PROCESS FOR PRODUCING LOW VOC COATING COMPOSITIONS
The present invention is directed to a process for producing a low VOC (volatile organic compound) coating composition. The process can comprise mixing a solvent borne coating component and a low or zero VOC waterborne coating component in the presence of a low molecular weight polytrimethylene ether glycol. The present invention can be used to produce low VOC coatings for automotive original equipment manufacturing (OEM) and refinish coating applications, industrial coating applications on equipments and structures, or architectural coating applications on buildings or other structures. This disclosure is further directed to a coating composition comprising components derived from renewable resources.
1 . A process for producing a coating composition, said process comprising the steps of:
(a) providing a first crosslinkable component comprising a first set of one or more film forming polymers and one or more organic solvents, said first crosslinkable component comprises in a range of from 10% to 80% weight percent of said one or more organic solvents, percentage based on the total weight of said first crosslinkable component;
(b) providing a second crosslinkable component comprising a second set of one or more film forming polymers and water, said second crosslinkable component comprises in a range of from 10% to 80% weight percent of water, percentage based on the total weight of said second crosslinkable component;
(c) providing a polytrimethylene ether glycol having a Mn (number average molecular weight) in a range of from 100 to 490; and
(d) producing said coating composition by mixing said first crosslinkable component, said second crosslinkable component, said polytrimethylene ether glycol, a crosslinking component, and optionally, an additive component.
2 . The process of claim 1 , wherein said first crosslinkable component (a) and said second crosslinkable component (b) are mixed at a mixing ratio (a):(b) in a range of from 8:1 to 1:8.
3 . The process of claim 1 , wherein at least a portion of said polytrimethylene ether glycol is mixed with said first crosslinkable component prior to mixing with said second crosslinkable component, said crosslinking component, and optionally, said additive component.
4 . The process of claim 1 , wherein at least a portion of said polytrimethylene ether glycol is mixed with said second crosslinkable component prior to mixing with said first crosslinkable component, said crosslinking component, and optionally, said additive component.
5 . The process of claim 1 , wherein at least one of said first crosslinkable component and said second crosslinkable component further comprises one or more pigments.
6 . The process of claim 1 , wherein at least one of said first crosslinkable component and said second crosslinkable component comprises one or more crosslinkable functional groups selected from hydroxyl groups, amine groups, orthoester groups, orthocarbonate groups, cyclic amide groups, epoxy groups, or carboxyl groups.
7 . The process of claim 1 , wherein said crosslinking component comprises one or more crosslinkable functional groups selected from isocyanate groups, melamine groups, or a combination thereof.
8 . The process of claim 1 , wherein said first set of one or more film forming polymers comprises polymers selected from one or more acrylic polymers, one or more polyester polymers, one or more polyesterurethanes, one or more polyetherurethanes, one or more poly(meth)acrylamides, one or more polyepoxides, one or more polycarbonates.
9 . The process of claim 1 , wherein said second set of one or more film forming polymers comprises polymers selected from one or more acrylic polymers, one or more polyester polymers, one or more polyesterurethanes, one or more polyetherurethanes, one or more poly(meth)acrylamides, one or more polyepoxides, one or more polycarbonates.
10 . The process of claim 1 , wherein said second set of one or more film forming polymers comprises polymers selected from one or more water or water dispersible polyester polymers, or a combination thereof.
11 . The process of claim 1 , wherein said trimethylene glycol dimers is polymerized from bio-derived 1,3-propanediol.
12 . The process of claim 1 , wherein said coating composition comprises in a range of from 0.01% to 20% of the polytrimethylene ether glycol.
13 . An article coated with the process of claim 1 .
14 . A process for producing a dry coating layer over a substrate, said process comprising the steps of:
(i) applying the coating composition of claim 1 over said substrate to form a wet coating layer thereon; and
(ii) curing said wet coating layer at a temperature in a range of from 15° C. to 80° C. to form said dry coating layer.
15 . The process of claim 14 , wherein said substrate is a vehicle, a vehicle body part, or a combination thereof.
16 . The process of claim 14 , wherein said substrate is selected from wood, concrete, metal, plastic, glass, paper, fiber, gypsum plaster, cement, stone, rock, brick, masonry, or a combination thereof.