Molded activated charcoal and water purifier involving same
View Patent ↗The present invention provides molded activated carbon, and the molded activated carbon is produced by molding a mixture containing powdery activated carbon (a) having a median particle size of 80 μm to 120 μm and a standard deviation σg of 1.3 to 1.9 in a particle size distribution and a fibrous binder (b). The molded activated carbon of the present invention has excellent removability for free residual chlorine, volatile organic compounds, CAT, and 2-MIB and excellent turbidity filterability, and is for use as a water purifier cartridge or the like.
1. A molded activated carbon produced by molding a mixture comprising powdery activated carbon (a) having a median particle size of 80 μm to 120 μm, a standard deviation σg of 1.3 to 1.9 in a particle size distribution and a standard deviation σp of 0.3 to 0.5 in the particle size distribution; and a fibrous binder (b),
the standard deviation σg being expressed as D 15.87 /D 50 , where D 15.87 is a value of a diameter at 15.87% in a volume-based cumulative fraction in a case where a volume integral is obtained from large particles of the powdery activated carbon in a volume-average particle size distribution, and D 50 is a value of a diameter at 50% in a volume-based cumulative fraction in a case where a volume integral is obtained from large particles of the powdery activated carbon in a volume-average particle size distribution, and
the standard deviation σp is expressed as D 84.13 /D 50 , where D 84.13 is a value of a diameter at 84.13% in a volume-based cumulative fraction in a case where a volume integral is obtained from large particles of the powdery activated carbon in a volume-average particle size distribution, and D 50 is a value of a diameter at 50% in a volume-based cumulative fraction in a case where a volume integral is obtained from large particles of the powdery activated carbon in a volume-average particle size distribution.
2. The molded activated carbon of claim 1 , wherein the mixture further comprises an amorphous titanosilicate-based inorganic compound or an aluminosilicate-based inorganic compound (c).
3. The molded activated carbon of claim 1 , wherein the powdery activated carbon (a) has a benzene adsorption amount of 20 to 60 wt %.
4. The molded activated carbon of claim 1 , wherein the mixture comprises the fibrous binder (b) in a proportion of 3 to 8 parts by weight relative to 100 parts by weight of the powdery activated carbon (a).
5. The molded activated carbon of claim 1 , wherein the powdery activated carbon (a) is coconut shell-based activated carbon powder or phenolic resin-based activated carbon powder.
6. The molded activated carbon of claim 1 , wherein any activated carbon contained in the molded activated carbon is entirely the powdery activated carbon (a).
7. A water purifying filter comprising the molded activated carbon of claim 1 .
8. A cartridge wherein a housing is filled with the molded activated carbon of claim 1 .
9. A water purifier comprising the cartridge of claim 8 .
10. The water purifier of claim 9 , having (i) a turbidity removal efficiency of no less than 80% and (ii) a turbidity filterability of no less than 15 L per 1 mL of molded activated carbon.
11. A cartridge wherein a housing is filled with the water purifying filter of claim 7 .
12. A water purifier comprising the cartridge of claim 11 .
13. The water purifier of claim 12 , having (i) a turbidity removal efficiency of no less than 80% and (ii) a turbidity filterability of no less than 15 L per 1 mL of molded activated carbon.
14. The molded activated carbon of claim 1 , wherein the powdery activated carbon (a) has a standard deviation σp of 0.36 to 0.45 in the particle size distribution.
15. The molded activated carbon of claim 1 , wherein the powdery activated carbon (a) has a benzene adsorption amount of 25 to 40 wt %.
16. The molded activated carbon of claim 1 , wherein the mixture comprises the fibrous binder (b) in a proportion of 3.5 to 6 parts by weight relative to 100 parts by weight of the powdery activated carbon (a).
17. The molded activated carbon of claim 1 , wherein a fiber length of the fibrous binder is 4 mm or less.
18. The molded activated carbon of claim 1 , wherein the mixture further comprises 3 to 10 parts by weight of an amorphous titanosilicate-based inorganic compound, based on 100 parts by weight of powdery activated carbon.
19. The molded activated carbon of claim 1 , wherein the mixture further comprises 3 to 10 parts by weight of an aluminosilicate-based inorganic compound, based on 100 parts by weight of powdery activated carbon.