Resin-coated metal pigment, and process for producing same
Disclosed is a resin-coated metal pigment comprising 100 parts by weight of a metal pigment and 0.1 to 50 parts by weight of a resin, wherein the resin is attached on the surface of the metal pigment. The resin-coated metal pigment is produced by circulating a portion of a slurry solution containing the metal pigment in an external-circulation type vessel during the resin coating treatment in a reaction vessel and applying a vibration to the external-circulation type vessel with an ultrasonic wave.
1. A resin-coated metal pigment, wherein a proportion between (A) the number of particles contained in aggregates formed from two or more primary particles and (B) the number of primary particles which are not aggregated, B/(A+B), in the resin-coated metal pigment, is 0.3 to 1,
wherein the metal pigment is a scaly aluminum pigment, and
wherein a measured value of the 60-degree gloss of a coated plate obtained by applying a paint containing said resin-coated metal pigment to an acrylic resin plate is represented by G′; a measured value of the 60-degree gloss of a coated plate similarly prepared using an aluminum powder that is not coated with a resin is represented by G; and a gloss retention R is determined by the following formula: R=(G′/G)×100; and the gloss retention R is 70 or more.
2. The resin-coated metal pigment according to claim 1 , wherein unevenness of a resin coating layer adhering to a surface of the resin-coated metal pigment is 25 nm or less.
3. The resin-coated metal pigment according to claim 1 , wherein the resin-coated metal pigment has an alkali resistance represented by color difference ΔE of less than 1.0, wherein the alkali resistance is evaluated by a method in which when a coated plate obtained by coating an acrylic resin with a coating material containing the resin-coated metal pigment is immersed in a 2.5 N sodium hydroxide solution at 20° C. for 24 hours, the alkali resistance is represented by color difference ΔE between an immersion part and a non-immersion part.
4. The resin-coated metal pigment according to claim 1 , wherein the amount of gas generated is 10 ml or less when an aqueous coating material containing the resin-coated metal pigment is kept warm at 40° C. for 8 hours.
5. The resin-coated metal pigment according to claim 1 , wherein a difference between an average particle size of particles of a resin-coated metal pigment and an average particle size of particles of a metal pigment before being coated with a resin is larger than 0 and 5 μm or less.
6. The resin-coated metal pigment according to claim 5 , wherein unevenness of a resin coating layer adhering to a surface of the resin-coated metal pigment is 25 nm or less.
7. The resin-coated metal pigment according to claim 5 , wherein the resin-coated metal pigment has an alkali resistance represented by color difference ΔE of less than 1.0, wherein the alkali resistance is evaluated by a method in which when a coated plate obtained by coating an acrylic resin with a coating material containing the resin-coated metal pigment is immersed in a 2.5 N sodium hydroxide solution at 20° C. for 24 hours, the alkali resistance is represented by color difference ΔE between an immersion part and a non-immersion part.
8. The resin-coated metal pigment according to claim 5 , wherein the amount of gas generated is 10 ml or less when an aqueous coating material containing the resin-coated metal pigment is kept warm at 40° C. for 8 hours.