IP Library Granted Patent US 9,011,711
Granted Patent B2
US 9,011,711 · App. 13/391,417 · Granted Apr 21, 2015

Heat transfer fluid replacing R-410A

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Quick Facts
Patent No.
US 9,011,711
App. No.
13/391,417
Granted
Apr 21, 2015
Kind
B2
Abstract

The invention relates to a heat transfer method using a ternary composition containing 2,3,3,3-tetrafluoropropene, 1,1-difluoroethane and difluoromethane, as a heat transfer fluid in refrigeration systems, to replace the R-410A mixture.

Claims (14)

1. A method of modifying a heat transfer system containing R-410A comprising removing R-410A and adding refrigerant comprising a ternary composition consisting essentially of from 5 to 83 wt % of 2,3,3,3-tetrafluoropropene, from 15 to 75 wt. % of difluoromethane, and from 2 to 40 wt. % of 1,1-difluoroethane.

2. The method as claimed in claim 1 , wherein the ternary composition consists essentially of from 5 to 63 wt. % of 2,3,3,3-tetrafluoropropene and from 35 to 70 wt. % of difluoromethane and from 2 to 25 wt. % of 1,1-difluoroethane.

3. The method as claimed in claim 1 , wherein the refrigerant further comprises a stabilizer.

4. The method as claimed in claim 3 , wherein the stabilizer is selected from the group consisting of nitromethane, ascorbic acid, terephthalic acid, azoles, phenolic compounds, epoxides, phosphites, phosphates, phosphonates, thiols and lactones.

5. The method as claimed in claim 3 , wherein stabilizer represents at most 5% by weight relative to the refrigerant.

6. The method as claimed in claim 1 , wherein the heat transfer system is of the compression type.

7. The method as claimed in claim 6 , wherein the heat transfer system operate with exchangers in countercurrent mode or in crossed-current mode with countercurrent tendency.

8. The method as claimed in claim 6 , wherein the refrigerant consists of from 5 to 83 wt. % of 2,3,3,3-tetrafluoropropene, from 15 to 75 wt. % of difluoromethane and from 2 to 40 wt. % of 1,1-difluoroethane, and optionally, a stabilizer and/or lubricant.

9. The method as claimed in claim 6 , wherein the refrigerant consists of from 5 to 63 wt. % of 2,3,3,3-tetrafluoropropene and from 35 to 70 wt. % of difluoromethane and from 2 to 25 wt. % of 1,1-difluoroethane, and optionally, a stabilizer and/or lubricant.

10. The method as claimed in claim 6 , wherein the refrigerant consists of from 40 to 58 wt. % of 2,3,3,3-tetrafluoropropene and from 40 to 50 wt. % of difluoromethane and from 2 to 10 wt. % of 1,1-difluoroethane, and optionally, a stabilizer and/or lubricant.

11. The method as claimed in claim 1 , wherein the heat transfer system is of the compression type operating with exchangers in countercurrent mode or in crossed-current mode with countercurrent tendency.

12. The method as claimed in claim 1 , wherein the ternary composition consists essentially of from 40 to 58 wt. % of 2,3,3,3-tetrafluoropropene and from 40 to 50 wt. % of difluoromethane and from 2 to 10 wt. % of 1,1-difluoroethane.

13. The method as claimed in claim 1 , wherein the refrigerant further comprises a lubricant.

14. The method as claimed in claim 13 , wherein the lubricant is selected from the group consisting of mineral oil, alkylbenzene, polyalkylene glycol and polyvinyl ether.

Assignments (3)
CHANGE OF ADDRESS Recorded Jul 4, 2025
From: ARKEMA FRANCE
To: ARKEMA FRANCE
Reel/Frame 071814/0739 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE SHOULD BE ARKEMA FRANCE NOT ARKEMA INC. PREVIOUSLY RECORDED ON REEL 027780 FRAME 0812. ASSIGNOR(S) HEREBY CONFIRMS THE PLEASE UPDATE THE ASSIGNEE FROM ARKEMA INC. TO ARKEMA FRANCE.. Recorded Mar 19, 2012
From: RACHED, WISSAM
To: ARKEMA FRANCE
Reel/Frame 027883/0580 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 29, 2012
From: RACHED, WISSAM
To: ARKEMA INC.
Reel/Frame 027780/0812 →