EMULSION OF A POLYMER MODIFIED ASPHALT
A method for formulating an emulsified polymer modified asphalt, and the emulsion thus created. The method includes mixing at least one polymer and a first binder in a high shear device to produce a polymer-binder composite, where the polymer is at least 70% butadiene; mixing the polymer-binder composite with a second binder to form a polymer modified asphalt; and emulsifying the polymer modified asphalt by combining effective amounts of an emulsifying agent and of water with the polymer modified asphalt. The polymer-binder composite may be produced at lower than room temperature or may include metal fatty acids, such that the resultant polymer-binder composite may be stored and transported at room temperature.
1 . An emulsified polymer modified asphalt, comprising:
a polymer-binder composite, comprising:
at least one polymer comprising greater than 70% butadiene; and
a first binder,
where the at least one polymer and the first binder are combined in a high shear device to form the polymer-binder composite;
a second binder, where the second binder is mixed with the polymer-binder composite to form a polymer modified asphalt; and
effective amounts of an emulsifying agent and of water to allow emulsification of the polymer modified asphalt.
2 . The emulsified polymer modified asphalt of claim 1 where the at least one polymer comprises greater than 75% butadiene.
3 . The emulsified polymer modified asphalt of claim 1 where the at least one polymer comprises greater than 80% butadiene.
4 . The emulsified polymer modified asphalt of claim 1 where the at least one polymer comprises greater than 85% butadiene.
5 . The emulsified polymer modified asphalt of claim 1 where the at least one polymer and the first binder are combined in the high shear device at cooler than ambient temperature.
6 . The emulsified polymer modified asphalt of claim 1 where the polymer-binder composite further comprises metal fatty acids.
7 . The emulsified polymer modified asphalt of claim 6 where the metal fatty acids are zinc stearate.
8 . The emulsified polymer modified asphalt of claim 1 wherein the emulsifying agent is cationic.
9 . The emulsified polymer modified asphalt of claim 1 wherein the emulsifying agent is anionic.
10 . The emulsified polymer modified asphalt of claim 1 wherein the emulsifying agent is nonionic.
11 . The emulsified polymer modified asphalt of claim 1 wherein the emulsifying agent is amphoteric.
12 . The emulsified polymer modified asphalt of claim 1 wherein the emulsifying agent is zwitterionic.
13 . The emulsified polymer modified asphalt of claim 1 further comprising at least one emulsion additive.
14 . The emulsified polymer modified asphalt of claim 13 wherein the emulsion additive is selected from the group consisting of latex rubber, sulfur containing compounds, thickeners, or other rheology modifiers, tackifiers, flow improvers, pH adjusting chemicals, stabilizers and the like.
15 . The emulsified polymer modified asphalt of claim 1 wherein the polymer-binder composite further comprises at least one additive.
16 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer has a molecular weight greater than about 60,000 Da.
17 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer has a molecular weight greater than about 100,000 Da.
18 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer has a molecular weight greater than about 150,000 Da.
19 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer has a molecular weight greater than about 200,000 Da.
20 . The emulsified polymer modified asphalt of claim 1 wherein the polymer-binder composite mixture is readily soluble in the second binder when combined with the second binder.
21 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer and the first binder are subjected to mixing with a resident time in the high shear device of greater than about 0.5 seconds.
22 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer and the first binder are subjected to mixing with a scalar shear quantity of greater than about 250.
23 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer and the first binder are subjected to mixing with a scalar shear quantity of greater than about 1000.
24 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer and the first binder are subjected to mixing with a scalar shear quantity of greater than about 1500.
25 . The emulsified polymer modified asphalt of claim 1 where greater than 0.05 kW/kg of energy is utilized to combine the at least one polymer and the first binder.
26 . The emulsified polymer modified asphalt of claim 1 where greater than 0.1 kW/kg of energy is utilized to combine the at least one polymer and the first binder.
27 . The emulsified polymer modified asphalt of claim 1 where greater than 0.2 kW/kg of energy is utilized to combine the at least one polymer and the first binder.
28 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer and the first binder are subjected to mixing where the high shear device produces a pressure of greater than 100 psi and maintains laminar flow.
29 . The emulsified polymer modified asphalt of claim 1 wherein the at least one polymer and the first binder are subjected to mixing where the high shear device maintains RPMs of less than 1,500 and laminar flow.
