Fluorinated compound, fluorinated polymer and fluorinated copolymer
View Patent ↗To provide a fluorinated compound having an R F group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer and a fluorinated copolymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH 2 ═C(M)COO(CH 2 ) n PhCOO(CH 2 ) m C r F 2r+1 (I) (in the formula (I), M is a hydrogen atom, a methyl group or a halogen atom, n is an integer of from 0 to 2, Ph is a phenylene group, m is an integer of from 1 to 4, and r is an integer of from 1 to 6).
1. A fluorinated compound represented by the following formula (I):
CH 2 ═C(M)COO(CH 2 ) n PhCOO(CH 2 ) m C r F 2r+1 (I)
wherein:
M is a hydrogen atom, a methyl group or a halogen atom;
n is an integer of from 0 to 2;
Ph is a phenylene group;
m is an integer of from 1 to 4; and
r is an integer of from 1 to 6.
2. The fluorinated compound according to claim 1 , wherein Ph in the formula (I) is a 1,4-phenylene group.
3. The fluorinated compound according to claim 1 , wherein r in the formula (I) is an integer of from 2 to 6.
4. The fluorinated compound according to claim 3 , wherein r in the formula (I) is an integer of from 4 to 6.
5. The fluorinated compound according to claim 1 , wherein the fluorinated compound represented by the formula (I) is a compound represented by any one of the following formulae (I-1) to (I-7):
6. The fluorinated compound according to claim 1 , wherein in the formula (I), r is an integer of from 4 to 6, and C r F 2r+1 is linear.
7. The fluorinated compound according to claim 1 , wherein M is a hydrogen atom.
8. The fluorinated compound according to claim 1 , wherein M is a methyl group.
9. The fluorinated compound according to claim 1 , wherein n is 0.
10. The fluorinated compound according to claim 1 , wherein n is 1.
11. The fluorinated compound according to claim 1 , wherein m is 1.
12. The fluorinated compound according to claim 1 , wherein m is 2.
13. The fluorinated compound according to claim 1 , wherein m is 3.
14. The fluorinated compound according to claim 1 , wherein the fluorinated compound represented by the formula (I) is a compound represented by the formula (I-1):
15. The fluorinated compound according to claim 1 , wherein the fluorinated compound represented by the formula (I) is a compound represented by the formula (I-2):
16. The fluorinated compound according to claim 1 , wherein the fluorinated compound represented by the formula (I) is a compound represented by the formula (I-3):
17. The fluorinated compound according to claim 1 , wherein the fluorinated compound represented by the formula (I) is a compound represented by the formula (I-4):
18. The fluorinated compound according to claim 1 , wherein the fluorinated compound represented by the formula (I) is a compound represented by the formula (I-5):
19. The fluorinated compound according to claim 1 , wherein the fluorinated compound represented by the formula (I) is a compound represented by the formula (I-6):
20. The fluorinated compound according to claim 1 , wherein the fluorinated compound represented by the formula (I) is a compound represented by the formula (I-7):