treated titanium dioxide, titanium dioxide, zinc oxide, and zirconium oxide and acid, salts, esters, derivatives and combinations thereof.

4. The composition according to claim 1 , having an SPF of at least 25.

5. The composition according to claim 1 , wherein said one or more sun-care actives are present in an amount of about 1 wt. % to about 50 wt. % of the total weight of the composition.

6. The composition according to claim 1 , wherein said copolymer (or terpolymer) is about 0.05 wt. % to about 10 wt. % of the total weight of the composition.

7. The composition according to claim 6 , wherein said copolymer (or terpolymer) is about 0.5 wt. % to about 2 wt. % of the total weight of the composition.

8. The composition according to claim 1 , wherein said pharmaceutically/cosmetically/dermatologically acceptable vehicle is selected from the group consisting of a cream, a lotion, an emulsion, an oil, a spray, a gel, an aerosol, an aqueous solution, a hydra-alcoholic solution, a suspension, an anhydrous solution, a powder, a serum, an ointment, a gel, a paste and combinations thereof.

9. The composition according to claim 1 , further comprising one or more additional components selected from the group consisting of skin-feel additives, moisturizing agents film former/waterproofing agents, pH adjuster/chelating agents, emulsifiers, preservatives, and mixtures thereof.

10. The sun-care composition according to claim 1 in the form of an oil-in-water emulsion, a water-in-oil emulsion, an oil-water-oil emulsion, a water-oil-water emulsion, a water-in-silicone emulsion, an oily solution, a lipid fusion, a hydro-alcoholic gel, an anhydrous gel, an aqueous gel, an alcoholic solutions or a hydro-alcoholic solution.

11. A method for enhancing the SPF-value of one or more sun-care actives in UV-photoprotecting sun-care compositions comprising admixing and intimately formulating a pharmaceutically/cosmetically/dermatologically acceptable carrier and a copolymer (or terpolymer) comprising at least one vinyl pyrrolidone monomer and at least one vinyl caprolactam monomer in an amount effective to enhance the SPF value of said one or more sun-care actives.

Assignments (6)
RELEASE OF SECURITY INTEREST Recorded Jan 10, 2020
From: THE BANK OF NOVA SCOTIA
To: AVOCA LLC; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES LLC
Reel/Frame 051557/0504 →
SECURITY AGREEMENT Recorded Jul 3, 2017
From: AVOCA, INC.; HERCULES LLC; ISP INVESTMENTS LLC; PHARMACHEM LABORATORIES, INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 043084/0753 →
CONVERSION Recorded Jan 30, 2017
From: ISP INVESTMENTS INC.
To: ISP INVESTMENTS LLC
Reel/Frame 041556/0499 →
RELEASE OF PATENT SECURITY AGREEMENT Recorded Mar 18, 2013
From: THE BANK OF NOVA SCOTIA
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; ISP INVESTMENTS INC.; HERCULES INCORPORATED
Reel/Frame 030025/0320 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 4, 2012
From: BARRETT, CHRISTINE M.; ROSS, TRACEY; GUERRERO, RITAMARIE; HOOD, DAVID K.; FARES, HANI
To: ISP INVESTMENTS INC.
Reel/Frame 028157/0553 →
SECURITY AGREEMENT Recorded Mar 6, 2012
From: HERCULES INCORPORATED; ISP INVESTMENTS INC.
To: THE BANK OF NOVA SCOTIA
Reel/Frame 027810/0519 →