Insulated electric wire and coil using same
View Patent ↗An insulated electric wire includes a conductor and an insulating coating provided around a perimeter of the conductor. The insulating coating includes a first insulating coating film around the perimeter of the conductor, the first insulating coating film being formed of a resin containing an imide structure in its molecule, and a second insulating coating film around a perimeter of the first insulating coating film, the second insulating coating film being formed of a polyimide resin comprising a repeat unit represented by Formula 1, and having an imide concentration of not less than 15% and not more than 36%, wherein R 1 is a tetravalent group derived from decarboxylation of an aromatic tetracarboxylic acid, and R 2 is a divalent group derived from deamination of an aromatic diamine.
1. An insulated electric wire, comprising:
a conductor; and
an insulating coating provided around a perimeter of the conductor, the insulating coating including:
a first insulating coating film around the perimeter of the conductor, the first insulating coating film comprising a resin containing an imide structure in its molecule; and
a second insulating coating film disposed directly on a perimeter of the first insulating coating film, the second insulating coating film comprising a polyimide resin comprising a repeat unit represented by Formula 1, and having an imide concentration of not less than 15% and not more than 36%,
wherein R 1 is a tetravalent group derived from decarboxylation of an aromatic tetracarboxylic acid, and R 2 is a divalent group derived from deamination of an aromatic diamine,
wherein the first insulating coating film and the second insulating coating film are formed by applying an insulating varnish and baking the applied insulating varnish,
wherein the first insulating coating film comprises a polyimide resin having an imide concentration-greater than 36%, and
wherein the polyimide resin of the second insulating coating film consists of an acid component consisting of pyromellitic dianhydride (PMDA) and 3,3′,4,4′-biphenyl tetracarboxylic dianhydride (BPDA), and a diamine component consisting of 4,4′-bis(4-aminophenoxy)biphenyl (BAPB) and 4,4′-diaminodiphenyl ether (ODA).
2. The insulated electric wire according to claim 1 , wherein a thickness of the second insulating coating film is not less than 80% and less than 100% relative to a total thickness of the insulating coating.
3. The insulated electric wire according to claim 1 , wherein the aromatic diamine for producing R 2 in the Formula 1 contains at least 4,4′-bis(4-aminophenoxy)biphenyl.
4. The insulated electric wire according to claim 1 , wherein the first insulating coating film comprises a polyimide, polyamide-imide, or polyester imide.
5. A coil, comprising the insulated electric wire according to claim 1 .
6. The insulated electric wire according to claim 1 , wherein the first insulating coating film is disposed directly on the perimeter of the conductor.
7. The insulated electric wire according to claim 1 , wherein the aromatic diamine for producing R 2 in the Formula 1 comprises 4,4′-bis(4-aminophenoxy)biphenyl.
8. The insulated electric wire according to claim 1 , wherein the first insulating coating film is disposed on a surface of the conductor.
9. The insulated electric wire according to claim 1 , wherein the aromatic tetracarboxylic acid for producing R 1 in the Formula 1 is selected from the group consisting of pyromellitic dianhydride (PMDA), and 3,3′,4,4′-biphenyl tetracarboxylic dianhydride (BPDA).
10. The insulated electric wire according to claim 1 , wherein the aromatic diamine for producing R 2 in the Formula 1 is selected from the group consisting of 4,4′-bis(4-aminophenoxy)biphenyl, and 4,4′-diaminodiphenyl ether (ODA).
11. The insulated electric wire according to claim 1 , wherein at least one of ingredients for producing R 1 and R 2 in the polyimide resin represented by the Formula 1 comprises the aromatic tetracarboxylic acid or the aromatic diamine having a molecular mass of at least 300.
12. The insulated electric wire according to claim 1 , wherein the aromatic diamine has a molecular mass of at least 300.
13. The insulated electric wire according to claim 1 , wherein a sum of a molecular mass of the aromatic tetracarboxylic acid for producing R 1 and a molecular mass of the aromatic diamine for producing R 1 in the polyimide resin represented by the Formula 1 is at least 500.
14. The insulated electric wire according to claim 1 , wherein a molecular mass of the aromatic tetracarboxylic acid for producing R 1 is less than 250 and a molecular mass of the aromatic diamine for producing R 1 in the polyimide resin represented by the Formula 1 is less than 250.
15. The insulated electric wire according to claim 1 , wherein a total thickness of the insulating coating is in a range from 40 μm to 150 μm.
16. The insulated electric wire according to claim 2 , wherein the total thickness of the insulating coating is in a range from 40 μm to 150 μm.
17. The insulated electric wire according to claim 1 , wherein aromatic tetracarboxylic dianhydride and aromatic diamine for composing the resin of the first insulating coating film is selected from the aromatic tetracarboxylic dianhydrides and aromatic diamines for composing the second insulating coating film.
18. The insulated electric wire according to claim 17 , wherein the resin of the first insulating coating film is derived from a reaction between pyromellitic dianhydride (PMDA) for the aromatic tetracarboxylic dianhydrides and 4,4′-diaminodiphenyl ether (ODA) for aromatic diamines.
19. The insulated electric wire according to claim 1 , wherein the resin of the first insulating coating film is derived from a reaction between pyromellitic dianhydride (PMDA) for aromatic tetracarboxylic dianhydride and 4,4′-diaminodiphenyl ether (ODA) for aromatic diamine.