Process for dry grinding of one or more mineral materials including at least one calcium carbonate
The present invention provides a process for dry grinding one or more mineral materials which include at least calcium carbonate. The process includes a) crushing the mineral material or materials in at least one crushing unit until a crushed material is obtained with a d95 of less than 10 cm, and dry grinding the material in at least one grinding unit (i) in the presence of at least one comb-type hydrophilic polymer containing at least polyalkylene oxide function grafted on to at least one unsaturated ethylene monomer, and (ii) in such a manner that the quantity of liquid in the grinding unit is less than 15% by dry weight of the material crushed in the crushing unit, wherein recovered material has a d50 of 0.5 to 500 microns.
1. A product obtained by the process of dry grinding a mineral material comprising at least calcium carbonate, wherein the process comprises the stages of:
a) crushing the mineral material in at least one crushing unit until a crushed material is obtained with a d 95 of less than 10 cm;
b) optionally subjecting the material crushed according to stage a) to a flotation stage and/or a magnetic separation stage and/or a sieving stage and/or a chemical treatment stage;
c) dry grinding the material according to stage a) and/or b) in at least one grinding unit:
(i) in the presence of a grinding aid agent having a weight-average molecular weight (Mw) of 20,000 to 50,000, wherein the grinding aid agent comprises a polymer formed by radical polymerization of: (a) polyethylene glycol methacrylate, acrylic acid and maleic acid; (b) polyethylene glycol methacrylate and maleic acid; (c) polyethylene glycol methacrylate and acrylic acid in which the carboxylic acid groupings of acrylic acid are fully neutralized by sodium; (d) a monoether of maleic acid with lateral chains of polyethylene glycol methacrylate, and maleic acid; or (e) polyethylene glycol methacrylate functionalized with hexyl 1-decanyl and acrylic acid in which the carboxylic acid groups of acrylic acid are fully neutralized by sodium;
(ii) in such a manner that the quantity of liquid in the grinding unit is less than 15% by dry weight of the material crushed in the crushing unit;
d) optionally classifying the material dry ground according to stage c) with at least one classification unit; and
e) optionally repeating stages c) and/or d) on all or part of the dry ground material resulting from stages c) and/or d);
wherein the material recovered following stage c), and stage d) if performed, and stage e) if performed, has a d 50 of 0.5 to 500 microns and comprises said grinding aid agent.
2. The product according to claim 1 , wherein step c) is performed in the presence of 0.005 to 1.0% by dry weight of the grinding aid agent, relative to the dry weight of the material crushed in each grinding unit.
3. The product according to claim 1 , wherein step c) is performed in the presence of 0.03 to 0.5% by dry weight of the grinding aid agent, relative to the dry weight of the material crushed in each grinding unit.
4. The product according to claim 1 , wherein the grinding aid agent used in stage c) is blended with another agent.
5. The product according to claim 4 , wherein the other agent is a carbohydrate, a polyethylene glycol (PEG), tri isopropanol amine (TIPA), or their blends.
6. The product according to claim 1 , wherein the grinding aid agent used in stage c) is blended with a polyethylene glycol (PEG) in a ratio PEG: grinding aid agent equal to 50:50.
7. The product according to claim 1 , wherein the grinding aid agent used in stage c) is blended with tri isopropanol amine (TIPA) in a ratio TIPA: grinding aid agent equal to 20:80.
8. The product according to claim 1 , wherein the mineral matter is calcium carbonate comprising limestone, marble, chalk, dolomite or any blend thereof.
9. The product according to claim 1 , wherein the mineral matter comprises calcium carbonate and one or more of a clay, bentonite, a kaolin, a feldspar, a calcinated clay, a non-clayey silicate, a talc, a mica or any blend thereof.
10. The product according to claim 1 , wherein in stage c), the liquid content in the grinding unit is less than 10% relative to the total dry weight of the material for grinding in the said grinding unit.
11. The product according to claim 1 , wherein in stage c), the liquid content in the grinding unit is less than 5% relative to the total dry weight of the material for grinding in the said grinding unit.
12. The product according to claim 1 , wherein in stage c), the liquid content in the grinding unit is less than 1% relative to the total dry weight of the material for grinding in the said grinding unit.
13. The product according to claim 1 , wherein stage d) takes place.
14. The product according to claim 13 , wherein the classified material resulting from stage d) has a d 50 (average diameter) of between 0.7 and 150 microns.
15. The product according to claim 13 , wherein the classified material resulting from stage d) has a d 50 (average diameter) of between 1 and 45 microns.
16. The product according to claim 13 , wherein the classified material resulting from stage d) has a d 50 (average diameter) of between 1.2 and 5 microns.