Polyurethane dispersions and methods of making and using same
The presently disclosed and claimed inventive concept(s) relates generally to polyethylene terephthalate (“PET”) polymers, digested oligomeric derivatives of PET (“dPET”), functionalized oligomeric derivatives of dPET (“dfPET”), and polyurethane dispersions (“PUD”) made from or incorporating dfPET therein.
1. A composition comprising an aqueous polyurethane dispersion, wherein the dispersion is a reaction product of: (a) toluene diisocyanate; (b) dimethylolpropionic acid; (c) 42 wt. %, based on the combined amounts of toluene diisocyanate, dimethylolpropionic acid, and dfPET, of a depolymerized polyethylene terephthalate (dfPET), said dfPET having a hydroxyl number of 225 mg KOH/g and comprising a reaction product of polyethylene terephthalate (PET) and one molar equivalent of neopentyl glycol per mole of PET; and (d) a chain extender selected from the group consisting of 1,4-butanediol; a mixture of 1,4-butanediol and piperazine; a mixture of 1,4-butanediol and polyethylene glycol 200; and a mixture of 1,6-hexanediol and 1,6-hexanediamine.
2. The composition of claim 1 wherein the dispersion is prepared in a solvent mixture comprising acetone and N-methyl-2-pyrrolidone.
3. The composition of claim 2 wherein the aqueous dispersion comprises, after concentration, less than 5 wt. %, based on the amount of concentrated aqueous dispersion, of the solvent mixture.
4. A coating made from the composition of claim 1 .
5. A composition comprising an aqueous polyurethane dispersion, wherein the dispersion is a reaction product of: (a) tetramethylxylylene diisocyanate (TMXDI); (b) dimethylolpropionic acid; (c) 14 wt. %, based on the combined amounts of TMXDI, dimethylolpropionic acid, and dfPET, of a depolymerized polyethylene terephthalate (dfPET), said dfPET having a hydroxyl number of 373 mg KOH/g and comprising a reaction product of polyethylene terephthalate (PET) and one molar equivalent of neopentyl glycol per mole of PET, and (d) 1,3-diaminopropane.
6. The composition of claim 5 wherein the dispersion is prepared in a solvent mixture comprising acetone and N-methyl-2-pyrrolidone.
7. The composition of claim 6 wherein the aqueous dispersion comprises, after concentration, less than 5 wt. %, based on the amount of concentrated aqueous dispersion, of the solvent mixture.
8. A coating made from the composition of claim 5 .