Microemulsion flowback aid composition and method of using same
View Patent ↗Disclosed and claimed is a microemulsion flowback aid composition and a method of enhancing recovery of oil or gas during fracturing or stimulation processes. The microemulsion flowback aid composition includes (i) an oil-like phase comprising at least one nonionic surfactant having a hydrophilic-lipophilic balance (HLB) of less than about 9; (ii) a coupling agent capable of stabilizing the microemulsion flowback aid composition; (iii) at least one water-soluble or dispersible nonionic surfactant that is different from the at least one nonionic surfactant in the oil-like phase; (iv) at least one additional surfactant selected from anionic, cationic, amphoteric, and combinations thereof; and (v) water.
1. A microemulsion flowback aid composition consisting of:(i) a first nonionic surfactant having a hydrophilic-lipophilic balance (HLB) of less than about 9 and selected from linear and branched alkoxylated alcohols, alkoxylated alkylphenols, glycerol esters, glycol esters, polyetheyleneglycol esters, polyglycerol esters, sorbitol esters, ethylene oxide/propylene oxide copolymers, or combinations thereof; (ii) a water-soluble organic solvent; (iii) a second nonionic surfactant that is water-soluble or dispersible and is different from the first nonionic surfactant; (iv) a cationic surfactant, an amphoteric surfactant, or a combination thereof; (v) a nonionic demulsifier selected from a cross-linked ethylene oxide/propylene oxide copolymer or a mixture of a cross-linked ethylene oxide/propylene oxide copolymer and a polyethyleneimine alkoxylate; and (vi) water.
2. The microemulsion flowback aid composition of claim 1 , wherein the amphoteric surfactant is selected from cocoamidopropyl betaine, cocodimethyl betaine, alkyl amine oxide, or a combination thereof.
3. The microemulsion flowback aid composition of claim 1 , wherein the alkoxylated alcohols are selected from ethoxylated C 6 -C 20 alcohols, propoxylated C 6 -C 20 alcohols, or a combination thereof.
4. The microemulsion flowback aid composition of claim 3 , wherein the alkoxylated alcohols comprise about 1-6 moles of alkylene oxide per mole of alcohol.
5. The microemulsion flowback aid composition of claim 1 , wherein the composition comprises from about 0.1% to about 35% by weight of the first nonionic surfactant.
6. The microemulsion flowback aid composition of claim 1 , wherein the water-soluble organic solvent is selected from short chain alcohols with between 1 and 6 carbon atoms, diols with between 1 and 6 carbon atoms, glycerol, alkyl ethers of alkylene glycols with between 1 and 6 carbon atoms, polyalkylene glycols less than 6 kD, or any combination thereof.
7. The microemulsion flowback aid composition of claim 6 , wherein the short chain alcohol is selected from methanol, ethanol, n-propanol, or any combination thereof.
8. The microemulsion flowback aid composition of claim 6 , wherein the diol is selected from methylene glycol, ethylene glycol, propylene glycol, or any combination thereof.
9. The microemulsion flowback aid composition of claim 6 , wherein the alkyl ethers of alkylene glycols comprises ethylene glycol mono-n-butyl ether.
10. The microemulsion flowback aid composition of claim 1 , wherein the composition comprises from about 5% to about 40% by weight of the water-soluble organic solvent.
11. The microemulsion flowback aid composition of claim 1 , wherein the second nonionic surfactant is selected from an alkoxylated alcohol, ethylene oxide/propylene oxide copolymers, an alkoxylated alkylphenol having an HLB greater than about 10, or any combination thereof.
12. The microemulsion flowback aid composition of claim 1 , wherein the cationic surfactant is selected from alkyl ammonium halides, alkyl aryl ammonium halides, imidazolium, or any combination thereof.
13. The microemulsion flowback aid composition of claim 1 , wherein the composition comprises up to about 20% by weight of the nonionic demulsifier.
14. The microemulsion flowback aid compositon of claim 1 , wherein the composition comprises up to about 25% by weight of the second nonionic surfactant.
15. The microemulsion flowback aid composition of claim 1 , wherein the composition comprises from about 2% to about 20% by weight of the cationic surfactant, the amphoteric surfactant, or the combination thereof.