30 . A method for formulating an emulsified polymer modified asphalt, comprising:
mixing at least one polymer and a first binder in a high shear device to produce a polymer-binder composite, where the at least one polymer has greater than 70% butadiene;
mixing the polymer-binder composite with a second binder to form a polymer modified asphalt; and
emulsifying the polymer modified asphalt by combining effective amounts of an emulsifying agent and of water with the polymer modified asphalt.
31 . The method of claim 30 where the at least one polymer has greater than 75% butadiene.
32 . The method of claim 30 where the at least one polymer has greater than 80% butadiene.
33 . The method of claim 30 where the at least one polymer has greater than 85% butadiene.
34 . The method of claim 30 where mixing the at least one polymer and the first binder occurs at a cooler than ambient temperature.
35 . The method of claim 30 , further comprising mixing metal fatty acids with the at least one polymer and the first binder.
36 . The method of claim 35 where the metal fatty acids are zinc stearate.
37 . The method of claim 30 wherein the high shear device is a high shear extruder.
38 . The method of claim 30 wherein the step of mixing the at least one polymer and the first binder in the high shear device to produce the polymer-binder composite further comprises mixing at least one additive into the high shear device along with the at least one polymer and first binder to produce the polymer-binder composite.
39 . The method of claim 30 wherein mixing the at least one polymer and the first binder in the high shear device to produce the polymer-binder composite is accomplished in less than one minute.
40 . The method of claim 30 wherein the at least one polymer has a molecular weight that is greater than 60,000 Da.
41 . The method of claim 30 wherein the at least one polymer has a molecular weight that is greater than 100,000 Da.
42 . The method of claim 30 wherein the at least one polymer has a molecular weight that is greater than 150,000 Da.
43 . The method of claim 30 wherein the at least one polymer has a molecular weight greater than about 200,000 Da.
44 . The method of claim 30 wherein mixing the at least one polymer and the first binder in the high shear device to produce the polymer-binder composite further comprises subjecting the at least one polymer and the first binder to mixing with a resident time in the high shear device of greater than 0.5 seconds.
45 . The method of claim 30 wherein mixing the at least one polymer and the first binder in the high shear device to produce the polymer-binder composite further comprises subjecting the at least one polymer and the first binder to mixing with a scalar shear quantity of greater than about 250.
46 . The method of claim 30 wherein mixing the at least one polymer and the first binder in the high shear device to produce the polymer-binder composite further comprises subjecting the at least one polymer and the first binder to mixing with a scalar shear quantity of greater than about 1,000.
47 . The method of claim 30 wherein mixing the at least one polymer and the first binder in the high shear device to produce the polymer-binder composite further comprises subjecting the at least one polymer and the first binder to mixing with a scalar shear quantity of greater than about 1,500.
48 . The method of claim 30 wherein greater than 0.05 kW/kg of energy is utilized to mix the at least one polymer and the first binder in the high shear device to produce the polymer-binder composite.
49 . The method of claim 30 wherein greater than 0.1 kW/kg of energy is utilized to mix the at least one polymer and the first binder in the high shear device to produce the polymer-binder composite.
50 . The method of claim 30 wherein greater than 0.2 kW/kg of energy is utilized to mix the at least one polymer and the first binder in the high shear device to produce the polymer-binder composite.
51 . The method of claim 30 wherein the emulsifying agent is cationic.
52 . The method of claim 30 wherein the emulsifying agent is anionic.
53 . The method of claim 30 wherein the emulsifying agent is nonionic.
54 . The method of claim 30 wherein the emulsifying agent is amphoteric.
55 . The method of claim 30 wherein the emulsifying agent is zwitterionic.
56 . The method of claim 30 further comprising the step of transporting the polymer-binder composite to a secondary location prior to mixing the polymer-binder composite with the second binder to form the polymer modified asphalt.
57 . The method of claim 56 further comprising the step of storing the polymer-binder composite for a predetermined amount of time prior to transporting the polymer-binder composite to the secondary location.
58 . The method of claim 30 wherein the step of emulsifying the polymer modified asphalt by combining effective amounts of an emulsifying agent and of water with the polymer modified asphalt further comprises combining an effective amount of an additive with the emulsifying agent and the water.
59 . The method of claim 58 wherein the additive is selected from the group consisting of latex rubber, sulfur containing compounds, thickeners, or other rheology modifiers, tackifiers, flow improvers, pH adjusting chemicals, stabilizers and the like.