Solid state scintillator material, solid state scintillator, radiation detector, and radiation inspection apparatus
View Patent ↗In an embodiment, a solid state scintillator material includes a composition represented by a general formula: (Gd 1-α-β-γ TB α Lu β Ce γ ) 3 (Al 1-x Ga x ) a O b , where α and β are numbers satisfying 0<α≦0.5, 0<β≦0.5, and α+β≦0.85, γ is a number satisfying 0.0001≦γ≦0.1, x is a number satisfying 0<x<1, a is a number satisfying 4.8≦a≦5.2 and b is a number satisfying 11.6≦b≦12.4 (atomic ratio), and a garnet structure.
1. A solid state scintillator material, comprising:
a composition represented by a general formula:
(Gd 1-α-β-γ Tb α Lu β Ce γ ) 3 (Al 1-x Ga x ) a O b
where, α and β are numbers satisfying 0<α≦0.5, 0<β≦0.5, and α+β≦0.85 (atomic ratio),
γ is a number satisfying 0.0001≦γ≦0.1 (atomic ratio),
x is a number satisfying 0<x<1 (atomic ratio),
a is a number satisfying 4.8≦a≦5.2 (atomic ratio),
b is a number satisfying 11.6≦b≦12.4 (atomic ratio); and
a garnet structure,
wherein the material contains Ba in a range of 10 to 200 mass ppm, and
wherein a ratio (I p /I G ) of a maximum peak intensity I p of a perovskite phase with respect to a maximum peak intensity I G of a garnet phase by X-ray diffraction is 0.01 or less (including zero).
2. The material according to claim 1 , wherein the α is 0.1≦α≦0.48, the β is 0.001≦β≦0.49, and the x is 0.01≦x≦0.8.
3. The material according to claim 1 , wherein an F content of the material is 300 mass ppm or less (including zero).
4. The material according to claim 1 , wherein an emission spectrum obtained by exciting the material with X-rays has a maximum emission peak in a range of 530 to 560 nm, and includes a sharp spectrum and a broad spectrum.
5. A solid state scintillator comprising a polycrystalline body of an oxide,
wherein the oxide polycrystalline body comprises:
a composition represented by a general formula:
(Gd 1-α-β-γ Tb α Lu β Ce γ ) 3 (Al 1-x Ga x ) a O b
where, α and β are numbers satisfying 0<α≦0.5, 0<β≦0.5, and α+β≦0.85 (atomic ratio),
γ is a number satisfying 0.0001≦γ≦0.1 (atomic ratio),
x is a number satisfying 0<x<1 (atomic ratio),
a is a number satisfying 4.8≦a≦5.2 (atomic ratio),
b is a number satisfying 11.6≦b≦2.4 (atomic ratio); and
a garnet structure,
wherein the oxide polycrystalline body contains Ba in a range of 10 to 200 mass ppm, and
wherein a ratio (I p /I G ) of a maximum peak intensity I p of a perovskite phase with respect to a maximum peak intensity I G of a garnet phase by X-ray diffraction of the oxide polycrystalline body is 0.01 or less (including zero).
6. The scintillator according to claim 5 , wherein the α is 0.1≦α≦0.48, the β is 0.001≦β≦0.49, and the x is 0.01≦x≦0.8.
7. The scintillator according to claim 5 , wherein an F content of the oxide polycrystalline body is 300 mass ppm or less (including zero).
8. The scintillator according to claim 5 , wherein an emission spectrum obtained by exciting the oxide polycrystalline body with X-rays has a maximum emission peak in a range of 530 to 560 nm, and includes a sharp spectrum and a broad spectrum.
9. The scintillator according to claim 5 , wherein the oxide polycrystalline body has an average crystal grain diameter in a range of 2 to 50 μm.
10. The scintillator according to claim 5 , wherein diffuse transmittance at a wavelength of 680 nm is 50% or more.
11. The scintillator according to claim 5 , wherein a decay time in which afterglow becomes 5% is 4 ms or less.
12. The scintillator according to claim 5 , wherein the oxide polycrystalline body has a relative density of 99.5% or more.
13. A radiation detector comprising the solid state scintillator according to claim 5 .
14. A radiation inspection apparatus comprising the radiation detector according to claim 13 .