Low-temperature and average-temperature refrigeration
View Patent ↗The invention relates to binary compositions of 2,3,3,3-tetrafluoropropene and difluoromethane, as a heat transfer fluid in compression, low-temperature and average temperature refrigeration systems, with exchangers operating in counterflow mode or in split flow mode with counterflow tendency. The invention also relates to a heat transfer method.
1. A method of replacing R-404A in a compression-type low- and medium-temperature refrigeration system, with exchangers operating in countercurrent mode or in crossed-current mode with countercurrent tendency, the method comprising replacing R-404A or R-407C with a composition comprising a refrigerant, the refrigerant consisting of from 61 to 85 wt. % of 2,3,3,3-tetrafluoropropene and from 15 to 39 wt. % difluoromethane.
2. The method of replacing R-404A as claimed in claim 1 , wherein the refrigerant consists of from 70 to 79 wt. % of 2,3,3,3-tetrafluoropropene and from 21 to 30 wt. % of difluoromethane.
3. The method of replacing R-404A as claimed in claim 1 , wherein the composition further comprises a stabilizer.
4. The method of replacing R-404A as claimed in claim 3 , wherein the stabilizer is selected from the group consisting of nitromethane, ascorbic acid, terephthalic acid, azoles, phenolic compounds, epoxides, phosphites, phosphates, phosphonates, thiols and lactones.
5. The method of replacing R-404A as claimed in claim 3 , wherein stabilizer represents at most 5% by weight relative to the refrigerant.
6. The method of replacing R-404A as claimed in claim 1 , wherein the composition further comprises a lubricant.
7. The method of replacing R-404A as claimed in claim 6 , wherein the lubricant is selected from the group consisting of mineral oil, alkylbenzene, polyalkylene glycol and polyvinyl ether.
8. The method of replacing R-404A as claimed in claim 1 , wherein the low- and medium-temperature refrigeration system has a range from −45° C. to −10° C. at an evaporator.