Use of high ratio aqueous alkali silicates in drilling fluids
View Patent ↗An improved drilling and completion fluid can be used in subterranean drilling for oil and gas. Sodium silicate and potassium silicate-based drilling fluids are commonly used drilling fluids with the notable attributes of exceptional shale stabilization characteristics coupled with exceptional environmental performance Environmental and wellbore stabilization characteristics are improved by using high ratio aqueous silicates wherein ratio is defined as the molar ratio of SiO 2 :Me 2 O, where Me is an alkali and is most commonly sodium or potassium (i.e. Na 2 O and K 2 O). For high ratio aqueous alkali silicates, the molar ratio of SiO 2 :Me 2 O can range from just over 4.0 to about 12.0.
1. An aqueous phase drilling fluid for improving wellbore stabilization comprising an aqueous drilling fluid; and a high ratio, wholly solubilized, aqueous alkali silicate in the form of polysilicate anions wherein the molar ratio of silica oxide to alkali oxide is greater than 4.0 and less than 12.0, wherein said silicate is present in solution as free polysilicate species and said high ratio aqueous alkali silicate chemically reacts with shale in the subterranean formation adjacent to the wellbore.
2. The drilling fluid of claim 1 wherein the concentration of said silica oxide in the drilling fluid is in the range of 0.25 weight % to 6.0 weight %.
3. The drilling fluid of claim 2 wherein the molar ratio of silica oxide to alkali oxide is greater than 4.5.
4. The drilling fluid of claim 3 wherein the molar ratio of silica oxide to alkali oxide is less than 7.0.
5. The drilling fluid of claim 2 wherein the alkali oxide is sodium oxide.
6. The drilling fluid of claim 2 wherein the alkali oxide is potassium oxide.
7. The drilling fluid of claim 1 wherein the molar ratio of silica oxide to alkali oxide is greater than 4.5.
8. The drilling fluid of claim 7 wherein the molar ratio of silica oxide to alkali oxide is less than 7.0.
9. The drilling fluid of claim 1 wherein the alkali oxide is sodium oxide.
10. The drilling fluid of claim 1 wherein the alkali oxide is potassium oxide.
11. The drilling fluid of claim 1 wherein said drilling fluid comprising a high ratio aqueous alkali silicate has a reduced salinity relative to a drilling fluid comprising a conventional ratio aqueous alkali silicate.
12. The drilling fluid of claim 1 wherein said chemical reaction of said high ratio aqueous silica oxide and said shale stabilizes said shale.
13. The drilling fluid of claim 1 wherein said chemical reaction of said high ratio aqueous silica oxide and said shale prevents shale delamination.
14. The drilling fluid of claim 1 wherein said chemical reaction of said high ratio aqueous silica oxide and said shale seals microfractures and porous zones.
15. The drilling fluid of claim 1 wherein said chemical reaction of said high ratio aqueous silica oxide and said shale prevents bitumen accretion.
16. The drilling fluid of claim 1 wherein the pH of said drilling fluid is maintained above 10.
17. A continuous aqueous phase drilling fluid for improving wellbore stabilization in oil sands comprising an aqueous drilling fluid; and a high ratio, wholly solubilized, hydrous alkali silicate in the form of polysilicate ions wherein the molar ratio of silica oxide to alkali oxide is greater than 4.0 and less than 12.0, wherein said silicate is present in solution as free polysilicate species.