Aqueous cyan inkjet ink composition containing a mixture of a self-dispersed pigment and a specific cosolvent mixture
View Patent ↗The invention relates to an aqueous cyan inkjet ink composition for use in ink jet printers comprising an aqueous carrier, a self dispersed cyan pigment, a polymeric additive, a surfactant, and a specific cosolvent mixture comprising a C 2 -C 8 terminal alkanediol, a cyclic amide compound and its derivative, a polyol/polyalkylene oxide condensate, and a trihydric alcohol. Preferably, the self dispersed cyan pigment is surface modified with bisphosphonate group. The cyan inkjet ink demonstrates excellent stability, superior chroma, good printhead maintenance characteristics and high heater reliability in permanent and semi permanent printheads.
1. An aqueous cyan inkjet ink composition for use in ink jet printers comprising:
(a) from about 1.0% to about 5.0% by weight, based on the total weight of the cyan inkjet ink composition, of a self-dispersed cyan pigment;
(b) from about 15.0% to about 25.0% by weight, based on the total weight of the cyan inkjet ink composition, of a cosolvent mixture having:
(1) a C 2 -C 8 terminal alkanediol or a mixture thereof;
(2) a polyol/polyalkylene oxide condensate having the formula
wherein X is H or C 1 -C 6 alkyl, R is H, C 1 -C 6 alkyl or CH 2 O(CH 2 CH 2 O) e H, b is 0 or 1, a+d+f (c+e) is from about 2 to about 100, and f is from about 1 to about 6;
(3) a cyclic amide or its derivative;
(4) a trihydric alcohol;
(c) from about 0.5% to about 2.0% by weight, based on the total weight of the cyan inkjet ink composition, of a surfactant;
(d) from about 0.1% to about 2.0% by weight, based on the total weight of the cyan inkjet ink composition, of a polymeric additive; and
(e) the balance an aqueous carrier,
wherein the ink has excellent printhead maintenance, startup, print quality and minimized kogation.
2. The aqueous cyan inkjet ink composition according to claim 1 wherein the cosolvent mixture comprises:
(1) 1,3-propanediol present in the amount of about 10.0%, based on the total weight of the cyan inkjet ink composition;
(2) polyol/alkylene oxide condensate wherein X is hydrogen, R is C 2 H 5 , b is 1, f is 1, and a+d+f (c+e) is 14-18, present in the amount of about 2.0%, based on the total weight of the cyan inkjet ink composition;
(3) 1-(2-hydroxyethyl)-2-pyrrolidone present in the amount of about 6.0%, based on the total weight of the cyan inkjet ink composition; and
(4) trimethylolpropane present in the amount of about 2.0%, based on the total weight of the cyan inkjet ink composition.
3. The aqueous cyan inkjet ink composition of claim 1 wherein the self-dispersed cyan pigment is modified with bisphosphonate group.
4. The aqueous cyan inkjet ink composition of claim 1 wherein the surfactant is ethoxylated 2,4,7,9-tetramethyl-5-decyn-4,7-diol and is present in the amount of about 0.75%, based on the total weight of the cyan inkjet ink composition.
5. The aqueous cyan inkjet ink composition of claim 1 wherein the self-dispersed cyan pigment is present in the amount of about 3.0%, based on the total weight of the cyan inkjet ink composition.
6. The aqueous cyan inkjet ink composition of claim 1 wherein the polymeric additive is present in the amount of 0.5%, based on the total weight of the cyan inkjet ink composition.
7. The aqueous cyan inkjet ink composition of claim 1 , wherein the polymeric additive contains at least three components: a hydrophilic component, a hydrophobic component, and a protective colloid component.
8. The aqueous cyan inkjet ink composition of claim 7 wherein the hydrophilic component is methacrylic acid, the hydrophobic component is polypropylene glycol nonylphenyl ether acrylate, and the protective colloid segment is poly(ethylene glycol) 2,4,6-tris-(1-phenylethyl)phenyl ether methacylate.
9. The aqueous cyan inkjet ink composition of claim 8 wherein the molar ratio of the methacrylic acid to the polypropylene glycol nonylphenyl ether acrylate to the poly (ethylene glycol) 2,4,6-tris-(1-phenylethyl)phenyl ether methacrylate is 6.2:1:1.
10. The aqueous cyan inkjet ink composition of claim 8 wherein the molar ratio of the methacrylic acid to the polypropylene glycol nonylphenyl ether acrylate to the poly (ethylene glycol) 2,4,6-tris-(1-phenylethyl)phenyl ether methacrylate is 15:1:1.
11. The aqueous cyan inkjet ink composition of claim 1 further comprising a biocide.
12. The aqueous cyan inkjet ink composition according to claim 1 wherein the cosolvent mixture comprises:
(1) 1,3-propanediol present in the amount of about 10.0% based on the total weight of the cyan inkjet ink composition.
(2) polyol/alkylene oxide condensate wherein X is hydrogen, R is C 2 H, b is 1, f is 1, and a+d+f(c+e) is 14-18, present in the amount of about 2.0% based on the total weight of the cyan inkjet ink composition.
(3) 1-(2-hydroxyethyl)-2-pyrrolidone present in the amount of about 6.0% based on the total weight of the cyan inkjet ink composition; and
(4) glycerol present in the amount of about 2.0%, based on the total weight of the cyan inkjet ink composition.