Hydrophilic aliphatic polyurethane foams
View Patent ↗The invention relates to hydrophilic aliphatic polyurethane foams obtained by reacting special prepolymers having a low monomer concentration and hydrophilic polyisocyanates in the presence of water. The absorptive properties make said polyurethane foams particularly suitable for producing wound dressings, cosmetic articles, or incontinence products.
1. Process for preparing hydrophilic aliphatic polyurethane foams consisting essentially of mixing
A) isocyanate-functional prepolymers having a weight fraction of low molecular weight aliphatic diisocyanates having a molar mass of 140 to 278 g/mol of below 1.0% by weight based on the prepolymer, obtainable by reaction of
A1) low molecular weight aliphatic diisocyanates having a molar mass of 140 to 278 g/mol with
A2) di- to hexafunctional polyalkylene oxides having an OH number of 22.5 to 112 mg KOH/g and an ethylene oxide content of 50 to 100 mol % based on the total amount of oxyalkylene groups present,
with
B) optionally heterocyclic 4-ring or 6-ring oligomers of low molecular weight aliphatic diisocyanates having a molar mass of 140 to 278 g/mol,
C) water,
D) optionally catalysts,
E) optionally C 8 -C 22 monocarboxylic acids or their ammonium or alkali metal salts or C 12 -C 44 dicarboxylic acids or their ammonium or alkali metal salts,
F) optionally surfactants, and
G) optionally mono- or polyhydric alcohols, and
H) hydrophilic polyisocyanates obtainable by reaction of
H1) low molecular weight aliphatic diisocyanates having a molar mass of 140 to 278 g/mol and/or polyisocyanates obtainable therefrom with an isocyanate functionality of 2 to 6, with
H2) monofunctional polyalkylene oxides having an OH number of 10 to 250, and an ethylene oxide content of 50 to 100 mol % based on the total amount of oxyalkylene groups present,
to form a mixture,
foaming the mixture by means of carbon dioxide formed in the course of the reaction of the isocyanate groups of the prepolymers A) with water C) and optionally by the use of further blowing agents and
curing the mixture by chemical crosslinking.
2. The process according to claim 1 , wherein the monofunctional polyalkylene oxide H2) has an OH number of 20 to 112.
3. The process according to claim 1 , wherein the monofunctional polyalkylene oxide H2) has an ethylene oxide content of 60 to 90 mol % based on the total amount of oxyalkylene groups present.
4. The process according to claim 1 , wherein the NCO content of the isocyanate-functional prepolymer A) is 1.5% to 3.0% by weight.
5. The process according to claim 1 , wherein A1) consists of an hexamethylene diisocyanate (HDI), an isophorone diisocyanate (IPDI) or mixtures thereof.
6. The process according to claim 1 , wherein the polyalkylene oxide A2) comprises a copolymer of ethylene oxide and propylene oxide having an ethylene oxide content, based on the total amount of oxyalkylene groups present, of 60 to 85 mol % and started on polyols or amines.
7. The process according to claim 1 , wherein the polyalkylene oxide of component A2) has a number average molecular weight of 3000 to 8500 g/mol.
8. The process according to claim 1 , wherein the polyalkylene oxide of A2) has OH functionalities of 3 to 4.
9. The process according to claim 1 , wherein component B) is present and comprises an heterocyclic 4-ring oligomer.
10. The process according to claim 1 , wherein the catalyst D) comprises a metal salt, an amine, an amidine and/or a guanidine.
11. The process according to claim 1 , wherein components A) to H) are used in the following amounts:
100 parts by weight of isocyanate-functional prepolymers A)
0 to 30 parts by weight of heterocyclic oligomers B)
0.1 to 200 parts by weight of water C)
0 to 1 part by weight of catalysts D)
0 to 5 parts by weight of C 8 -C 12 monocarboxylic acids or their ammonium or alkali metal salts or C 12 -C 44 dicarboxylic acids or their ammonium or alkali metal salts E),
0 to 10 parts by weight of surfactants F)
0 to 20 parts by weight of alcohols G)
5 to 250 parts by weight of hydrophilic polyisocyanates H).
12. A polyurethane foam obtained by the process according to claim 1 .
13. A wound dressing, cosmetic article or incontinence product obtained from the polyurethane foam according to claim 12 .
14. The process according to claim 1 , wherein components A) to H) are used in the following amounts:
100 parts by weight of isocyanate-functional prepolymers A)
0 to 30 parts by weight of heterocyclic oligomers B)
1 to 60 parts by weight of water C)
0 to 1 part by weight of catalysts D)
0 to 5 parts by weight of C 8 -C 12 monocarboxylic acids or their ammonium or alkali metal salts or C 12 -C 44 dicarboxylic acids or their ammonium or alkali metal salts E),
0 to 10 parts by weight of surfactants F)
0 to 20 parts by weight of alcohols G)
5 to 250 parts by weight of hydrophilic polyisocyanates H).