FIBER-REACTIVE AZO DYES, PREPARATION THEREOF AND USE THEREOF
The present invention provides azo dyes of formula (1) where Hal, M and Y are each as defined in claim 1 , processes for their preparation and their use.
1 - 10 . (canceled)
11 . An azo dye of formula (1)
where
Y represents —CH═CH 2 or —CH 2 CH 2 Z, where Z is an alkali-detachable group;
M represents hydrogen, ammonium, an alkali metal or the equivalent of an alkaline earth metal; and
Hal is Cl or F.
12 . The azo dye as claimed in claim 11 wherein Y represents —CH═CH 2 , β-chlorethyl or β-sulfatoethyl.
13 . The azo dye as claimed in claim 11 wherein M represents hydrogen, lithium or sodium.
14 . The azo dye as claimed in claim 11 wherein Hal represents Cl.
15 . The azo dye as claimed in claim 11 , wherein Hal represents F.
16 . The azo dye as claimed in claim 14 , wherein Y represents —CH═CH 2 , β-chlorethyl or β-sulfatoethyl and M represents hydrogen, lithium or sodium.
17 . The azo dye as claimed in claim 15 , wherein Y represents —CH═CH 2 , β-chlorethyl or β-sulfatoethyl and M represents hydrogen, lithium or sodium.
18 . A process for preparing an azo dye of formula (1) as claimed in claim 11 , which comprises preparing compounds of formulae (2), (3), (4) and (5)
where Z and M each have the meanings given in claim 11 , in a sequence of diazotization, acylation and coupling reactions.
19 . The process as claimed in claim 18 , wherein
a) the compound of formula (2) is diazotized and coupled onto the compound of formula (3) to form the compound of formula (8)
b) the compound of formula (8) is subsequently reacted with the compound of formula (5) to form the compound of formula (7)
and
c) the compound of formula (7) is reacted with the compound of formula (4) to form the compound of formula (1).
20 . A process for dyeing or printing material comprising hydroxyl and/or carboxamide groups, which comprises applying one or more dyes to the material in dissolved form and fixing the dye or dyes on the material by means of heat or with the aid of an alkaline agent or by means of both measures, which comprises utilizing the azo dye as claimed in claim 11 .
21 . An ink for digital textile printing by the ink jet process, comprising the azo dye as claimed in claim 11 .