Method of manufacturing a nano-rod and method of manufacturing a display substrate
A method of manufacturing a nano-rod and a method of manufacturing a display substrate in which a seed including a metal oxide is formed. A nano-rod is formed by reacting the seed with a metal precursor in an organic solvent. Therefore, the nano-rod may be easily formed, and a manufacturing reliability of the nano-rod and a display substrate using the nano-rod may be improved.
1. A method of forming nano-rods, the method comprising:
forming seed particles comprising a metal oxide, in a first solution;
removing the seed particles from the first solution; and
forming nano-rods in a second solution comprising the seed particles dispersed therein, a metal precursor of a metal of the metal oxide, and an organic solvent, such that each of the seed particles grows in two opposing directions, to form the nano-rods extending in a direction substantially parallel to the two opposing directions and being larger than the seed particles,
wherein the nano rods are formed at a temperature between about 200° C. and about 340° C., and
wherein the nano rods are formed by reacting about 0.05 mmol to about 0.35 mmol of the seed particles, about 0.1 mmol to about 1.5 mmol of the metal precursor, and about 0.5 mmol to about 3.5 mmol of a surfactant with about 1 g to about 10 g of the organic solvent.
2. The method of claim 1 , wherein the organic solvent comprises at least one selected from a group consisting of trioctyl amine, octadecene and oleyl amine.
3. The method of claim 1 , wherein the metal precursor comprises at least one selected from a group consisting of zinc acetate and zinc acetate dehydrate.
4. The method of claim 1 , wherein, in forming the nano-rods, an alkyl amine-based surfactant different from the organic solvent is further added in the organic solvent.
5. A method of forming nano-rods, the method comprising:
forming seed particles comprising a metal oxide, in a first solution, the first solution comprising a metal precursor of a metal of the metal oxide, a hydroxide, and an alcohol;
removing the seed particles from the first solution; and
forming nano-rods in a second solution comprising the seed particles dispersed therein, a metal precursor of the metal of the metal oxide, and an organic solvent, such that each of the seed particles grows in two opposing directions to form the nano-rods extending in a direction substantially parallel to the two opposing directions and being larger than the seed particles,
wherein the nano rods are formed at a temperature between about 200° C. and about 340° C.
wherein the nano rods are formed by reacting about 0.05 mmol to about 0.35 mmol of the seed particles, about 0.1 mmol to about 1.5 mmol of the metal precursor, and about 0.5 mmol to about 3.5 mmol of a surfactant with about 1 g to about 10 g of the organic solvent, and
wherein the organic solvent comprises at least one selected from a group consisting of trioctyl amine, octadecene, and oleyl amine.
6. The method of claim 1 , wherein, in forming the nano rods, a mole ratio between the seed particles and the metal precursor is between about 1:1 and about 1:10.
7. The method of claim 6 , wherein, in forming the nano rods, a surfactant different from the organic solvent is further added in the organic solvent, and
wherein a mole ratio between the metal precursor and the surfactant is between about 1:2 and about 1:6.
8. The method of claim 1 , wherein the organic solvent controls the growth direction of the nano-rods.
9. The method of claim 5 , wherein the organic solvent controls the growth direction of the nano-rods.