Ink composition, inkjet recording method, printed material, method for producing planographic printing plate, and planographic printing plate
View Patent ↗The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B′) an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.
1. An inkjet recording composition comprising an ink composition, the ink composition comprising:
(a) a polymerization initiator comprising an aromatic ketone or an acylphosphine oxide compound;
(b) an ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton which is represented by the following formula (B-2) and having a content ratio of 3 to 35% by mass relative to the total mass of the ink composition;
(c) a pigment; and
(d) an additional polymerizable compound which is other than the (b) ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton:
which comprises a monoacrylate and which does not comprise an oligomer,
wherein the viscosity of the ink composition at an ejection temperature of from 40 to 80° C. is from 7 to 30 mPa·s.
2. The inkjet recording composition according to claim 1 , wherein the content of the monoacrylate compound is 40% by mass or more based on the total mass of the (d) additional polymerizable compound.
3. The inkjet recording composition according to claim 1 , wherein the ink composition further comprises a solvent in an amount of from 0.1 to 3% by mass with respect to the total mass of the ink composition.
4. The inkjet recording composition according to claim 1 , wherein the (d) additional polymerizable compound further comprises a polyfunctional acrylate monomer.
5. The inkjet recording composition according to claim 4 , wherein the polyfunctional acrylate monomer has a molecular weight of 400 or more.
6. The inkjet recording composition according to claim 1 , wherein the (d) additional polymerizable compound comprises a combination of a monoacrylate and a polyfunctional acrylate monomer.
7. The inkjet recording composition according to claim 6 , wherein the polyfunctional acrylate monomer has a molecular weight of 400 or more.
8. The inkjet recording composition according to claim 1 , wherein the surface tension of the ink composition is from 20 to 30 mN/m.
9. The inkjet recording composition according to claim 1 , wherein the ink composition further comprises a sensitizing dye.
10. The inkjet recording composition according to claim 1 , wherein the ink composition further comprises a polymerization inhibitor.
11. The inkjet recording composition according to claim 1 , wherein the content of the (b) ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is from 4 to 25% by mass relative to the total mass of the ink composition.
12. The inkjet recording composition according to claim 1 , wherein the ink composition further comprises a surfactant.
13. The inkjet recording composition according to claim 1 , wherein the (d) additional polymerizable compound further comprises a vinyl ether compound.
14. The inkjet recording composition according to claim 1 , wherein the (a) polymerization initiator comprises an acylphosphine oxide compound.
15. The inkjet recording composition according to claim 1 , wherein the content of the (b) ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is from 11 to 35% by mass relative to the total mass of the ink composition.