IP Library Granted Patent US 12,565,695
Granted Patent B2
US 12,565,695 · App. 13/399,975 · Granted Mar 3, 2026

2XXX series aluminum lithium alloys

Inventors: Julien Boselli (Pittsburgh, PA); Roberto J. Rioja (Murrysville, PA); Gregory B. Venema (Bettendorf, IA); Ralph R. Sawtell (Gibsonia, PA)
Assignee: ARCONIC TECHNOLOGIES LLC
C22C21/00C22C21/12C22C21/16C22C21/18C22F1/04C22F1/057
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Quick Facts
Patent No.
US 12,565,695
App. No.
13/399,975
Granted
Mar 3, 2026
Kind
B2
Abstract

Thick wrought 2xxx aluminum lithium alloy products are disclosed. The wrought aluminum alloy products have a thickness of at least 12.7 mm and contain from 3.00 to 3.80 wt. % Cu, from 0.05 to 0.35 wt. % Mg, from 0.975 to 1.385 wt. % Li, wherein −0.3*Mg−0.15Cu+1.65≤Li≤−0.3*Mg−0.15Cu+1.85, from 0.05 to 0.50 wt. % of at least one grain structure control element, wherein the grain structure control element is selected from the group consisting of Zr, Sc, Cr, V, Hf, other rare earth elements, and combinations thereof, up to 1.0 wt. % Zn, up to 1.0 wt. % Mn, up to 0.12 wt. % Si, up to 0.15 wt. % Fe, up to 0.15 wt. % Ti, up to 0.10 wt. % of any other element, with the total of these other elements not exceeding 0.35 wt. %, the balance being aluminum.

Claims (22)

1 . An aluminum alloy product, the aluminum alloy consisting of:

from 3.20 to 3.60 wt. % Cu;

from 0.15 to 0.30 wt. % Mg;

from 1.05 to 1.25 wt. % Li;

from 0.05 to 0.50 wt. % of at least one grain structure control element, wherein the at least one grain structure control element is selected from the group consisting of Zr, Sc, Cr, V, Hf, and combinations thereof;

from 0.20 to 1.0 wt. % Zn;

from 0.2 to 0.5 wt. % Mn;

up to 0.12 wt. % Si;

up to 0.15 wt. % Fe;

up to 0.15 wt. % Ti;

up to 0.05 wt. % of any other element, with the total of these other elements not exceeding 0.15 wt. %, wherein the other elements include silver (Ag); and

the balance being aluminum,

wherein the aluminum alloy product has a thickness of 50.8-76.2 mm and realizes a strength-toughness relationship that satisfies the expression:

FT-SL≥=−0.199(TYS−ST)+116;

wherein TYS-ST is the ST tensile yield strength of the plate in MPa as measured in accordance with ASTM Standard E8 and ASTM B557,

wherein FT-SL is the S-L plane strain fracture toughness (KIC) of the plate in MPa√Vm as measured in accordance with ASTM E399,

wherein the aluminum alloy product realizes a TYS-ST of at least 400 MPa, and wherein the aluminum alloy product realizes a FT-SL of at least about 22 MPa√m.

2 . The aluminum alloy product of claim 1 , wherein the grain structure control element is at least Zr, and wherein the alloy contains 0.05 to 0.20 wt. % Zr.

3 . The aluminum alloy product of claim 1 , comprising at least 3.40 wt. % Cu.

4 . The aluminum alloy product of claim 1 , comprising not greater than 0.25 wt. % Mg.

5 . The aluminum alloy product of claim 4 , comprising at least 1.150 wt. % Li.

6 . The aluminum alloy product of claim 4 , comprising not greater than 0.50 wt. % Zn.

Assignments (12)
RELEASE OF SECURITY INTEREST Recorded Aug 22, 2023
From: U.S. BANK NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
To: ARCONIC TECHNOLOGIES LLC
Reel/Frame 064661/0283 →
RELEASE OF SECURITY INTEREST Recorded Aug 22, 2023
From: DEUTSCHE BANK AG NEW YORK BRANCH
To: ARCONIC TECHNOLOGIES LLC
Reel/Frame 064661/0409 →
NOTICE OF GRANT OF SECURITY INTEREST IN INTELLECTUAL PROPERTY (FIRST LIEN) Recorded Aug 18, 2023
From: ARCONIC TECHNOLOGIES LLC
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 064641/0781 →
NOTICE OF GRANT OF SECURITY INTEREST (ABL) IN INTELLECTUAL PROPERTY Recorded Aug 18, 2023
From: ARCONIC TECHNOLOGIES LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 064641/0798 →
SECURITY INTEREST Recorded May 14, 2020
From: ARCONIC TECHNOLOGIES LLC
To: DEUTSCHE BANK AG NEW YORK BRANCH
Reel/Frame 052672/0425 →
RELEASE OF SECURITY INTEREST Recorded May 14, 2020
From: JPMORGAN CHASE BANK, N.A.
To: ARCONIC TECHNOLOGIES LLC
Reel/Frame 052671/0850 →
SECURITY INTEREST Recorded May 14, 2020
From: ARCONIC TECHNOLOGIES LLC
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 052671/0937 →
PATENT SECURITY AGREEMENT Recorded Mar 31, 2020
From: ARCONIC TECHNOLOGIES LLC
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 052272/0669 →
SECURITY INTEREST Recorded Mar 26, 2020
From: ARCONIC TECHNOLOGIES LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 052235/0826 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 10, 2020
From: ARCONIC INC.
To: ARCONIC TECHNOLOGIES LLC
Reel/Frame 052072/0859 →
CHANGE OF NAME Recorded Nov 11, 2016
From: ALCOA INC.
To: ARCONIC INC.
Reel/Frame 040599/0309 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 17, 2012
From: BOSELLI, JULIEN; RIOJA, ROBERTO J.; VENEMA, GREGORY B.; SAWTELL, RALPH R.
To: ALCOA INC.
Reel/Frame 028229/0019 →
Continuity (2)
Provisional Application 61444093 · Feb 17, 2011
Related Publication 20120225271A1 · Sep 6, 2012
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