Biaxially oriented polyester film
View Patent ↗The present invention provides a polyester film which is excellent in hydrolysis resistance of a base film, is hardly deteriorated in adhesion property to various members or top-coating agents, and can suitably used, for example, as a film for a protective member for protecting a back surface of solar cells. The present invention relates to a biaxially oriented polyester film in the form of a laminated film comprising a biaxially oriented polyester base film having a phosphorus element content of 0 to 170 ppm and a terminal carboxylic acid content of not more than 26 equivalents/t, and a coating layer formed on at least one surface of the biaxially oriented polyester base film which comprises a polyurethane having a polycarbonate skeleton or a polyether skeleton and a crosslinking agent, wherein the laminated film has a haze value of not more than 10%.
1. A biaxially oriented polyester film in the form of a laminated film comprising;
a biaxially oriented polyester base film having a phosphorus element content of 0 to 170 ppm and a terminal carboxylic acid content of not more than 26 equivalents/t, and
a coating layer formed on at least one surface of the biaxially oriented polyester base film which comprises a polyurethane having a polycarbonate skeleton or a polyether skeleton and a crosslinking agent,
wherein the laminated film has a haze value of not more than 10%, wherein the coating layer comprises no polyester-based. resin and polyester polyurethane resin, or the coating layer comprises a polyester-based. resin and polyester polyurethane resin in the amount of less than 10% by weight based on the weight of coating layer,
the laminated film further comprising a solar cell sealing resin layer directly laminated on the coating layer, which solar cell sealing resin layer comprises at least one member selected from the group consisting of ethyiene-vinyl acetate copolymer, polyvinyl butyral, ethylene-methyl acrylate copolymers, ethylene-ethyl acrylate copolymers and ethylene-α-olefin copolymers.
2. The biaxially oriented polyester film according to claim 1 , wherein the crosslinking agent is a polymer having an oxazoline group or a carbodiimide group.
3. The biaxially oriented polyester film according to claim 1 , wherein a total amount of the polyurethane and the crosslinking agent in the coating layer is not less than 50% by weight, and a weight ratio of the polyurethane to the crosslinking agent is 10:90 to 90:10.
4. The biaxially oriented polyester film according to claim 1 , wherein the biaxially oriented polyester film is produced by using a polyester obtained by solid-state polymerization as a part or whole of a raw material therefor.
5. The biaxially oriented polyester film according to claim 1 , wherein the coating layer comprises a polyurethane having a polyether skeleton and a crosslinking agent,
wherein the coating layer comprises no resin other than the polyurethane having the polyether skeleton, or the coating layer comprises a resin other than the polyurethane having the polyether skeleton in the amount of less than 10 % by weight based on the weight of coating layer.
6. The biaxially oriented polyester film according to claim 1 , wherein the polyether skeleton is derived from polytetramethylene glycol.