Process for chemical passivation of polymer surfaces
View Patent ↗Process for passivating polymeric particles to prevent undesirable interaction with the environment. In particular, sputter coating of metal and surface treatment with aqueous solutions are shown to successfully passivate the particles, such as for example, toner particles, and prevent interaction between the particles and the epoxy embedding resin which causes artifacts, observed by transmission electron microscopy (TEM) imaging.
1. A process for passivating a polymeric material, comprising:
(a) surface treating the polymeric material, wherein the polymeric material constitutes the surface of one or more toner particles, the one or more toner particles comprising a crystalline polyester; and wherein the surface treatment comprises
(i) immersing the polymeric material into an aqueous solution of either ruthenium tetroxide or osmium tetroxide,
(ii) rinsing the polymeric material, and
(iii) drying the polymeric material, thereby providing a passivated polymeric material.
2. The process of claim 1 , wherein the aqueous solution comprises the ruthenium tetroxide or osmium tetroxide in an amount of from about 0.1 percent to about 10.0 percent by weight of a total weight of the solution.
3. The process of claim 1 , wherein the polymeric material is immersed in the aqueous solution for about 10 minutes to about 4 hours.
4. The process of claim 1 , wherein the polymeric material is dried for about 30 minutes to about 24 hours.
5. The process of claim 1 , wherein the polymeric material is dried at a temperature of from about 16° C. to about 30° C.
6. A process for passivating one or more toner particles, comprising:
(a) surface treating one or more toner particles, wherein the one or more toner particles comprise crystalline polyester and wherein the surface treatment comprises
(i) immersing the one or more toner particles into an aqueous solution of osmium tetroxide,
(ii) rinsing the one or more toner particles, and
(iii) drying the one or more toner particles, thereby providing one or more passivated toner particles; and
(b) embedding the one or more passivated toner particles in an embedding resin.
7. The process of claim 6 , wherein the embedding resin comprises an epoxy resin.
8. A process for embedding one or more toner particles in an embedding resin, comprising:
(a) surface treating one or more toner particles, wherein the one or more toner particles comprise crystalline polyester and wherein the surface treatment comprises
(i) immersing the one or more toner particles into an aqueous solution of either ruthenium tetroxide or osmium tetroxide,
(ii) rinsing the one or more toner particles, and
(iii) drying the one or more toner particles, thereby providing one or more passivated toner particles; and
(b) embedding the one or more passivated toner particles in the embedding resin.
9. The process of claim 6 , wherein the embedding resin is a two-component epoxy consisting of a Bisphenol A-based resin and tetraethylene pentamine.