Process for preparing pellets of poly(trimethylene terephthalate)
View Patent ↗The process creates a radial temperature gradient in an extruded strand in a direction normal to the direction of motion thereof (that is, normal to the longitudinal direction thereof) so that upon exiting the first quench region the surface of the strand has solidified while at least the preponderant portion of the interior of the strand remains above the cold crystallization temperature, T cc Then, in the annealing region, heat from the warmer interior will be transferred to the cooler surface, causing the surface to heat up into the range of T cc , thereby inducing the surface to undergo crystallization. Once the surface has undergone crystallization, the strand is thoroughly quenched in a second quench region so that the strand will be ready for pelletization, accumulation or other handling steps.
1. A process comprising:
(a) preparing a molten strand of a poly(trimethylene terephthalate) composition wherein the strand has a surface and an interior;
(b) contacting the molten strand with water in a first quench region for a sufficient period of time so that the surface of the molten strand solidifies and at least a preponderant portion of the interior remains above the cold crystallization temperature of the poly(trimethylene terephthalate) composition, thereby preparing a surface-solidified strand;
(c) separating the surface-solidified strand from the water;
(d) exposing the surface-solidified strand to ambient air in an annealing region for a sufficient period of time to induce cold crystallization on the surface of the strand producing a surface-crystallized strand; and
(e) contacting the surface-crystallized strand with water in a second quench region for a sufficient period of time to solidify the interior of the strand.
2. The process of claim 1 further comprising pelletizing the strand after it exits the second quench region.
3. The process of claim 1 wherein the period of time in the first quench region lies in the range of 0.2 to 2 seconds.
4. The process of claim 3 wherein the period of time in the first quench region lies in the range of 0.3 to 1.0 second.
5. The process of claim 1 wherein the period of time in the annealing region lies in the range of 0.3 to 5 seconds.
6. The process of claim 5 wherein the period of time in the annealing region lies in the range of 0.5 to 2.5 seconds.
7. The process of claim 1 wherein the period of time in the second quench region lies in the range of 1 to 10 seconds.
8. The process of claim 7 wherein the period of time in the second quench region lies in the range of 1.5 to 3.5 seconds.
9. The process of claim 1 wherein the water in the first and second quench regions, independently, has a temperature of greater than 0° C. but less than 60° C.
10. The process of claim 9 wherein the water in the first and second quench regions, independently, has a temperature within the range of 35 to 45° C.
11. The process of claim 1 wherein the period of time in the first quench region lies in the range of 0.3 to 1.0 second; the period of time in the annealing region lies in the range of 0.5 to 2.5 seconds; the period of time in the second quench region lies in the range of 1.5 to 3.5 seconds; the water in the first and second quench regions, independently, has a temperature in the region of 35 to 45° C.