Methods of fabricating a polycrystalline diamond body with a sintering aid/infiltrant at least saturated with non-diamond carbon and resultant products such as compacts
View Patent ↗Embodiments of the invention relate to methods of fabricating a polycrystalline diamond compacts and applications for such polycrystalline diamond compacts. In an embodiment, a method of fabricating a polycrystalline diamond body includes mechanically milling non-diamond carbon and a sintering aid material for a time and aggressiveness sufficient to form a plurality of carbon-saturated sintering aid particles and sintering a plurality of diamond particles in the presence of the plurality of carbon-saturated sintering aid particles to form the polycrystalline diamond body.
1. A method of fabricating a polycrystalline diamond compact, comprising:
mechanically milling non-diamond carbon and a sintering aid material for a time and aggressiveness sufficient to form a plurality of carbon-saturated sintering aid particles; and
sintering a plurality of diamond particles in the presence of the plurality of carbon-saturated sintering aid particles to form a polycrystalline diamond table, wherein the carbon-saturated sintering aid particles catalyzes formation of diamond-to-diamond bonding between the plurality of diamond particles used to form the polycrystalline diamond table.
2. The method of claim 1 wherein mechanically milling non-diamond carbon and a sintering aid material for a time and aggressiveness sufficient to form a plurality of carbon-saturated sintering aid particles comprises ball milling, attritor milling, horizontal ball milling, or high energy ball milling the non-diamond carbon and the sintering aid material.
3. The method of claim 1 wherein the time is less than about 2200 hours.
4. The method of claim 1 wherein the time is about 100 hours to about 1100 hours.
5. The method of claim 1 wherein the time is about 150 hours to about 700 hours.
6. The method of claim 1 wherein the time is about 200 hours to about 500 hours.
7. The method of claim 1 wherein the plurality of sintering aid particles comprises at least one member selected from the group consisting of cobalt, nickel, iron, copper, aluminum, titanium, tungsten, niobium, zirconium, tantalum, silicon, and boron.
8. The method of claim 1 wherein the plurality of sintering aid particles comprises at least one member selected from the group consisting of copper, aluminum, and tungsten.
9. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of greater than about 0.01 atomic %.
10. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 0.01 atomic % to about 35 atomic %.
11. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 10 atomic % to about 30 atomic %.
12. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 5 atomic % to about 25 atomic %.
13. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 20 atomic % to about 30 atomic %.
14. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 10 atomic % to about 20 atomic %.
15. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 5 atomic % to about 15 atomic %.
16. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 1 atomic % to about 10 atomic %.
17. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 25 atomic % to about 30 atomic %.
18. The method of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 20 atomic % to about 25 atomic %.
19. The method of claim 1 wherein the non-diamond carbon comprises at least one member selected from the group consisting of lamp black, graphite, carbon-12 graphite, carbon-13 graphite, carbon-14 graphite, carbon nanotubes, graphene, amorphous carbon, amorphous carbon-12, amorphous carbon-13, amorphous carbon-14, carbon-12, carbon-13, carbon-14, and fullerenes.
20. The method of claim 1 , further comprising:
prior to the act of sintering, assembling the plurality of carbon-saturated sintering aid particles between the plurality of diamond particles and a substrate to form an assembly; and
wherein sintering a plurality of diamond particles in the presence of the plurality of carbon-saturated sintering aid particles to form a polycrystalline diamond table comprises subjecting the assembly to a high-pressure/high-temperature process effective to infiltrate the plurality of diamond particles with a carbon-saturated infiltrant from the plurality of carbon-saturated sintering aid particles to sinter the plurality of diamond particles and form the polycrystalline diamond table that bonds to the substrate.
21. The method of claim 20 , further comprising:
removing the polycrystalline diamond table from the substrate;
leaching the polycrystalline diamond table to at least partially remove sintering aid material, provided from the carbon-saturated infiltrant, from the polycrystalline diamond table to form an at least partially leached polycrystalline diamond table; and
bonding the at least partially leached polycrystalline diamond table to an additional substrate to form an additional polycrystalline diamond compact.
22. A method of fabricating a polycrystalline diamond body, comprising:
mechanically milling non-diamond carbon and a sintering aid material for a time sufficient to form a plurality of carbon-saturated sintering aid particles;
mixing the plurality of carbon-saturated sintering aid particles and a plurality of diamond particles to form a mixture; and
subjecting the mixture to a high-pressure/high-temperature process effective to sinter the plurality of diamond particles and form the polycrystalline diamond body.
23. A method of fabricating a polycrystalline diamond compact, comprising:
mechanically milling non-diamond carbon with a sintering aid material for a time sufficient to form a plurality of carbon-saturated sintering aid particles;
sintering a plurality of diamond particles in the presence of the plurality of carbon-saturated sintering aid particles to form a polycrystalline diamond table, wherein the carbon-saturated sintering aid particles catalyzes formation of diamond-to-diamond bonding between the plurality of diamond particles used to form the polycrystalline diamond table;
at least partially leaching a sintering aid material from the polycrystalline diamond table to form an at least partially leached polycrystalline diamond table;
forming an assembly including the at least partially leached polycrystalline diamond table positioned at least proximate to a substrate; and
subjecting the assembly to a high-pressure/high-temperature process effective to infiltrate the at least partially leached polycrystalline diamond table with an infiltrant and bond the infiltrated polycrystalline diamond table to the substrate.
24. The method of claim 22 wherein the time is about 100 hours to about 1100 hours.
25. The method of claim 22 wherein the time is about 150 hours to about 700 hours.
26. The method of claim 22 wherein the time is about 200 hours to about 500 hours.
27. The method of claim 22 wherein the plurality of sintering aid particles comprises at least one member selected from the group consisting of cobalt, nickel, iron, copper, aluminum, titanium, tungsten, niobium, zirconium, tantalum, silicon, and boron.
28. The method of claim 22 wherein the plurality of sintering aid particles comprises at least one member selected from the group consisting of copper, aluminum, and tungsten.
29. The method of claim 22 wherein the non-diamond carbon comprises at least one member selected from the group consisting of lamp black, graphite, carbon-12 graphite, carbon-13 graphite, carbon-14 graphite, carbon nanotubes, graphene, amorphous carbon, amorphous carbon-12, amorphous carbon-13, amorphous carbon-14, carbon-12, carbon-13, carbon-14, and fullerenes.